基本情報
- CAS
2580-56-5- 標準SMILES
CN(C)c1ccc(C(=C2C=CC(=[NH+]c3ccccc3)c3ccccc32)c2ccc(N(C)C)cc2)cc1.[Cl-]- InChIKey
LLWJPGAKXJBKKA-UHFFFAOYSA-N- 分子式
- C33H32N3.Cl
- 平均分子量
- 506.1 g/mol
- 単同位体質量
- 505.2284757
概要
Victoria blue B is an iminium salt composed of 4-{(4-anilinonaphthalen-1-yl)[4-(dimethylamino)phenyl]methylidene}-N,N-dimethylcyclohexa-2,5-dien-1-iminium and chloride ions in a 1:1 ratio. It binds to nucleic acids and can be used in standardised staining techniques suitable for automated cell-pattern recognition. It has a role as a fluorochrome and a histological dye. It is an iminium salt and an organic chloride salt. It contains a victoria blue B(1+).
名称と識別子
- 優先名称
- Victoria Blue B
- IUPAC
- [4-[bis[4-(dimethylamino)phenyl]methylidene]naphthalen-1-ylidene]-phenylazanium chloride
- 現地名
- ベーシック ブルー 26
- 英語名
- Basic Blue 26
- 分子式
- C33H32ClN3
- 分子量
- 506.09
名称と別名
Basic blue 26Victoria blue B2580-56-5Calcozine Blue BC.I. BASIC BLUE 26C.I. 44045CI 44045Z1V8UTB56CDTXSID0038889COVARIANE BLEU W 6129NSC-11245LOWACRYL BLUE 26
名称をさらに表示
ベーシック ブルー 26ビクトリアブルーFBC.I.ベーシックブルー26ビクトリアブルーBベーシックブルー26N-[4-[[4-(ジメチルアミノ)フェニル][4-(フェニルアミノ)-1-ナフタレニル]メチレン]-2,5-シクロヘキサジエン-1-イリデン]-N-メチルメタンアミニウム·クロリドN-[4-[[4-(ジメチルアミノ)フェニル][4-(フェニルアミノ)-1-ナフチル]メチレン]シクロヘキサン-2,5-ジエン-1-イリデン]-N-メチルメタンアミニウム·クロリドビクトリアブルージメチル（4-｛（4-アニリノ-1-ナフチル）［4-（ジメチルアミノ）フェニル］メチリデン｝シクロヘキサ-2，5-ジエン-1-イリデン）アンモニウム＝クロリド塩基性青26ビクトリアブル-B[4-[[4-anilino-1-naphthyl][4-(dimethylamino)phenyl]methylene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium chlorideHectoBlueBVictoriaBACI NO 44045BASIC BLUE BBVictoria blCorn blue BN
CHEBI:87651Methanaminium, N-(4-((4-(dimethylamino)phenyl)(4-(phenylamino)-1-naphthalenyl)methylene)-2,5-cyclohexadien-1-ylidene)-N-methyl-, chlorideMethanaminium, N-[4-[[4-(dimethylamino)phenyl][4-(phenylamino)-1-naphthalenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-methyl-, chlorideRefChem:934023DTXCID8018889219-943-64-(alpha-(4-anilino-1-naphthyl)-p-dimethylamino)benzylidene-2,5-cyclohexadien-1-ylidenedimethyl ammonium chlorideN-(4-((4-(Dimethylamino)phenyl)(4-(phenylamino)-1-naphthalenyl)methylene)-2,5-cyclohexadien-1-ylidene)-N-methylmethanaminium, chloride
データベース識別子
- CAS
2580-56-5- PubChem CID
- 17407
- DTXSID
DTXSID0038889- ChEBI
CHEBI:87651- UNII
- Z1V8UTB56C
- EC Number
- 219-943-6
物性
構造計算による物性
- 極性表面積
- 20.5 Ų
- 水素結合供与体数
- 1
- 水素結合受容体数
- 3
- 回転可能結合数
- 5
- 重原子数
- 37
- 形式電荷
- 0
- 複雑度
- 769
実験および物理化学的性質
CosmeticsCosmetic colorant; Hair dyeing
Physical DescriptionLiquid
物理化学的性質
- 融点
- 206 °C · 206 °C (dec.)(lit.)
