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カドミウムセレニド

Cadmium selenide

HCID 14784
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
1306-24-7
標準SMILES
[Se]=[Cd]
InChIKey
AQCDIIAORKRFCD-UHFFFAOYSA-N
分子式
CdSe
平均分子量
191.38 g/mol
単同位体質量
193.8198798

概要

Cadmium selenide is a cadmium molecular entity.

名称と識別子

優先名称
Cadmium selenide
IUPAC
selanylidenecadmium
現地名
カドミウムセレニド
英語名
Cadmium selenide
分子式
CdSe
分子量
191.37

名称と別名

CADMIUM SELENIDE1306-24-7Cadmium selenide (CdSe)selanylidenecadmiumcadmium(II) selenidecadmium(2+) selenideDTXSID1061651A7F646JC5CCHEBI:50834CdSe cpdRefChem:122596DTXCID2033990
名称をさらに表示
セレン化カドミウムカドミウムセレニドCADMIUM SELENIDE STREMDOTS™ QUANTUM DOT (CDSE CORE), 50UMOL/L IN HEXANES, 525NM PEAK EMISSIONセレン化カドミウム, 99.99%CADMIUM SELENIDE STREMDOTS™ QUANTUM DOT (CDSE CORE), 50UMOL/L IN HEXANES, 575NM PEAK EMISSIONCADMIUM SELENIDE STREMDOTS™ QUANTUM DOT (CDSE CORE), 50UMOL/L IN HEXANES, 600NM PEAK EMISSIONCADMIUM SELENIDE STREMDOTS™ QUANTUM DOT (CDSE CORE), 50UMOL/L IN HEXANES, 550NM PEAK EMISSIONセレン化カドミウム StremDots™ quantum dot (CdSe core), 50umol/L in hexanes, 550nm peak emissionセレン化カドミウム StremDots™ quantum dot (CdSe core), 50umol/L in hexanes, 575nm peak emissionセレン化カドミウム (99.999+%-Cd) PURATREMセレン化カドミウム StremDots™ quantum dot (CdSe core), 50umol/L in hexanes, 600nm peak emissionセレン化カドミウム StremDots™ quantum dot (CdSe core), 50umol/L in hexanes, 525nm peak emissionRed BBSLUMIDOT CDSEProMotion CodeCadmium ColoursselenoxocadmiumLumidot CdSe 520

データベース識別子

CAS
1306-24-7、157453-13-9、331269-19-3
PubChem CID
14784
DTXSID
DTXSID1061651
ChEBI
CHEBI:50834
EC Number
215-148-3
Nikkaji
J96.071C

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
0
回転可能結合数
0
重原子数
2
形式電荷
0
複雑度
2

実験および物理化学的性質

Chemical ClassesMetals -> Cadmium Compounds, Inorganic
SpringerMaterials Propertiesvalence band parameter
Physical Description · 2 件

Dry Powder

White to brown solid; Turns red in sunlight; [Merck Index] Red or black odorless powder; Insoluble in water; [MSDSonline]

物理化学的性質

融点
1350 °C · >1350°C
沸点
69 °C · 69.00°C
比重(密度)
5.81 g/mL · 5.81 g/mL at 25 °C(lit.)
屈折率
2.87 · 2.87 (900 nm)
貯蔵温度
2 · 2-8°C
溶解性
2 O · insoluble in H2O
外見
粒状
色
ブラウンレッドからブラック
比重
5.81 · 5.81
水溶解度
水に不溶。
Merck
14 · 14,1626
安定性
冷蔵保存
InChI
1S/Cd.Se
InChIKey
AQCDIIAORKRFCD-UHFFFAOYSA-N

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

Danger

H301+H331 (32.5%): Toxic if swallowed or if inhaled [Danger Acute toxicity, oral; acute toxicity, inhalation]

P203, P260, P261, P264, P270, P271, P273, P280, P301+P316, P302+P352, P304+P340, P316, P317, P318, P319, P321, P330, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 323 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H302: Harmful if swallowed [Warning Acute toxicity, oral]

危険有害性情報

Regulatory Information · 5 件

Chemical: Cadmium selenide (CdSe)

Cadmium selenide (CdSe) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Cadmium selenide (CdSe) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 04-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/23754

Restricted substance: Cadmium selenide

Cadmium selenide: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Mixed zinc cadmium sulfides and selenides: Human health tier II assessment
Hazards SummaryAn irritant; Can be absorbed through skin; Danger of cumulative effects; [MSDSonline] See Cadmium and the linked diseases. See Selenium.
Hazard Classes and Categories · 2 件

