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HCID 14799作成日：2026年11月4日

Mercury oxide sulfate

https://huagongshe.com/ja/chemical/14799

Mercury oxide sulfate の分子構造式

識別子と物理属性

CAS No.1312-03-4
分子式HgSO4.2HgO
平均分子量729.84 g/mol
単同位体質量733.85349 g/mol
SMILESO=S(=O)([O-])[O-].[Hg+2].[Hg+2].[Hg+2].[O-2].[O-2]
InChIKeySZAAFGJXWYCFPL-UHFFFAOYSA-L
PubChem CID14799
EC No.215-191-8
DTXSIDDTXSID40927121

化学・物理的性質

極性表面積90.6
水素結合供与体数0
水素結合受容体数6
回転可能結合数0
重原子数10
形式電荷0
複雑度62.2
臭いOdorless
密度6.44
Color/FormLemon-yellow powderBRIGHT-YELLOW SCALES
溶解度SOLUBILITY IN WATER @ 16 °C: 0.003 G/100 CCSLIGHTLY SOL IN HOT WATERINSOL IN ALCOHOLSol in acids
蒸気密度25.2 (Air= 1)
Physical DescriptionMercuric subsulfate, [solid] appears as a lemon-yellow powder or bright yellow scaly material. Very slightly soluble in water and denser than water. Hence sinks in water. Toxic by inhalation and by ingestion.
Other Experimental PropertiesProved to be mercury oxonium sulfate in x-ray studies of its structure. Polymeric oxonium cations (Hg3O2)x form 2-dimensional infinite layers. The sulfate ions lie inside loops of wide-meshed cation lattice.

