CAS 2495-37-6 Benzyl methacrylate (HCID 17236)

名称と識別子

優先名称: Benzyl methacrylate
IUPAC: benzyl 2-methylprop-2-enoate
現地名: メタクリル酸ベンジル
英語名: Benzyl methacrylate
分子式: C11H12O2
分子量: 176.21

名称と別名

BENZYL METHACRYLATE2495-37-62-Propenoic acid, 2-methyl-, phenylmethyl esterDTXSID0022193Z3248K2SSMNSC-20970DTXCID302193RefChem:566762219-674-4benzyl 2-methylprop-2-enoatebenzylmethacrylateMethacrylic acid benzyl ester

名称をさらに表示

メタクリル酸ベンジル2-メチルプロペン酸ベンジルベンジルメタクリラートベンジル=メタクリラート2-メチルアクリル酸ベンジルベンジルメタクリレートベンジルメタクリレ-トメタクリル酸ベンジル, 98%, STAB. WITH CA 50-100PPM 4-METHOXYPHENOLBZMABenzylmethacrylatMethacrylic acid benzylBENZYLMETHACRAYLATEBenzyl 2-methylacrylateCHLUMICRYI BZMA MonomerBenzyl methacrylate ,98%

phenylmethyl 2-methylprop-2-enoateMethacrylic acid, benzyl ester25085-83-0EINECS 219-674-4UNII-Z3248K2SSMMFCD00053684NSC 20970Benzyl methacrylate, 98%

データベース識別子

CAS: 2495-37-6
PubChem CID: 17236
DTXSID: DTXSID0022193
ChEMBL: CHEMBL3187485
UNII: Z3248K2SSM
EC Number: 219-674-4
Nikkaji: J60.239F

物性

構造計算による物性

XLogP: 2.9
極性表面積: 26.3 Å²
水素結合供与体数: 0
水素結合受容体数: 2
回転可能結合数: 4
重原子数: 13
形式電荷: 0
複雑度: 190

実験および物理化学的性質

SpringerMaterials PropertiesBoiling point

Physical DescriptionLiquid

物理化学的性質

融点: 25 °C · <25 °C
沸点: 95 · 95-98 °C/4 mmHg (lit.)
比重(密度): 1.04 g/mL · 1.04 g/mL at 25 °C (lit.)
蒸気圧: 3 Pa · 3Pa at 20℃
屈折率: 20 · n20/D 1.512(lit.)
闪点: 225 °F · 225 °F
貯蔵温度: 2 · 2-8°C(protect from light)
外見: clear liquid
色: Colorless
水溶解度: 水に不溶。
BRN: 2045924 · 2045924
安定性: 安定。可燃性。フリーラジカル開始剤、酸化剤、還元剤とは相容れない。高温を避けてください。光に敏感。
化粧品成分の機能: フィルム形成
InChI: 1S/C11H12O2/c1-9(2)11(12)13-8-10-6-4-3-5-7-10/h3-7H,1,8H2,2H3
InChIKey: AOJOEFVRHOZDFN-UHFFFAOYSA-N
SMILES: CC(=C)C(=O)OCc1ccccc1
LogP: 3.1 at · 3.1 at 20℃
CAS データベース: 2495 · 2495-37-6(CAS DataBase Reference)
NISTの化学物質情報: Benzyl methacrylate(2495-37-6)
EPAの化学物質情報: 2 · 2-Propenoic acid, 2-methyl-, phenylmethyl ester (2495-37-6)

化学的性質

化学的特性Colorless oily liquid. Very slightly soluble in water, soluble in alcohol and oils. Soft, warm, herbaceous-rosy odor of moderate tenacity.

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H315 (91.1%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P272, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 313 reports by companies from 19 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 4 件

Chemical: 2-Propenoic acid, 2-methyl-, phenylmethyl ester

2-Propenoic acid, 2-methyl-, phenylmethyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 2-Propenoic acid, 2-methyl-, phenylmethyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 20-05-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/10958

Benzyl methacrylate: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazard Classes and CategoriesSkin Irrit. 2 (91.1%)

安全データ

wgk: 1
tsca: TSCA listed
hs_code: 29163990
risk_code: 36/37/38
化審法: (3)-1017, (3)-1047
消防法: 危-4-3-III
hazard_code: Xi
safety_code: 26
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3
ストレージクラス: 10 - Combustible liquids

化学と産業

用途と製造

U.S. Production2023: 700,000 - <850,000 lb

Industry UsesAdhesion/cohesion promoter

General Manufacturing Information · 2 件

Adhesive Manufacturing

2-Propenoic acid, 2-methyl-, phenylmethyl ester: ACTIVE

応用分野 · 2 件

説明The cyclic methacrylate monomer benzyl methacrylate (BzMA) was evaluated as an alternative to traditional methyl methacrylate (MMA) as a hard monomer in the application of an acrylate latex pressure-sensitive adhesive (PSA). BzMA is widely used in nanoimprinting lithography, paint applications, inkjet inks, transparent adhesives, orthodontic adhesive compositions, and stationary phases in liquid chromatography[1].

使用Benzyl methacrylate is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.