Acute Tox. 3 (98.1%)

Acute toxicity - category 4

安全と保護具

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Cadmium is absorbed from oral, inhalation, and dermal routes. Cadmium initially binds to metallothionein and albumin and is transported mainly to the kidney and liver. Toxic effects are observed once the concentration of cadmium exceeds that of available metallothionein, and it has also been shown that the cadmium-metallothionein complex may be damaging. Cadmium is not known to undergo any direct metabolic conversion and is excreted unchanged, mainly in the urine. Selenium may be absorbed through inhalation and ingestion, while some selenium compounds may also be absorbed dermally. Once in the body, selenium is distributed mainly to the liver and kidney. Selenium is an essential micronutrient and is a component of glutathione peroxidase, iodothyronine 5'-deiodinases, and thioredoxin reductase. Organic selenium is first metabolized into inorganic selenium. Inorganic selenium is reduced stepwise to the intermediate hydrogen selenide, which is either incorporated into selenoproteins after being transformed to selenophosphate and selenocysteinyl tRNA or excreted into the urine after being transformed into methylated metabolites of selenide. Elemental selenium is also methylated before excretion. Selenium is primarily eliminated in the urine and feces, but certain selenium compounds may also be exhaled. (L619, L6)

用途と製造

Uses · 3 件

Used in photoconductors, semiconductors, photoelectric cells, rectifiers, and phosphors; [Merck Index] Used as red pigment; [Hawley]

Semiconductor Manufacturing [Category: Industry]

Cadmium selenide is used as a semiconductor. It is also found in laser diodes. (L471)

U.S. Production2023: 50,000 - <250,000 lb
Consumer UsesSemiconductor and photovoltaic agent
Industry UsesSemiconductor and photovoltaic agent
Household ProductsInformation on 6 consumer products that contain Cadmium selenide in the following categories is provided:

関連反応

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化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
cadmium selemide
Cadmium monoselenide
215-148-3EINECS 215-148-3UNII-A7F646JC5C(Selenido)cadmiumSCHEMBL19326Cadmium selenide, 325 meshFC164914NS00112451
SMILES
[Se]=[Cd]
Knoop Microhardness
1300 · 1300, N/mm2
CAS データベース
1306 · 1306-24-7(CAS DataBase Reference)
EPAの化学物質情報
Cadmium selenide (CdSe) (1306-24-7)
化学的性質 · 1 件

化学的特性3–12mm pieces (sintered), and -325 mesh 10μm or less with 99.999% purity; white to brown; cub or hexagonal crystal(s); hex: a=0.4309nm, c=0.7021 nm, enthalpy of fusion 305.307 kJ/mol; becomes red in sunlight; used as a red pigment, in semiconductors, and as an evaporation material and sputtering target to produce photoconductive films and infrared filters; possible use in the electrofabrication of microdiode arrays [HAW93] [MER06] [CER91] [KLE93] [KRE91]

Exposure Control and Personal Protection · 2 件

Biological Exposure Indices (BEI) [ACGIH] - Cd in urine = 5 ug/g creatinine; Cd in blood = 5 ug/L; sampling time not critical; Monitoring in blood should be preferred during the initial year of exposure and whenever changes in the degree of exposure are suspected. [ACGIH]

0.02 [mg/m3], inhalable fraction, as Se[German Research Foundation (DFG)]

Minimum Risk Level · 1 件

Acute Inhalation: 0.00003 mg/m3 (Cadmium) (L134) Chronic Inhalation: 0.00001 mg/m3 (Cadmium) (L134) Intermediate Oral: 0.0005 mg/kg/day (Cadmium) (L134) Chronic Oral: 0.0001 mg/kg/day (Cadmium) (L134) Chronic Oral: 0.005 mg/kg/day (Selenium) (L134)

Threshold Limit Values (TLV)0.01 [mg/m3], as Cd ( 0.002 mg/m3, as Cd, respirable fraction) 0.2 mg/m3, as Se
Permissible Exposure Limit (PEL)0.005 [mg/m3], as Cd( see 29 CFR 1910.1027) 0.2 mg/m3, as Se
Immediately Dangerous to Life or Health (IDLH)9.0 [mg/m3], as Cd

毒性情報

TreatmentCadmium poisoning is treated by removal from exposure and supportive care. If ingested, induced vomiting or gastric lavage may be performed. (L139)
Health Effects · 1 件

