Perfluoro(methyl vinyl ether) (HCID 14474)

概要

Perfluoro(methylvinyl ether) appears as a colorless gas. Heavier than air. Easily liquefied. Contact with the liquid may cause frost bite by evaporative cooling. May asphyxiate by displacing air. A flame may flash back from the source of ignition to the source of a leak. Under prolonged exposure to fire or heat containers may rupture violently and rocket.

名称と識別子

優先名称: Perfluoro(methyl vinyl ether)
IUPAC: 1,1,2-trifluoro-2-(trifluoromethoxy)ethene
現地名: (トリフルオロビニル)(トリフルオロメチル)エーテル
英語名: Trifluoromethyl trifluorovinyl ether
分子式: C3F6O
分子量: 166.02

名称と別名

Trifluoromethyl trifluorovinyl ether1187-93-5Perfluoro(methyl vinyl ether)Trifluoro(trifluoromethoxy)ethyleneEthene, 1,1,2-trifluoro-2-(trifluoromethoxy)-Ethene, trifluoro(trifluoromethoxy)-3-OXAPERFLUOROBUTENEEINECS 214-703-7UNII-6II375V3XGBRN 19074576II375V3XGETHER, TRIFLUOROMETHYL TRIFLUOROVINYL

名称をさらに表示

(トリフルオロメチル)(1,2,2-トリフルオロエテニル)エーテルトリフルオロメチル(トリフルオロビニル)エーテル1,1,2-トリフルオロ-2-(トリフルオロメトキシ)エテントリフルオロメチル(1,2,2-トリフルオロエテニル)エーテルヘキサフルオロ-3-オキサ-1-ブテントリフルオロメチルトリフルオロビニルエーテル1,1,2,4,4,4-ヘキサフルオロ-3-オキサ-1-ブテン1-(トリフルオロメトキシ)-1,2,2-トリフルオロエテン(トリフルオロメチル)(トリフルオロエテニル)エーテル1-(トリフルオロメトキシ)トリフルオロエテンペルフルオロメチルビニルエーテルヘキサフルオロ-2-オキサ-3-ブテン(トリフルオロメチル)(1,2,2-トリフルオロビニル)エーテルトリフルオロビニル(トリフルオロメチル)エーテル(トリフルオロメトキシ)トリフルオロエテン(トリフルオロビニル)(トリフルオロメチル)エーテル(1,2,2-トリフルオロエテニル)トリフルオロメチルエーテルペルフルオロ(メチル=ビニル=エーテル)トリフルオロメチル(トリフルオロエテニル)エーテル(トリフルオロメチル)(トリフルオロビニル)エーテルPMVEPerfluoro(methylvinylether)Perfluoromethylvinyl Ether (PMVE)uorovinyLtrifluoromethoxyetheneHexafluoro-3-oxa-1-buteneHexafluoro-2-oxa-3-buteneperfluorinatedmethylvinylether(Trifluoromethoxy)trifluoroethene

trifluoromethoxytrifluoroethyleneDTXSID3051599EC 214-703-7TRIFLUOROMETHYL TRIFLUORVINYL ETHERPERFLUOROVINYL PERFLUOROMETHYL ETHERRefChem:171634DTXCID10301511,1,2-trifluoro-2-(trifluoromethoxy)ethene

データベース識別子

CAS: 1187-93-5
PubChem CID: 14474
DTXSID: DTXSID3051599
UNII: 6II375V3XG
EC Number: 214-703-7
Nikkaji: J203.449B

物性

構造計算による物性

XLogP: 2.4
極性表面積: 9.2 Å²
水素結合供与体数: 0
水素結合受容体数: 7
回転可能結合数: 1
重原子数: 10
形式電荷: 0
複雑度: 142

実験および物理化学的性質

PFAS · 6 件

PFAS -> Suspected persistent, mobile, toxic (PMT) PFAS or PFAS-like compounds

PFAS -> OECD Category

PFAS -> Other/unspecified

PFAS -> PFAS identified in REACH Regulation EC No. 1272/2008

SpringerMaterials PropertiesSchoenflies notation

Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR

Physical Description · 2 件

Perfluoro(methylvinyl ether) appears as a colorless gas. Heavier than air. Easily liquefied. Contact with the liquid may cause frost bite by evaporative cooling. May asphyxiate by displacing air. A flame may flash back from the source of ignition to the source of a leak. Under prolonged exposure to fire or heat containers may rupture violently and rocket.

Gas Vapor

物理化学的性質

沸点: -22 °C · -22 °C
比重(密度): 1.321 · 1.3210 (estimate)
蒸気圧: 101.325 kPa · 101.325kPa at 20℃
水溶解度: 31.5 mg/L · 31.5mg/L at 28℃
InChI: InChI=1S/C3F6O/c4-1(5)2(6)10-3(7,8)9
InChIKey: BLTXWCKMNMYXEA-UHFFFAOYSA-N
SMILES: C(/F)(\F)=C(/F)\OC(F)(F)F
LogP: 1.42 · 1.42
EPAの化学物質情報: 1 · Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)- (1187-93-5)

安全と法規制

GHS分類

GHS Classification · 6 件

Danger

H220 (18.2%): Extremely flammable gas [Danger Flammable gases]

P203, P210, P222, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P377, P381, P403, P403+P233, P405, P410+P403, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 11 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H220: Extremely flammable gas [Danger Flammable gases]

危険有害性情報

Regulatory Information · 3 件

Regulation (EC) No 1935/2004 (amended)

Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 25-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/13408

DOT LabelFlammable Gas

Fire Hazards · 2 件

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

· EXTREMELY FLAMMABLE.

Health Hazards · 2 件

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

· Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.

DOT ID and Guide3153 115

Reactive GroupEthers

安全と保護具

Fire FightingExcerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Accidental Release Measures · 2 件

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 件

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).

Nonfire Spill ResponseExcerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Isolation and Evacuation · 2 件

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Immediate precautionary measure

安全データ

tsca: TSCA listed
rtecs: KO4350000
ridadr: UN 3153
hs_code: 2909199090
risk_code: 20
化審法: 新規公示化学物質（2011年3月31日以前届出）
hazard_code: F
hazard_note: Flammable gas
safety_code: 23-38
hazard_class: 2.1

化学と産業

用途と製造

U.S. Production2023: 250,000 - <550,000 lb

Industry UsesMonomers

Use ClassificationPFAS (per- and polyfluoroalkyl substances) -> OECD Category

General Manufacturing Information · 2 件

Plastics Material and Resin Manufacturing

Ethene, 1,1,2-trifluoro-2-(trifluoromethoxy)-: ACTIVE

応用分野 · 1 件

一般的な説明A colorless gas. Heavier than air. Easily liquefied. Contact with the liquid may cause frost bite by evaporative cooling. May asphyxiate by displacing air. A flame may flash back from the source of ignition to the source of a leak. Under prolonged exposure to fire or heat containers may rupture violently and rocket.