ジメチルシアナミド

Dimethylcyanamide

HCID 15112

基本情報

CAS
1467-79-4
標準SMILES
CN(C)C#N
InChIKey
OAGOUCJGXNLJNL-UHFFFAOYSA-N
分子式
C3H6N2
平均分子量
70.09 g/mol
単同位体質量
70.05309819

概要

Dimethyl cyanamide is a clear liquid. (NTP, 1992)

名称と識別子

優先名称
Dimethylcyanamide
IUPAC
dimethylcyanamide
現地名
ジメチルシアナミド
英語名
Dimethylcyanamide
分子式
C3H6N2
分子量
70.09

名称と別名

Dimethylcyanamide1467-79-4DIMETHYL CYANAMIDEN-Cyano-N-methylmethanamineCyanamide, dimethyl-DimethylkyanamidN-Cyanodimethylamine6P25IPQ8GNNSC-7765DTXSID9025116RefChem:134326DTXCID405116
名称をさらに表示
ジメチルシアナミドジメチルシアノアミンジメチルアミノシアニドN-シアノ-N-メチルメタンアミンシアノジメチルアミン(ジメチルアミノ)シアニドN,N-ジメチルシアナミド(CH3)2NCequivNdimethyl-cyanamidDimethylcyanamineDimethylcyanoamineN-Cyanodimethylamide
215-991-7Cyanamide, N,N-dimethyl-MFCD00001767cyanodimethylamineDimethylkyanamid [Czech]CCRIS 5909N,N-dimethylcyanamideHSDB 4274

データベース識別子

CAS
1467-79-4
PubChem CID
15112
DTXSID
DTXSID9025116
ChEBI
CHEBI:229338
UNII
6P25IPQ8GN
EC Number
215-991-7
Nikkaji
J33.545B

物性

構造計算による物性

XLogP
-0.2
極性表面積
27 Ų
水素結合供与体数
0
水素結合受容体数
2
回転可能結合数
0
重原子数
5

実験および物理化学的性質

Chemical ClassesNitrogen Compounds -> Cyanamides
SpringerMaterials PropertiesSchoenflies notation
LogP-0.15
Density · 2 件

0.88 (NTP, 1992) - Less dense than water; will float

0.876

Color/FormCOLORLESS, MOBILE LIQUID
Solubility · 3 件

Decomposes (NTP, 1992)

VERY SOL IN WATER

SOL IN ALCOHOL, ETHER & ACETONE

物理化学的性質

融点
-41 °C · -41 °C
沸点
161 · 161-163 °C(lit.)
比重(密度)
0.867 g/mL · 0.867 g/mL at 25 °C(lit.)
屈折率
20 · n20/D 1.41(lit.)
闪点
137 °F · 137 °F
貯蔵温度
2 · Inert atmosphere,2-8°C

化学的性質

化学的特性CLEAR COLORLESS TO YELLOWISH LIQUID

安全と法規制

GHS分類

GHS Classification · 6 件

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P261, P264, P270, P271, P301+P316, P304+P340, P316, P321, P330, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 41 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H227: Combustible liquid [Warning Flammable liquids]

危険有害性情報

Regulatory InformationDimethylcyanamide: Does not have an individual approval but may be used under an appropriate group standard
DOT LabelPoison
Fire HazardsThis chemical is combustible. (NTP, 1992)
Health HazardsACUTE/CHRONIC HAZARDS: This compound is an irritant. It reacts with water to produce toxic and flammable vapors. (NTP, 1992)
Hazards SummaryReacts with water producing cyanide gas; An irritant; [CAMEO] An irritant; Can be absorbed through skin; Effects in high-dose animal studies include convulsions; [MSDSonline] See Hydrogen cyanide.
Reactive GroupAmines, Phosphines, and Pyridines

安全と保護具

Fire FightingFires involving this compound should be controlled using a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Exposure Control and Personal Protection2.0 [mg/m3], inhalable fraction, as CN[German Research Foundation (DFG)]
Nonfire Spill Response · 1 件

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:
Permissible Exposure Limit (PEL)5.0 [mg/m3], as CN

毒性情報

Adverse EffectsOther Poison - Chemical Asphyxiant
Human Toxicity Excerpts · 2 件

CMPD APPEARS TO BE HAZARDOUS, ESP BY SKIN ABSORPTION

The neurotoxic effects of dimethyl cyanamide are weakness and ataxia. /From table/

Non-Human Toxicity Excerpts · 1 件

... ORAL ... IN RATS & GUINEA PIGS ... SYMPTOMS WERE WEAKNESS, ATAXIA, GASPING RESPIRATIONS, & UNCONSCIOUSNESS. IT WAS READILY ABSORBED THROUGH GUINEA PIG SKIN ... WITH LITTLE SKIN IRRITATION. IT WAS NOT SEVERE EYE IRRITANT TO RABBIT. NO SKIN SENSITIZATION WAS PRODUCED IN GUINEA PIG.

Toxicity DataLC50 (rat) = 2,500 mg/m3

安全データ

wgk
3
tsca
TSCA listed
rtecs
GS6475000
ridadr
UN 2810 6.1/PG 3
hs_code
29269095
risk_code
23/25

化学と産業

薬理情報

Absorption, Distribution and ExcretionIT WAS READILY ABSORBED THROUGH GUINEA PIG SKIN ... .

用途と製造

Uses · 2 件

Used as chemical intermediate and solvent; [Hawley]

CHEMICAL INTERMEDIATE; SOLVENT

Methods of ManufacturingREACTION OF NITROMETHANE WITH TRIS-(DIMETHYLAMINO)ARSINE; PHOTOISOMERIZATION OF CARBODIIMIDES
General Manufacturing InformationCyanamide, N,N-dimethyl-: ACTIVE
応用分野 · 3 件

用途化学中間体、溶媒

使用Dimethylcyanamide in the presence of tetrachlorosilane and zinc chloride is used as a promoter for one-pot, three component synthesis of a novel series of 1,3-oxazines. Being a dialkylcyanamide, it has been proved to be a more reactive substrate toward metal-mediated nucleophilic addition than alkylcyanides.

一般的な説明Clear liquid.

調製方法

Dimethyl cyanamide is made by the reaction of nitromethane with tris(dimethylamino) arsine.

サプライヤー42 社

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
陕西缔都化学有限公司029-029-81123119 17391733320 · [email protected]
爱斯特(成都)生物制药股份有限公司+86-28-85122536 85324413 · [email protected]
上海仲因实业有限公司2537653158 16621191650 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]

関連反応

65 件

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