Chronic exposure to cadmium fumes can cause chemical pneumonitis, pulmonary edema, and lung diseases such as bronchitis and emphysema. Cadmium also accumulates in the kidneys, causing permanent damage. Loss of bone density also occurs. Chronic oral exposure to high concentrations of selenium compounds can produce a disease called selenosis. The major signs of selenosis are hair loss, nail brittleness, and neurological abnormalities (such as numbness and other odd sensations in the extremities). Animal studies have shown that selenium may also affect sperm production and the female reproductive cycle. (L619, L6)

Adverse EffectsNephrotoxin - The chemical is potentially toxic to the kidneys in the occupational setting.
Exposure RoutesOral (L6) ; inhalation (L6) ; dermal (L6)
Toxicity Summary · 1 件

Cadmium initially binds to metallothionein and is transported to the kidney. Toxic effects are observed once the concentration of cadmium exceeds that of available metallothionein, and it has also been shown that the cadmium-metallothionein complex may be damaging. Accumulation of cadmium in the kidney results in increased excretion of vital low and high weight molecular proteins. Cadmium is a high affinity zinc analog and can interfere in its biological processes. It also binds to and activates the estrogen receptor, likely stimulating the growth of certain types of cancer cells and causing other estrogenic effects, such as reproductive dysfunction. Cadmium causes cell apoptosis by activating mitogen-activated protein kinases. Selenium readily substitutes for sulfur in biomolecules and in many biochemical reactions, especially when the concentration of selenium is high and the concentration of sulfur is low. Inactivation of the sulfhydryl enzymes necessary for oxidative reactions in cellular respiration, through effects on mitochondrial and microsomal electron transport, might contribute to acute selenium toxicity. Selenomethionine (a common organic selenium compound) also appears to randomly substitute for methionine in protein synthesis. This substitution may affect the structure and functionability of the protein, for example, by altering disulfide bridges. Inorganic forms of selenium appear to react with tissue thiols by redox catalysis, resulting in formation of reactive oxygen species and causing damage by oxidative stress. (L619, L8, A18, A19, A28)

Signs and Symptoms · 1 件

Acute inhalation of cadmium fumes results in metal fume fever, which is characterized by chills, fever, headache, weakness, dryness of the nose and throat, chest pain, and coughing. Ingestion of cadmium causes vomiting and diarrhea. Short-term oral exposure to high concentrations of selenium may cause nausea, vomiting, and diarrhea. Brief exposures to high levels of elemental selenium or selenium dioxide in air can result in respiratory tract irritation, bronchitis, difficulty breathing, and stomach pains. Longer-term exposure to either of these air-borne forms can cause respiratory irritation, bronchial spasms, and coughing. (L619, L6)

Carcinogen Classification1, carcinogenic to humans. (L135)

安全データ

wgk
3
tsca
TSCA listed
rtecs
EV2300000
ridadr
UN 2570 6.1/PG 3
hs_code
28429090
risk_code
21-23/25-33-50/53-65-52/53-48/20-38-20/21/22-11-63
hazard_code
T,N,Xn,F
safety_code
36/37-45-60-61-28-20/21-62-16
hazard_class
6.1
packing_group
II
Hazard Classifications
Acute Tox. 3 InhalationAcute Tox. 3 OralAcute Tox. 4 DermalAquatic Acute 1Aquatic Chronic 1STOT RE 2 Oral
ストレージクラス
6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
General Manufacturing Information · 2 件

Electrical Equipment, Appliance, and Component Manufacturing

Cadmium selenide (CdSe): ACTIVE

応用分野 · 5 件

解説水に不溶の暗赤色結晶,CdSe.II-VI型半導体.

用途機能性材料、太陽電池材料、蛍光試薬。

説明Cadmium selenide (CdSe) appears as grayish-brown or red crystals, is insoluble in water, highly toxic, and has a melting point of 1350°C. It can be produced by co-heating metallic cadmium with hydrogen selenide and is used in electron emitters, spectral analysis, photoconductors, semiconductors, and photosensitive components.

使用Cadmium selenide is used as a n-type semiconductor and its nanoparticles are used in laser diodes, opto-electronic devices, nanosensing, biomedical imaging and high efficiency solar cells. Since, it is transparent to infrared light, it finds application in photoresistors and windows for instruments utilizing IR light.

一般的な説明CdSe crystal can exist in solid hexagonal or cubic structure. CdSe behaves as an n-type semiconductor, with a bandgap of 1.74 eV (300K).1

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