安全性と法規制

輸送ラベル（DOT）Poison
火災危険Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
健康有害性Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
反応性グループMetals, Less Reactive
RCRA 要件D009A solid waste containing mercury may or may not become characterized as a hazardous waste when subjected to the Toxicity Characteristic Leaching Procedure listed in 40 CFR 261.24, and if so characterized, must be managed as a hazardous waste. /Mercury/
OSHA StandardsVacated 1989 OSHA PEL still enforced in some states: Hg vapor, TWA 0.05 mg/cu m, skinNon-alkyl cmpds, Ceiling 0.1 mg/cu m, skin. /Mercury cmpd, as Hg, (except (organo) alkyls)/
Reactivity ProfileMERCURIC SUBSULFATE, [SOLID] is soluble in acids.
大気基準Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Mercury oxide sulfate is included on this list.
Air and Water ReactionsVery slightly soluble in water.
EPA Hazardous Waste NumberD009Mercury. A waste containing mercury may or may not be characterized as a hazardous waste following testing by the Toxicity Characteristic Leaching Procedure as prescribed by the Resource Conservation and Recovery Act (RCRA) regulations. /Mercury/
NIOSH RecommendationsRecommended Exposure Limit: 10 Hr Time-Weighted Avg: 0.05 mg/cu m, skin (Hg vapor). /Mercury [except (organo) alkyls] (as Hg)/Recommended Exposure Limit: Ceiling Value: 0.1 mg/cu m, skin. /Mercury compounds [except (organo) alkyls] (as Hg)/
清浄水法要件Toxic pollutant designated pursuant to section 307(a)(1) of the Clean Water Act and is subject to effluent limitations. /Mercury and cmpd/
消火Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
応急処置Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
清掃方法Mercury spills should be cleaned up immediately by use of a special vacuum cleaner. Then the area should be washed with a dilute calcium sulfide solution. Small quantities of mercury can be picked up by mixing with copper metal granules. ... /Mercury/Mercury removal from waste water can be accomplished by these processes: BMS processChlorine is added to the waste water, oxidizing any mercury present to the ionic state. The BMS adsorbent (an activated carbon concentrate of sulfur cmpd on its surface) is used to collect ionic mercury. The spent adsorbent is then distilled to recover the mercury, leaving a carbon residue for reuse or disposal. TMR IMAC ProcessWaste water is fed into a reactor, whereby a slight excess of chlorine is maintained, oxidizing any mercury present to ionic mercury. The liquid is then passed through the TMR IMAC ion-exchange resin where mercury ions are adsorbed. The mercury is then stripped from the spent resin with hydrochloric acid solution. /Mercury cmpds/SPILLED MERCURY CMPD OR SOLN CAN BE CLEANED UP BY ANY METHOD THAT DOES NOT CAUSE EXCESSIVE AIRBORNE CONTAMINATION OR SKIN CONTACT. /MERCURY COMPOUNDS/1) Ventilate area of spill. 2) Collect spilled material for reclamation using commercially available mercury vapor depressants or specialized vacuum cleaners. /Inorganic mercury/
非火災時の漏出対応Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
処分方法Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number D009, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste.
Preventive MeasuresIf material not on fire and not involved in fire: Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Attempt to stop leak if without undue personnel hazard. /Mercury compound, liquid, NOS/Personnel protection: Avoid breathing dusts, and fumes from burning material. Keep upwind. Avoid bodily contact with the material. ... Do not handle broken packages unless wearing appropriate personal protective equipment. Wash away any material which may have contacted the body with copious amounts of water or soap and water. ... If contact with the material anticipated, wear appropriate chemical protective clothing. /Mercury compound, solid, NOS/Personnel protection: Keep upwind. Avoid breathing vapors. ... Do not handle broken packages unless wearing appropriate personal protective equipment. /Mercury compounds, liquid, NOS/Preventative measure: adequate ventilationcareful attention to good housekeeping, e.g., avoidance of spills, and prompt and proper cleaning if a spill occursall containers of mercury and its compounds should be kept tightly closedshould be washed on a regular basis with dilute calcium sulfide solution or other suitable reactantfloors should be nonporousall workers directly involved in the plant operation should shower thoroughly each day before leaving. /Mercury compounds/
Isolation and EvacuationExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Minimum Risk LevelChronic Inhalation: 0.0002 mg/m3 (L134)
Threshold Limit Values (TLV)8 hr Time Weighted Avg (TWA): 0.025 mg/cu m, skin /Mercury, elemental and inorganic forms, as Hg/Excursion Limit Recommendation: Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than a total of 30 minutes during a work day, and under no circumstances should they exceed 5 times the TLV-TWA, provided that the TLV-TWA is not exceeded. /Mercury, elemental and inorganic forms, as Hg/A4: Not classifiable as a human carcinogen. /Mercury, elemental and inorganic forms, as Hg/Biological Exposure Index (BEI): Determinant: total inorganic mercury in urineSampling Time: prior to shiftBEI: 35 ug/g creatine. The determinant may be present in biological specimens collected from subjects who have not been occupationally exposed, at a concentration which could affect interpretation of the result. Such background concentrations are incorporated in the BEI value. /Mercury/Biological Exposure Index (BEI): Determinant: total inorganic mercury in bloodSampling Time: end of shift at end of workweekBEI: 15 ug/L. The determinant may be present in biological specimens collected from subjects who have not been occupationally exposed, at a concentration which could affect interpretation of the result. Such background concentrations are incorporated in the BEI value. /Mercury/
Personal Protective Equipment (PPE)Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Immediately Dangerous to Life or Health (IDLH)10 mg Hg/m3 (NIOSH, 2024)10 mg/cu m (as Hg) /Mercury cmpd (except (organo) alkyl compounds (as Hg)/
TreatmentMercury poisoning is treated by immediate decontamination and chelation therapy using DMSA, DMPS, DPCN, or dimercaprol. (A7)
健康影響Mercury mainly affects the nervous system. Exposure to high levels of metallic, inorganic, or organic mercury can permanently damage the brain, kidneys, and developing fetus. Effects on brain functioning may result in irritability, shyness, tremors, changes in vision or hearing, and memory problems. Acrodynia, a type of mercury poisoning in children, is characterized by pain and pink discoloration of the hands and feet. Mercury poisoning can also cause Hunter-Russell syndrome and Minamata disease. (L7)
暴露経路Oral (L7)inhalation (L7)dermal (L7)
毒性の概要High-affinity binding of the divalent mercuric ion to thiol or sulfhydryl groups of proteins is believed to be the major mechanism for the activity of mercury. Through alterations in intracellular thiol status, mercury can promote oxidative stress, lipid peroxidation, mitochondrial dysfunction, and changes in heme metabolism. Mercury is known to bind to microsomal and mitochondrial enzymes, resulting in cell injury and death. For example, mercury is known to inhibit aquaporins, halting water flow across the cell membrane. It also inhibits the protein LCK, which causes decreased T-cell signalling and immune system depression. Mercury is also believed to inhibit neuronal excitability by acting on the postsynaptic neuronal membrane. It also affects the nervous system by inhibiting protein kinase C and alkaline phosphatase, which impairs brain microvascular formation and function, as well as alters the blood-brain barrier. Mercury also produces an autoimmune response, likely by modification of major histocompatibility complex (MHC) class II molecules, self peptides, T-cell receptors, or cell-surface adhesion molecules. (L7, A8, A25, A26)
Signs and SymptomsCommon symptoms include peripheral neuropathy (presenting as paresthesia or itching, burning or pain), skin discoloration (pink cheeks, fingertips and toes), edema (swelling), and desquamation (dead skin peels off in layers). (A5)
Carcinogen Classification3, not classifiable as to its carcinogenicity to humans. (L135)
Evidence for CarcinogenicityA4: Not classifiable as a human carcinogen. /Mercury, elemental and inorganic forms, as Hg/
州飲料水ガイドライン(AZ) ARIZONA 3 ug/l /Mercury/
Federal Drinking Water StandardsEPA 2 ug/l /Mercury/
連邦飲料水ガイドラインEPA 2 ug/l /Mercury/