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硫酸パラジウム(II)

Sulfuric acid, palladium(2+) salt (1:1)

HCID 166846
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
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基本情報

CAS
13566-03-5
標準SMILES
O=S(=O)([O-])[O-].[Pd+2]
InChIKey
RFLFDJSIZCCYIP-UHFFFAOYSA-L
分子式
O4PdS
平均分子量
202.49 g/mol
単同位体質量
201.85521

概要

Palladium(II) sulfate is a sulfate of palladium. Palladium is a chemical element with the chemical symbol Pd and an atomic number of 46. It is found as a free metal alloyed with gold and other platinum group metals and in the rare minerals cooperite and polarite. (L794)

名称と識別子

優先名称
Sulfuric acid, palladium(2+) salt (1:1)
IUPAC
palladium(2+) sulfate
現地名
硫酸パラジウム(II)
英語名
Palladium(II) sulfate
分子式
O4PdS
分子量
202.48

名称と別名

13566-03-5Palladium(2+) sulfatePalladium sulphatePalladium monosulfatePalladium sulfate (PdSO4)Sulfuric acid, palladium(2+) salt (1:1)DTXSID30884517EINECS 236-957-8RefChem:889914DTXCID501023953236-957-8Palladium(II) sulfate
名称をさらに表示
硫酸パラジウム(II)硫酸パラジウム(Ⅱ)無水硫酸パラジウム(II) SOLUTION硫酸パラジウム(II)二水和物1,3-ジオキサ-2λ6-チア-4-パラダシクロブタン-2,2-ジオンDichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II)palladium(ii) sulfate, solutionadium(II) suLPALLADOUSSULPHATEPalladium(Ⅱ) sulfatePalladium(II) Sufate
Palladium sulfatePalladous sulfatepalladium(2+);sulfateSulfuric acid, palladium saltMFCD00011173Palladium( cento) sulfate22723-63-3Q4445811

データベース識別子

CAS
13566-03-5、22723-63-3

物性

構造計算による物性

極性表面積
88.6 Ų
水素結合供与体数
0
水素結合受容体数
4
回転可能結合数
0
重原子数
6
形式電荷
0
複雑度
62.2

物理化学的性質

沸点
330 ℃ · 330℃(lit.)
比重(密度)
3.24 · 3.24[at 20℃]
貯蔵温度
Inert atmosphere,Room Temperature
外見
結晶
色
茶色
水溶解度
水と完全に混和します。
主な用途
PEM燃料電池均一触媒材料合成前駆体
InChI
InChI=1S/H2O4S.Pd/c1-5(2,3)4;/h(H2,1,2,3,4);/q;+2/p-2
InChIKey
RFLFDJSIZCCYIP-UHFFFAOYSA-L
SMILES
S([O-])([O-])(=O)=O.[Pd+2]
CAS データベース
13566 · 13566-03-5(CAS DataBase Reference)
EPAの化学物質情報
Sulfuric acid, palladium(2+) salt (1:1) (13566-03-5)

化学的性質

化学的特性brown crystal(s) [STR93]

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 4 件

Danger

H290 (23.3%): May be corrosive to metals [Warning Corrosive to Metals]

P234, P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P390, P391, P405, P406, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 129 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 3 件

Chemical: Sulfuric acid, palladium(2+) salt (1:1)

REACH registered substance: Palladium sulphate (EC: 236-957-8)

Sulfuric acid, palladium(2+) salt (1:1): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Other Safety InformationIMAP assessments - Sulfuric acid, palladium(2+) salt (1:1): Environment tier I assessment
Hazard Classes and CategoriesMet. Corr. 1 (23.3%)

毒性情報

Treatment · 1 件

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Palladium may be absorbed through oral, dermal, and inhalation exposure. Once in the body it distributes to the kidney, liver, spleen, lymph nodes, adrenal gland, lung and bone. Palladium's ability to form complexes allows it the bind to amino acids, proteins, DNA, and other macromolecules. Palladium and its metabolites are excreted in the urine and faeces. (A21)

用途と製造

General Manufacturing InformationSulfuric acid, palladium(2+) salt (1:1): ACTIVE

応用分野

使用Palladium(II) sulfate is used as a catalyst in chemical synthesis.Palladium(II) sulfate was used with a phosphomolybdovanadic acid to convert 1-butene (R = C2H5) to 2-butanone with more than 95% selectivity at 98% conversion.

サプライヤー100 社

北京华美互利生物化工010-56205725 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
河南多贝化工有限公司0370-6999054 17550096163 · [email protected]
上海腾准生物科技有限公司19821570922 · [email protected]
上海毕得医药科技股份有限公司400-1647117 13681763483 · [email protected]
清宁生物(江苏博泉生物科技有限公司)王 19352250998 13160238781 · [email protected]

関連反応

0 件
反応記録を作成

現在のフィルター条件では反応記録がありません。

化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
PubChem CID
166846
DTXSID
DTXSID30884517
EC Number
236-957-8
Nikkaji
J241.188A
Health Effects
Contact with palladium may cause palladium sensitivity and allergy. Animal studies have shown that palladium may damage the liver and kidney. (L798)
Toxicity Summary · 1 件

Due to their ability to form strong complexes with both inorganic and organic ligands, palladium ions can disturb cellular equilibria, replace other essential ions, and interact with functional groups of macromolecules, such as proteins or DNA. Palladium complexes binding to DNA and RNA leads to strand breakage. Palladium ions are able to inhibit most major cellular functions, including DNA and RNA synthesis. Palladium compounds have been shown to bind to and inhibit various enzymes, including creatine kinase and prolyl hydroxylase. (L798)

Signs and SymptomsSkin contact with palladium may cause contact dermatitis, erythema, and oedema. (L798)
Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

安全データ

wgk
3
tsca
TSCA listed
ridadr
UN 3260 8/PG 2
risk_code
34
hazard_code
C
safety_code
22-26-36/37/39-45
hazard_class
8
Hazard Classifications
Eye Dam. 1Met. Corr. 1Skin Corr. 1B
ストレージクラス
8A - Combustible corrosive hazardous materials
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