1,5-Diphenylpenta-1,4-dien-3-one;palladium

HCID 154270CAS 32005-36-0

基本情報

標準SMILES: O=C(C=Cc1ccccc1)C=Cc1ccccc1.O=C(C=Cc1ccccc1)C=Cc1ccccc1.[Pd]
InChIKey: UKSZBOKPHAQOMP-UHFFFAOYSA-N
分子式: C34H28O2Pd
平均分子量: 575 g/mol
単同位体質量: 574.11241614

概要

Bis(1,5-diphenyl-1,4-pentadien-3-one) palladium(0) is a chemical compound of palladium. Palladium is a chemical element with the chemical symbol Pd and an atomic number of 46. It is found as a free metal alloyed with gold and other platinum group metals and in the rare minerals cooperite and polarite. (L794)

名称と識別子

優先名称: 1,5-Diphenylpenta-1,4-dien-3-one;palladium
IUPAC: bis(1,5-diphenylpenta-1,4-dien-3-one);palladium

名称と別名

32005-36-01,5-diphenylpenta-1,4-dien-3-one;palladiumBis((1,2,4,5-eta)-1,5-diphenyl-1,4-pentadien-3-one)palladiumC34H28O2PdPalladium(0) bis(dibenzylideneacetone)Bis(dibenzylideneacetone) Palladium(0)tris-(dibenzylideneacetone)dipalladium(0)SCHEMBL19685bis(dibenylideneacetone) palladiumbis(dibenzylidenacetone) palladiumDTXSID70953892UKSZBOKPHAQOMP-UHFFFAOYSA-N

名称をさらに表示

bis(dibenzylideneacetone) palladiumpalladium bis(dibenzylideneacetone)bis (dibenzylideneacetone) palladiumbis(dibenzylidene acetone) palladiumZH0006Bis-(dibenzylidene acetone) palladiumAKOS030228490bis(dibenzylideneacetone)palladium (0)

データベース識別子

CAS: 32005-36-0
PubChem CID: 154270
DTXSID: DTXSID70953892
EC Number: 608-691-6

物性

構造計算による物性

極性表面積: 34.1 Å²
水素結合供与体数: 0
水素結合受容体数: 2
回転可能結合数: 8
重原子数: 37
形式電荷: 0
複雑度: 272

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H315 (10.8%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P272, P280, P302+P352, P305+P351+P338, P321, P332+P317, P333+P317, P337+P317, P362+P364, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 37 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazard Classes and CategoriesSkin Irrit. 2 (10.8%)

毒性情報

Health EffectsContact with palladium may cause palladium sensitivity and allergy. Animal studies have shown that palladium may damage the liver and kidney. (L798)

Toxicity Summary · 1 件

Due to their ability to form strong complexes with both inorganic and organic ligands, palladium ions can disturb cellular equilibria, replace other essential ions, and interact with functional groups of macromolecules, such as proteins or DNA. Palladium complexes binding to DNA and RNA leads to strand breakage. Palladium ions are able to inhibit most major cellular functions, including DNA and RNA synthesis. Palladium compounds have been shown to bind to and inhibit various enzymes, including creatine kinase and prolyl hydroxylase. (L798)

Signs and SymptomsSkin contact with palladium may cause contact dermatitis, erythema, and oedema. (L798)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Palladium may be absorbed through oral, dermal, and inhalation exposure. Once in the body it distributes to the kidney, liver, spleen, lymph nodes, adrenal gland, lung and bone. Palladium's ability to form complexes allows it the bind to amino acids, proteins, DNA, and other macromolecules. Palladium and its metabolites are excreted in the urine and faeces. (A21)