- 比重(密度)
- 1.336 · 1.336[at 20℃]
- 溶解性
- DMSO (Slightly), Methanol (Slightly), Water (Slightly)
- 外見
- 粉
- 色
- ダークブラウン
- 水溶解度
- 熱湯に溶ける
- BRN
- 4094258 · 4094258
- 安定性
- Hygroscopic, Light Sensitive
- 化粧品成分の機能
- ヘアカラーリング着色剤
- InChI
- InChI=1S/C33H31N3.ClH/c1-35(2)27-18-14-24(15-19-27)33(25-16-20-28(21-17-25)36(3)4)31-22-23-32(30-13-9-8-12-29(30)31)34-26-10-6-5-7-11-26;/h5-23H,1-4H3;1H
- InChIKey
- LLWJPGAKXJBKKA-UHFFFAOYSA-N
- SMILES
- C(=C1C=C/C(=[N+](/C)\C)/C=C1)(C1C=CC(N(C)C)=CC=1)C1=CC=C(NC2C=CC=CC=2)C2=CC=CC=C12.[Cl-]
- LogP
- 0.929 at · 0.929 at 20℃
- CAS データベース
- 2580 · 2580-56-5(CAS DataBase Reference)
- EPAの化学物質情報
- 4 · Methanaminium, N-[4-[[4-(dimethylamino)phenyl][4-(phenylamino)-1-naphthalenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-methyl-, chloride (2580-56-5)
化学的性質
化学的特性Basic Blue 26 is bright brown powder
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
This chemical does not meet GHS hazard criteria for 10.2% (27 of 264) of reports.
Danger
H302 (84.8%): Harmful if swallowed [Warning Acute toxicity, oral]
P261, P264, P264+P265, P270, P272, P273, P280, P301+P317, P302+P352, P305+P351+P338, P305+P354+P338, P317, P321, P330, P333+P317, P337+P317, P362+P364, P391, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 264 reports by companies from 17 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Not Classified
危険有害性情報
Regulatory Information
Chemical: Methanaminium, N-[4-[[4-(dimethylamino)phenyl][4-(phenylamino)-1-naphthalenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-methyl-, chloride
Methanaminium, N-[4-[[4-(dimethylamino)phenyl][4-(phenylamino)-1-naphthalenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-methyl-, chloride (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Methanaminium, N-[4-[[4-(dimethylamino)phenyl][4-(phenylamino)-1-naphthalenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-methyl-, chloride (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
REACH registered substance: [4-[[4-anilino-1-naphthyl][4-(dimethylamino)phenyl]methylene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium chloride (EC: 219-943-6)
Substance: [4-[[4-anilino-1-naphthyl][4-(dimethylamino)phenyl]methylene]cyclohexa-2,5-dien-1-ylidene] dimethylammonium chloride (C.I. Basic Blue 26)
Methanaminium, N-[4-[[4-(dimethylamino)phenyl][4-(phenylamino)-1-naphthalenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-methyl-, chloride: Does not have an individual approval but may be used under an appropriate group standard
Other Safety InformationIMAP assessments - Crystal violet and related dyes: Human health tier II assessment
Hazard Classes and Categories
Acute Tox. 4 (84.8%)
Acute toxicity - category 3
安全データ
- wgk
- 3
- tsca
- TSCA listed
- ridadr
- UN 3077 9 / PGIII
- hs_code
- 32129000
- risk_code
- 22-36
- 化審法
- (5)-1998
- hazard_code
- Xn
- safety_code
- 26
- Hazard Classifications
- Acute Tox. 4 OralAquatic Acute 1Aquatic Chronic 1Eye Dam. 1Skin Corr. 1Skin Sens. 1
- ストレージクラス
- 8B - Non-combustible corrosive hazardous materials
化学と産業
用途と製造
U.S. Production2023: <50,000 lb
Consumer UsesDye
Industry UsesDye
Use ClassificationCosmetics -> Cosmetic colorant; Hair dyeing
General Manufacturing Information
Synthetic Dye and Pigment Manufacturing
Methanaminium, N-[4-[[4-(dimethylamino)phenyl][4-(phenylamino)-1-naphthalenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-methyl-, chloride (1:1): ACTIVE
応用分野
用途繊維及び紙の染色。
用途インク、クリーナー、コーティングの製造用染料
使用Basic Blue 26 used in the quantitative determination of phospholipids and as a nuclear stain in cytology/histochemical applications.
