CAS 1760-24-3 (Trimethoxysilylpropyl)ethylenediamine (HCID 15659)

概要

RN given refers to parent cpd; a silylating agent

名称と識別子

優先名称: (Trimethoxysilylpropyl)ethylenediamine
IUPAC: N'-(3-trimethoxysilylpropyl)ethane-1,2-diamine
現地名: 3-(2-アミノエチルアミノ)プロピルトリメトキシシラン
英語名: N-[3-(Trimethoxysilyl)propyl]ethylenediamine
分子式: C8H22N2O3Si
分子量: 222.36

名称と別名

en-APTASDow corning Z-6020 silane(trimethoxysilylpropyl)ethylenediamineN-(3-Trimethoxysilylpropyl)-ethylenediamineDTXSID5027433Silane, (3-(2-aminoethyl)aminopropyl)trimethoxy-28ZCS5GA8GETHYLENEDIAMINE, N-(3-(TRIMETHOXYSILYL)PROPYL)-Aminoethyl-aminopropyl-trimethoxysilaneN-(3-(Trimethoxysilyl)propyl)-1,2-ethanediamineDTXCID607433N-[3-(trimethoxysilyl)propyl]ethane-1,2-diamine

名称をさらに表示

3-(2-アミノエチルアミノ)プロピルトリメトキシシランN-(2-アミノエチル)-3-(トリメトキシシリル)プロパン-1-アミン[3-(2-アミノエチルアミノ)プロピル]トリメトキシシラン3-[(2-アミノエチル)アミノ]プロピルトリメトキシシラン6-(トリメトキシシリル)-3-アザヘキサン-1-アミンN-[3-(トリメトキシシリル)プロピル]エタン-1,2-ジアミン3-(トリメトキシシリル)-N-(2-アミノエチル)プロパン-1-アミン3-[N-(2-アミノエチル)アミノ]プロピルトリメトキシシランN-(2-アミノエチル)-3-(トリメトキシシリル)プロピルアミンN-[3-(トリメトキシシリル)プロピル]-1,2-エタンジアミンN-[3-(トリメトキシシリル)プロピル]エチレンジアミンN'-[3-(トリメトキシシリル)プロピル]エチレンジアミントリメトキシ[3-(2-アミノエチルアミノ)プロピル]シラン[3-[(2-アミノエチル)アミノ]プロピル]トリメトキシシラン(4,7-ジアザヘプタン-1-イル)トリメトキシシランN-(3-トリメトキシシリルプロピル)エチレンジアミン3-(2-アミノエチル)アミノプロピルトリメトキシシラン[3-(トリメトキシシリル)プロピル](2-アミノエチル)アミン2-[[3-(トリメトキシシリル)プロピル]アミノ]エタンアミントリメトキシ[3-[(2-アミノエチル)アミノ]プロピル]シランKH-792N-(2-AMINOETHYL)-3-AMINOPROPYLTRIMETHOXYSILANEDAMON1-(3-(TriMethoxysilyl)propyl)ethane-1,2-diaMineKH－791gf91kbm603(AMINOETHYL)-3-AMINOPROPYLTRIMETHOXY-SILANE

1,2-Ethanediamine, N1-(3-(trimethoxysilyl)propyl)-N-[3-(Trimethoxysilyl)propyl]-1,2-ethanediamine1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]-N-(3-(TRIMETHOXYSILYL)PROPYL)ETHANE-1,2-DIAMINEN-AAPTN-silaneRefChem:826123trimethoxysilylpropylethylenediaminen-(2-aminoethyl)-3-aminopropyl-trimethoxysilane

データベース識別子

CAS: 1760-24-3
PubChem CID: 15659
DTXSID: DTXSID5027433
ChEMBL: CHEMBL3188366
UNII: 28ZCS5GA8G
EC Number: 217-164-6
Nikkaji: J53.972D

物性

構造計算による物性

極性表面積: 65.7 Å²
水素結合供与体数: 2
水素結合受容体数: 5
回転可能結合数: 9
重原子数: 14
形式電荷: 0
複雑度: 125

実験および物理化学的性質

Chemical ClassesMetals -> Metalloid Compounds (Silicon)

Density1.01 @25 °C

Vapor Pressure0.03 [mmHg]

Food Contact SubstancesFCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR

Physical Description · 2 件

Liquid

Light yellow liquid; [Sigma-Aldrich MSDS]

