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1,3-ビス(ヒドロキシメチル)-4,5-ジヒドロキシイミダゾリジン-2-オン

Dimethyloldihydroxyethyleneurea

HCID 15824
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
1854-26-8
標準SMILES
O=C1N(CO)C(O)C(O)N1CO
InChIKey
ZEYUSQVGRCPBPG-UHFFFAOYSA-N
分子式
C5H10N2O5
平均分子量
178.14 g/mol
単同位体質量
178.05897142

概要

Dimethyloldihydroxyethyleneurea is a clear pale yellow 40% aqueous solution. (NTP, 1992)

名称と識別子

優先名称
Dimethyloldihydroxyethyleneurea
IUPAC
4,5-dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one
現地名
1,3-ビス(ヒドロキシメチル)-4,5-ジヒドロキシイミダゾリジン-2-オン
英語名
4,5-dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one
分子式
C5H10N2O5
分子量
178.1433

名称と別名

1854-26-84,5-Dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-oneArkofixDmdheuDIMETHYLOLDIHYDROXYETHYLENEUREADimethylolglyoxalureaDepremol GSumitex NSPermafresh LFPermafresh LHPermafresh LKSProtocol C
名称をさらに表示
ジメチロールグリオキサル尿素4,5-ジヒドロキシ-1,3-ビス(ヒドロキシメチル)-2-イミダゾリジノン1,3-ビス(ヒドロキシメチル)-4,5-ジヒドロキシ-2-イミダゾリノン1,3-ビス(ヒドロキシメチル)-4,5-ジヒドロキシイミダゾリジン-2-オンジメチロールジヒドロキシエチレン尿素1,3-ビス(ヒドロキシメチル)-4,5-ジヒドロキシ-2-イミダゾリドン4,5-ジヒドロキシ-1,3-ビス(ヒドロキシメチル)イミダゾリジン-2-オンN,N’ジメチロルグリオキザルモノウレイン4,5-ジヒドロキシ-1,3-ビス(2-イミダゾリジオン)Dimethylol dihydroxy ethylene urea resin2D ResinNCI-C60322Dimethylol dihydroxyethyleneurea.NNDIMETHYLOLDIHYDROXYETHYLENEUREADIMETHYLOLHYDROXYETHYLENE-UREARESINDIMETHYLOL-4,5-DIHYDROXYETHYLENEUREA
Verapret DKhCassurit LRFirmatex RKFixapret CPSarcoset GMVerapret DHFixapret CPKFixapret CPN

物性

構造計算による物性

XLogP
-1.6
極性表面積
104 Ų
水素結合供与体数
4
水素結合受容体数
5
回転可能結合数
2
重原子数
12
形式電荷
0
複雑度
169

実験および物理化学的性質

Chemical ClassesNitrogen Compounds -> Other Nitrogen Compounds
Solubilitygreater than or equal to 100 mg/mL at 68 °F (NTP, 1992)
Physical Description · 3 件

Dimethyloldihydroxyethyleneurea is a clear pale yellow 40% aqueous solution. (NTP, 1992)

Liquid

Pale yellow solution; [CAMEO]

物理化学的性質

沸点
294.32 °C · 294.32°C (rough estimate)
比重(密度)
1.5628 · 1.5628 (rough estimate)
屈折率
1.4386 · 1.4386 (estimate)
酸解離定数(Pka)
12.75 · 12.75±0.40(Predicted)
EPAの化学物質情報
Dimethyloldihydroxyethyleneurea (1854-26-8)

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 98.6% (140 of 142) of all reports.

Not Classified

Aggregated GHS information provided per 142 reports by companies from 4 notifications to the ECHA C&L Inventory.

Warning

H335: May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P271, P273, P304+P340, P319, P403+P233, P405, and P501 (click each P-code to see the statement)

危険有害性情報

Regulatory Information · 3 件

Chemical: 2-Imidazolidinone, 4,5-dihydroxy-1,3-bis(hydroxymethyl)-

2-Imidazolidinone, 4,5-dihydroxy-1,3-bis(hydroxymethyl)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Imidazolidinone, 4,5-dihydroxy-1,3-bis(hydroxymethyl)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

2-Imidazolidinone, 4,5-dihydroxy-1,3-bis(hydroxymethyl)-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Other Safety InformationEvaluation - Hydroxymethylated imidazolidinones
Fire HazardsThe flash point of this chemical has not been determined, but it is probably combustible. (NTP, 1992)
Hazards SummaryHas a very low acute toxicity and does not cause primary irritation. [eChemPortal: SIDSUNEP] Danger of skin sensitization; [MAK]
Reactive GroupAlcohols and Polyols
Reactivity Profile · 1 件

An alcohol and an amide. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides. Organic amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).

化学と産業

用途と製造

Uses · 3 件

Used in cotton or cotton-polyester blend fabrics; [ChemIDplus] Used in fabrics for wash-and-wear, crease resistance, shrinkage control, and durable finish applications; [HSDB]

Textiles (Printing, Dyeing, or Finishing) [Category: Industry]

WASH-AND-WEAR FABRICS; CREASE RESISTANCE; SHRINKAGE CONTROL; DURABLE FINISHES; BODYING AGENT /PERMAFRESH/

U.S. Production2023: 500,000 - <1,000,000 lb
Consumer UsesBinder
Industry UsesBinder
General Manufacturing Information · 3 件

Textiles, apparel, and leather manufacturing

2-Imidazolidinone, 4,5-dihydroxy-1,3-bis(hydroxymethyl)-: ACTIVE

PERMAFRESH- TRADEMARK FOR A SERIES OF RESINS USED IN THE TEXTILE INDUSTRY. THEY INCLUDE CELLULOSE REACTANTS, MELAMINE DERIVATIVES DESIGNED AS A REPLACEMENT FOR CONVENTIONAL TRIMETHYLOL MELAMINE AND RELATED PRODUCTS; PARTIALLY CONDENSED MODIFIED CARBAMIDE RESINS; CYCLIC NITROGENOUS REACTANT; BIS-KETO-TRIAZINE; METHYLOL IMIDAZOLIDONE; MODIFIED CARBAMIDE RESIN; UREA-FORMALDEHYDE LIQ; DURABLE THERMOSETTING UREA-FORMALDEHYDE REACTIVE RESIN. /PERMAFRESH/

応用分野 · 3 件

用途繊維製品仕上げ剤原料

使用Dimethyloldihydroxy ethylene urea is a formaldehyde type of textile resin for "wash and wear" colored and white fabrics and shirtings, draperies and sheeting; chlorine resistant and stiffer than carbamates also used in paper.

一般的な説明Clear pale yellow 40% aqueous solution.

上流・下流製品情報

上流原料

グリオキサールformaldehyde

関連反応

0 件
反応記録を作成

現在のフィルター条件では反応記録がありません。

化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート

データベース識別子

CAS
1854-26-8、68411-81-4
PubChem CID
15824
DTXSID
DTXSID1025140
UNII
OKU7IX3H6E
EC Number
217-451-6
Nikkaji
J40.914F
Air and Water ReactionsWater soluble.
Hazard Classes and Categories · 2 件

Not Classified

Specific target organ toxicity - Single exposure - Category 3 (Respiratory tract irritation)

安全と保護具

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 件

SMALL SPILLS AND LEAKAGE: If you should spill this chemical, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a strong soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Personal Protective Equipment (PPE) · 1 件

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter.

毒性情報

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.

安全データ

tsca
TSCA listed
化審法
一般化学物質
有毒物質データの
1854-26-8(Hazardous Substances Data)
ホルマリン
尿素

下流製品

dimethylol ethylene urea resin

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