トリフェニルアルシンオキシド

Triphenylarsine oxide

HCID 14382CAS 1153-05-5

基本情報

標準SMILES
O=[As](c1ccccc1)(c1ccccc1)c1ccccc1
InChIKey
CLVJBRYGLQNRDA-UHFFFAOYSA-N
分子式
C18H15AsO
平均分子量
322.2 g/mol
単同位体質量
322.033885

名称と識別子

優先名称
Triphenylarsine oxide
IUPAC
diphenylarsorylbenzene
現地名
トリフェニルアルシンオキシド
英語名
Triphenylarsine oxide
分子式
C18H15AsO
分子量
322.23

名称と別名

TRIPHENYLARSINE OXIDEArsine oxide, triphenyl-EINECS 214-571-0NSC 12673DTXSID1061570Arsine oxide, triphenylRefChem:191899DTXCID2033364UN3465214-571-01153-05-5diphenylarsorylbenzene
名称をさらに表示
トリフェニルオキソアルソラントリフェニルアルシンオキシドトリフエニルアルシンオキシドトリフエニルアルジンオキシド(ジフェニルアルソロソ)ベンゼントリフェニルアルシン=オキシド(C6H5)3As=OTriphenyloxoarsorane
(diphenylarsoroso)benzeneTriphenylarsenic oxidetriphenyl arsinoxideTriphenyl-arsineoxidTriphenylarsaniumolateTPAOtriphenyl arsine oxideTriphenylarsine oxide, 97%

データベース識別子

CAS
1153-05-5
PubChem CID
14382
DTXSID
DTXSID1061570
EC Number
214-571-0
Nikkaji
J203.407G

物性

構造計算による物性

極性表面積
17.1 Ų
水素結合供与体数
0
水素結合受容体数
1
回転可能結合数
3
重原子数
20

実験および物理化学的性質

Physical DescriptionFaintly beige crystals; [Aldrich MSDS] Insoluble in water; [Alfa Aesar MSDS]

物理化学的性質

融点
191 · 191-193 °C (lit.)
沸点
468.4 · 468.4±28.0 °C(Predicted)
貯蔵温度
Poison room
外見
powder
BRN
2939833 · 2939833
InChI
1S/C18H15AsO/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral];H331 (100%): Toxic if inhaled [Danger Acute toxicity, inhalation];H400 (100%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard];H410 (100%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

P261, P264, P270, P271, P273, P301+P316, P304+P340, P316, P321, P330, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory InformationRestricted substance: Triphenylarsine oxide;EC: 214-571-0;Restriction condition document: PDF link
Hazards Summary · 1 件

Almost nothing is known regarding health effects of organic arsenic compounds in humans. Studies in animals show that some simple organic arsenic compounds are less toxic than inorganic forms. Ingestion of methyl and dimethyl compounds can cause diarrhea and damage to the kidneys. [ATSDR ToxProfiles] An irritant; Toxic by ingestion, inhalation, and skin absorption; Limited evidence of carcinogenicity; [Aldrich MSDS] See Dimethylarsenic acid.

Hazard Classes and CategoriesAcute Tox. 3 (100%);Acute Tox. 3 (100%);Aquatic Acute 1 (100%);Aquatic Chronic 1 (100%)

安全と保護具

Permissible Exposure Limit (PEL)0.5 [mg/m3], as As

法規制情報

Regulatory InformationRestricted substance: Triphenylarsine oxide;EC: 214-571-0;Restriction condition document: PDF link

安全データ

wgk
3
tsca
TSCA listed
ridadr
UN 3465 6.1/PG 2
hs_code
29310099
risk_code
23/25-50/53
hazard_code
T,N

化学と産業

用途と製造

General Manufacturing InformationArsine oxide, triphenyl-: ACTIVE

調製方法

純化方法The anhydrous oxide crystallises from *C6H6, whereas the monohydrate separates from EtOH with m 118o (m 114-117o was also reported). [Beilstein 16 H 846, 16 I 433, 16 II 433, 16 III 1022, 16 IV 1139.] HIGHLY TOXIC.

サプライヤー11 社

Aladdin Scientific[email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
上海瀚鸿科技股份有限公司021-54306202 13764082696 · [email protected]
青岛海智微元生物科技有限公司18317699790 18317699790 · [email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]

関連反応

2 件

関連ノート

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