物理化学的性質

融点: 0 °C · 0°C
沸点: 146 °C15 · 146 °C15 mm Hg(lit.)
比重(密度): 1.028 g/mL · 1.028 g/mL at 25 °C(lit.)
蒸気圧: 1.5 hPa · 1.5 hPa (20 °C)
屈折率: 20 · n20/D 1.444(lit.)
闪点: 220 °F · 220 °F
貯蔵温度: 30 °C · Store below +30°C.
溶解性: トルエンと混和する。
外見: 液体
酸解離定数(Pka): 10.11 · 10.11±0.19(Predicted)
比重: 1.01 · 1.01
色: 無色透明～薄黄色
PH: 10 · 10 (10g/l, H2O, 20℃)
水溶解度: 反応する
BRN: 636230 · 636230
InChI: 1S/C8H22N2O3Si/c1-11-14(12-2,13-3)8-4-6-10-7-5-9/h10H,4-9H2,1-3H3
InChIKey: PHQOGHDTIVQXHL-UHFFFAOYSA-N
SMILES: CO[Si](CCCNCCN)(OC)OC
LogP: -4 · -4--0.82 at 20℃
CAS データベース: 1760 · 1760-24-3(CAS DataBase Reference)
NISTの化学物質情報: N-(2-Aminoethyl-3-aminopropyl)trimethoxysilane(1760-24-3)
EPAの化学物質情報: 1 · 1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]- (1760-24-3)

化学的性質

化学的特性Colorless transparent liquid

安全と法規制

GHS分類

GHS Classification · 5 件

This chemical does not meet GHS hazard criteria for 28.7% (514 of 1791) of reports.

Danger

H302 (10.9%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P264, P264+P265, P270, P271, P272, P273, P280, P301+P317, P302+P352, P304+P340, P305+P354+P338, P317, P319, P321, P330, P332+P317, P333+P317, P362+P364, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 1791 reports by companies from 45 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 4 件

Chemical: 1,2-Ethanediamine, N-[3-(trimethoxysilyl)propyl]-

1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 05-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/15039

1,2-Ethanediamine, N-(3-(trimethoxysilyl)propyl)-: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationEvaluation - Chemicals that are unlikely to require further regulation to manage risks to environment

Hazards Summary · 1 件

Rapidly hydrolyzed; A moderate skin and severe eye irritant in rabbits; Skin sensitizing potential observed in guinea pig maximization test; No systemic toxicity, reproductive toxicity, or developmental toxicity observed in repeated-dose oral study of rats at doses up to 500 mg/kg/day; [OECD SIDS: N-(3-(Trimethoxysilyl)propyl)ethylenediamine (AEAPTMS) - 2003] May cause eye injury and skin sensitization; [ECHA REACH Registrations] Reacts with water producing methanol; An irritant that may cause serious eye injury; May cause skin sensitization; [Sigma-Aldrich MSDS] See Silane, (4-aminobutyl)diethoxymethyl-. See Methyl alcohol.

Hazard Classes and CategoriesAcute Tox. 4 (10.9%)

安全と保護具

Protective Action Criteria (PAC) · 3 件

1.6 [mg/m3]

18 [mg/m3]

110 [mg/m3]

毒性情報

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.

安全データ

F: 1-10
wgk: 3
tsca: TSCA listed
rtecs: KV7400000
ridadr: UN 3267 8/PG 2
毒性: LD50 orally in Rabbit: 2413 mg/kg LD50 dermal Rat > 2000 mg/kg
hs_code: 29310095
risk_code: 38-41-43-52/53-42/43-37/38
化審法: (2)-2083
消防法: 危-4-3-III
hazard_code: Xn,Xi
safety_code: 26-39-61-37/39-24-36/37/39-23
hazard_class: 8
packing_group: III
自然発火温度: 300 °C
Hazard Classifications: Acute Tox. 4 InhalationEye Dam. 1Skin Sens. 1BSTOT RE 2 Inhalation
ストレージクラス: 10 - Combustible liquids

化学と産業

用途と製造

Uses · 2 件

A silylating agent. [ChemIDplus] Used as a coupling agent, adhesion promoter, and crosslinker in fiberglass, adhesives, sealants, foundry resins, and coatings; [OECD SIDS: N-(3-(Trimethoxysilyl)propyl)ethylenediamine (AEAPTMS) - 2003]

Molding and Core Making [Category: Foundry]

U.S. Production2023: 1,000,000 - <2,500,000 lb

Consumer UsesAdhesion/cohesion promoter

Industry UsesPlating agent

Household ProductsInformation on 4 consumer products that contain N-(3-(Trimethoxysilyl)propyl)ethylenediamine in the following categories is provided:

General Manufacturing Information · 2 件

All Other Basic Inorganic Chemical Manufacturing

1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]-: ACTIVE

応用分野 · 1 件

使用N-[3-(Trimethoxysilyl)propyl]ethylenediamine has also been used as an organic ligand for the surface modification of silica gel to uptake heavy metal ions. It can react with fluorinated carbon nanotubes (F-CNT) to form aminoalkylalkoxysilane functionalized carbon nanotubes.