2-ブロモビフェニル

2-Bromobiphenyl

HCID 16329

基本情報

CAS
2052-07-5
標準SMILES
Brc1ccccc1-c1ccccc1
InChIKey
KTADSLDAUJLZGL-UHFFFAOYSA-N
分子式
C12H9Br
平均分子量
233.1 g/mol
単同位体質量
231.98876239

概要

2-bromobiphenyl is a clear liquid. Insoluble in water. (NTP, 1992)

名称と識別子

優先名称
2-Bromobiphenyl
IUPAC
1-bromo-2-phenylbenzene
現地名
2-ブロモビフェニル
英語名
2-Bromobiphenyl
分子式
C12H9Br
分子量
233.1

名称と別名

2-Bromobiphenyl2-Bromo-1,1'-biphenyl1,1'-Biphenyl, 2-bromo-1-bromo-2-phenylbenzeneO-BROMOBIPHENYLBiphenyl, 2-bromo-2-BromodiphenylDTXSID0024638m-biphenyl bromide2-BIPHENYLYL BROMIDEGXS4234YXD2-biphenyl bromide
名称をさらに表示
2-ブロモビフェニル2'-ブロモビフェニル2-ビフェニリルブロミドビフェニル-2-イルブロミド2-ブロモ-1,1'-ビフェニル2-ブロモビフェニル標準液2-ブロモビフェニール2-ブロモジフェニル2‐ブロモビフェニル2‐ブロモビフェニル標準品2‐ブロモビフェニル標準液2-ブロモビフェニル (35ΜG/ML イソオクタン溶液)2-ブロモビフェニル IN ACETONE2-ブロモビフェニル, 1000 µg/mL in Acetone2-ブロモ-1,1′-ビフェニル2′-ブロモビフェニル2-ブロモビフェニル標準品PBB NO 12-Brombiphenyl2- BromobenzeneBROMOBIPHENYL(2-)
CCRIS 5888EINECS 218-141-3NSC 67353NSC-67353BROMOBIPHENYL, 2-UNII-GXS4234YXD2-PHENYLBROMOBENZENEPBB 1

データベース識別子

CAS
2052-07-5
PubChem CID
16329
DTXSID
DTXSID0024638
ChEMBL
CHEMBL1462584
UNII
GXS4234YXD
EC Number
218-141-3
Nikkaji
J95.603A

物性

構造計算による物性

XLogP
4.6
極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
0
回転可能結合数
1
重原子数
13

実験および物理化学的性質

SpringerMaterials Properties13C nuclear magnetic resonance spectrum
LogP4.59
Density1.2175 (NTP, 1992) - Denser than water; will sink
SolubilityInsoluble (NTP, 1992)
Boiling Point565 to 568 °F at 760 mmHg (NTP, 1992)
Melting Point34.7 to 35.6 °F (NTP, 1992)

物理化学的性質

融点
1.5 · 1.5-2 °C(lit.)
沸点
297 · 297-298 °C(lit.)
比重(密度)
1.352 g/mL · 1.352 g/mL at 25 °C(lit.)
屈折率
20 · n20/D 1.628(lit.)
闪点
113 °C · 113 °C
貯蔵温度
Sealed in dry,Room Temperature

安全と法規制

GHS分類

GHS Classification · 5 件

This chemical does not meet GHS hazard criteria for 6.2% (2 of 32) of reports.

Warning

H315 (93.8%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 32 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 2 件

S - indicates a substance that is identified in a final Significant New Use Rule.

Status: Active Update: 10-01-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/30357

Fire HazardsFlash point data for this chemical are not available. It is probably combustible. (NTP, 1992)
Reactive GroupAryl Halides
Reactivity Profile2-BROMOBIPHENYL is sensitive to light. Low reactivity. (NTP, 1992)
Air and Water ReactionsInsoluble in water.
Hazard Classes and CategoriesSkin Irrit. 2 (93.8%)

安全と保護具

Fire FightingFires involving this material should be controlled using a dry chemical carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 件

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Personal Protective Equipment (PPE) · 1 件

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

安全データ

wgk
3
tsca
TSCA listed
hs_code
29036990
risk_code
36/37/38-20/21/22
化審法
(4)-18
安衛法
57,57-2

化学と産業

用途と製造

General Manufacturing Information1,1'-Biphenyl, 2-bromo-: ACTIVE
応用分野 · 3 件

用途有機合成原料。

使用It is used as an intermediate of organic synthesis and pharmaceutical. It also can react with norborn-2-ene to get 5-phenyl-1,2,3,4,4a,8b-hexahydro-1,4-methanobiphenylene, in synthesis of a novel trispirocyclic hydrocarbon. It is used as a reference compound to investigate extraction efficiency of solid-phase micro extraction fibers, based on methacrylic acid-trimethylolpropanetrimethacrylate copolymers.

一般的な説明Clear liquid. Insoluble in water.

サプライヤー100 社

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
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