三過塩素酸鉄(III)

Iron perchlorate

HCID 159679
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基本情報

CAS
13537-24-1
標準SMILES
[Fe+3].[O-][Cl+3]([O-])([O-])[O-].[O-][Cl+3]([O-])([O-])[O-].[O-][Cl+3]([O-])([O-])[O-]
InChIKey
LHOWRPZTCLUDOI-UHFFFAOYSA-K
分子式
Cl3FeO12
平均分子量
354.19 g/mol
単同位体質量
352.780469

名称と識別子

優先名称
Iron perchlorate
IUPAC
iron(3+) triperchlorate
現地名
三過塩素酸鉄(III)
英語名
IRON(III) PERCHLORATE HYDRATE
分子式
Cl3FeH2O13
分子量
372.21

名称と別名

Iron perchloratePerchloric acid, iron(3+) salt (3:1)Iron(3+) perchloric acid saltDTXSID50890670RefChem:148796DTXCID90103097613537-24-1Iron triperchlorateFerric perchlorateIron(III) perchlorateiron(3+);triperchloratePerchloric acid,iron(3+) salt (3:1)
名称をさらに表示
過塩素酸第二鉄三過塩素酸鉄(III)過塩素酸鉄(III)トリス過塩素酸鉄(III)過塩素酸鉄Fe(ClO4)3IRON(III) PERCHLORATE HYDRATE (PURPLE)Ferric perchlorate, GRiron(3+),triperchlorateiron perchlorate-hydratePerchloric acid,iron salt
Perchloric acid, iron(3+) saltiron(3+) triperchlorateEINECS 236-908-0SCHEMBL269886SCHEMBL30389139LHOWRPZTCLUDOI-UHFFFAOYSA-KFERRIC PERCHLORATE, HYDRATEDFERRIC PERCHLORATE, NON - YELLOW

データベース識別子

CAS
13537-24-1
PubChem CID
159679
DTXSID
DTXSID50890670
EC Number
236-908-0
Nikkaji
J43.822G

物性

構造計算による物性

極性表面積
223 Ų
水素結合供与体数
0
水素結合受容体数
12
回転可能結合数
0
重原子数
16

実験および物理化学的性質

Chemical ClassesOther Classes -> Perchlorates
Physical DescriptionYellowish odorless solid; Hygroscopic; [MSDSonline]

物理化学的性質

外見
結晶性
色
黄色
CAS データベース
13537 · 13537-24-1
EPAの化学物質情報
Perchloric acid, iron(3+) salt (13537-24-1)

化学的性質

化学的特性yellow crystal(s); hygroscopic [STR93]

化学性质鉄過塩素酸塩は通常鉄IIIイオンすなわちFe3を含む化合物であり強力な酸化剤として機能します過塩素酸イオンClO4–との結合により非常に安定した構造を持ち熱や化学的なストレスに強い特性を持っています

安全と法規制

GHS分類

GHS Classification · 5 件

This chemical does not meet GHS hazard criteria for 50% (2 of 4) of reports.

Danger

H272 (50%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 4 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory InformationPerchloric acid, iron(3+) salt: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Hazards SummaryMay cause fire on contact with combustible materials; An eye irritant; [MSDSonline] See Iron salts, soluble. See PERCHLORATES.
Hazard Classes and CategoriesOx. Sol. 2 (50%)

安全と保護具

Threshold Limit Values (TLV)1.0 [mg/m3], as Fe (soluble iron salts)
Protective Action Criteria (PAC) · 3 件

19 [mg/m3]

210 [mg/m3]

1300 [mg/m3]

毒性情報

Adverse EffectsMethemoglobinemia - The presence of increased methemoglobin in the blood; the compound is classified as secondary toxic effect

安全データ

wgk
3
tsca
TSCA listed
ridadr
UN 1481 5.1/PG 2
risk_code
8-36/37/38
hazard_code
O,Xi
safety_code
17-26-27

化学と産業

用途と製造

General Manufacturing InformationPerchloric acid, iron(3+) salt (3:1): ACTIVE
調製方法 · 2 件

製造方法This crystallizes as the pale pink decahydrate Fe(ClO4)3.10H2O from solutions of iron(III) chloride or hydrous iron(III) oxide in perchloric acid. Upon standing over phosphorus pentoxide the decahydrate becomes the hexahydrate ; a 9-hydrate crystallizes from solution above 42°. This salt has been important in the study of the hydrated Fe3+ ion since perchlorate ions have only very low coordinating ability.

純化方法Crystallise it twice from conc HClO4, the first time in the presence of a small amount of H2O2 to ensure that the iron is fully oxidised [Sullivan J Am Chem Soc 84 4256 1962]. Extreme care should be taken with this preparation because it is potentially EXPLOSIVE.

上流・下流製品情報

サプライヤー13 社

陕西缔都新材料有限公司029-63373950 17392216152 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
武汉易泰科技有限公司上海分公司18930552037 · [email protected]
上海晶抗生物工程有限公司021-54721350 13524668266 · [email protected]
北京大田丰拓化学技术有限公司13651141086 · [email protected]

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