調製方法
製造方法(a) 4-(Dichloro(4-(diethylamino)phenyl)methyl)-N,N-diethylbenzenamine and Naphthalen-1-amine condensation; (b) Bis (4 – (dimethylamino) phenyl) methanol and Naphthalen-1-amine condensation, the product into N-and the nitro derivatives, and then oxidation, remove the nitro.
上流・下流製品情報
上流原料
サプライヤー100 社
国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Shandong chuangyingchemical Co., Ltd.18853181302 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]
Career Henan Chemica Co+86-0371-86658258 +86-13203830695 · [email protected]
上海康朗生物科技有限公司021-61998208 18217752821 · [email protected]
无锡市凯立生物科技有限公司0510-80721533 13327925606 · [email protected]
爱斯特（成都）生物制药股份有限公司+86-28-85122536 85324413 · [email protected]
Baoji Guokang Healthchem co.,ltd+8615604608665 15604608665 · [email protected]
上海如吉生物科技发展有限公司+86-21-65211385-8001 36031160 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
上海弘顺生物科技有限公司15901914505 · [email protected]
科瑞迪化学400-821-5857 021-64326257 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
武汉易泰科技有限公司上海分公司18930552037 · [email protected]
上海晶抗生物工程有限公司021-54721350 13524668266 · [email protected]
大连美仑生物技术有限公司0411-62910999 13889544652 · [email protected]
安耐吉化学&3A（安徽泽升科技股份有限公司）400-0056266 · [email protected]
山东洛克化工有限公司17653113209 13065062079 · [email protected]
上海钰康生物科技有限公司+86-18930848214 +86-021-56762820 · [email protected]
湖北广奥生物科技有限公司027-02702759223056 18162699093 · [email protected]
伊势久（江苏连云港）生物科技有限责任公司18082049515 · [email protected]
玛雅试剂+86 (573) 82222445 (0)18006601000 452520369 · [email protected]
四川库利南科技有限公司400-1166-196 18981987031 · [email protected]
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衡水昊业科技有限公司0318-2012300 +86-18632882519 · [email protected]
斯百全化学（上海）有限公司021-021-021-67601398-809-809-809 15221380277 · [email protected]
上海源叶生物科技有限公司18916372613 · [email protected]
上海思域化工科技有限公司86-21-34053660 · [email protected]
赛默飞世尔科技（中国）有限公司800-810-5118 · [email protected]
南京杜莱生物技术有限公司025-84699383-8003;025-846993838003-8003 18013301590 · [email protected]
南京生利德生物科技有限公司025-57798810 18652991625 · [email protected]
上海倍卓生物科技有限公司021-61119791,13386096464 · [email protected]
上海将来实业股份有限公司021-61552785 · [email protected]
成都零六生物科技有限公司400-1166-196 13458535857 · [email protected]
上海麦克林生化科技股份有限公司15221275939 15221275939 · [email protected]
成都润泽本土化工有限公司13096311329 028-88469284 616445927 · [email protected]
湖北巨胜科技有限公司027-59599241 18871490274 · [email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
桦特昇生物科技（武汉）有限公司027-59207879 1972026995 18140587686 · [email protected]
天津阿尔塔科技有限公司022-6537-8550 15522853686 · [email protected]
Alfa Chemistry1-516-6625404 · [email protected]
北京诺其雅盛生物科技有限公司4000-819-385 010-62329685 13718666987
九鼎化学（上海）科技有限公司4009209199 · [email protected]
Henan Alfa Chemical Co., Ltd+8618339805032 · [email protected]
泰安嘉岳生物化工有限公司15318151873 · [email protected]
广东翁江化学试剂有限公司0751-2886766 13927870850 · [email protected]
山东智尚新材料有限公司+8617653113209 · [email protected]
補足説明
定義本品は、次の化学式で表されるトリアリルメタン系頭髪用色素である。
定義ChEBI: Victoria blue B is an iminium salt composed of 4-{(4-anilinonaphthalen-1-yl)[4-(dimethylamino)phenyl]methylidene}-N,N-dimethylcyclohexa-2,5-dien-1-iminium and chloride ions in a 1:1 ratio. It binds to nucleic acids and can be used in standardised staining techniques suitable for automated cell-pattern recognition. It has a role as a histological dye and a fluorochrome. It is an iminium salt and an organic chloride salt. It contains a victoria blue B(1+).
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