N,N-Diethylethanamine trihydrofluoride (HCID 175505)

概要

See also: Triethylammonium fluoride (annotation moved to).

名称と識別子

優先名称: N,N-Diethylethanamine trihydrofluoride
IUPAC: N,N-diethylethanamine;trihydrofluoride
現地名: トリエチルアミン三フッ化水素酸塩
英語名: Triethylamine trihydrofluoride
分子式: C6H18F3N
分子量: 161.21

名称と別名

Triethylamine trihydrofluorideN,N-Diethylethanamine trihydrofluoridetriethylamine trishydrofluorideEINECS 277-550-5DTXSID2074372Ethanamine, N,N-diethyl-, hydrofluoride (1:3)RefChem:822328DTXCID7047568Ethanamine, N,Ndiethyl, trihydrofluorideEthanamine, N,Ndiethyl, hydrofluoride (1:3)UN179073602-61-6

名称をさらに表示

トリエチルアミン三フッ化水素酸塩トリエチルアミン·3ヒドリドふっ素トリエチルアミン·3ふっ化水素トリエチルアミン=三フッ化水素酸塩N,N-ジエチルエタンアミン·3ふっ化水素酸塩トリエチルアミン·三ふっ化水素酸塩トリエチルアミン·三フッ酸トリエチルアミン·三フッ酸塩トリエチルアミン-トリス(ふっ化水素)ふっ化水素,37%トリエチルアミン溶液三ふっ化水素トリエチルアミントリエチルアミン三ふっ化水素塩トリエチルアミントリハイドロフルオリドトリエチルアミン三フッ化水素酸塩トリエチルアミン・三ふっ化水素酸塩トリエチルアミン・3ヒドリドふっ素トリエチルアミン三フッ化水素N,N-ジエチルエタンアミン・3ふっ化水素酸塩トリエチルアミン・3ふっ化水素HFTEA.3HFTRIETHYLAMINE TRIS(HYDROGEN FLUORIDE)Triethylamine trihydroflourideTREAT-HFtrihydrofluorideTriethylamine trihydriethylamine trihydrofluorideHYDROGEN FLUORIDE TRIETHYLAMINE

Ethanamine, N,N-diethyl-, trihydrofluorideN,N-diethylethanamine;trihydrofluorideMFCD00043294hydrogen fluoride in triethylaminehf 37% in triethylamineC6H18F3NTREAT HFZX9Z7YP3AB

データベース識別子

CAS: 73602-61-6
PubChem CID: 175505
DTXSID: DTXSID2074372
UNII: ZX9Z7YP3AB

物性

構造計算による物性

極性表面積: 3.2 Å²
水素結合供与体数: 3
水素結合受容体数: 4
回転可能結合数: 3
重原子数: 10
形式電荷: 0
複雑度: 25.7

実験および物理化学的性質

Chemical ClassesNitrogen Compounds -> Other Nitrogen Compounds

Physical DescriptionColorless liquid with a pungent odor; Hygroscopic; [Alfa Aesar MSDS]

物理化学的性質

融点: -29 · -29--27°C
沸点: 70 °C15 · 70 °C15 mm Hg(lit.)
比重(密度): 0.989 g/mL · 0.989 g/mL at 25 °C(lit.)
屈折率: 20 · n20/D 1.3915(lit.)
闪点: 190 °F · 190 °F
貯蔵温度: 30 °C · Store below +30°C.
溶解性: soluble in Chloroform, Hexane
外見: 液体
比重: 0.989 · 0.989
色: クリアイエロー～ブラウン
PH: 3 · 3 (H2O, 20℃)(saturated aqueous solution)
水溶解度: 溶ける
BRN: 5522945 · 5522945
InChI: 1S/C6H15N.3FH/c1-4-7(5-2)6-3;;;/h4-6H2,1-3H3;3*1H
InChIKey: IKGLACJFEHSFNN-UHFFFAOYSA-N
SMILES: F[H].F[H].F[H].CCN(CC)CC
CAS データベース: 73602 · 73602-61-6(CAS DataBase Reference)
EPAの化学物質情報: Ethanamine, N,N-diethyl-, trihydrofluoride (73602-61-6)

化学的性質

化学的特性clear yellow liquid

安全と法規制

危険有害性情報

Regulatory Information · 2 件

PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Triethylamine trishydrofluoride: HSNO Approval: HSR006811 Approved with controls

Hazards SummaryCauses burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; Highly toxic by ingestion, inhalation, and skin absorption; [Alfa Aesar MSDS] See Hydrogen fluoride. See Triethylamine hydrochloride.

毒性情報

Adverse EffectsDermatotoxin - Skin burns.

安全データ

wgk: 3
tsca: TSCA listed
ridadr: UN 3265 8/PG 2
PRTR法: 第一種指定化学物質
hs_code: 29211910
risk_code: 26/27/28-35-36/37/38-20/21/22-11
化審法: 優先評価化学物質
hazard_code: T+,T,C,Xi,F
hazard_note: Corrosive
safety_code: 26-36/37/39-45-7/9-36/37-36-61-29-16-3
hazard_class: 8
packing_group: II
毒劇物取締法: 毒物
Hazard Classifications: Acute Tox. 1 DermalAcute Tox. 2 InhalationAcute Tox. 2 OralEye Dam. 1Skin Corr. 1A
ストレージクラス: 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials

化学と産業

用途と製造

General Manufacturing InformationEthanamine, N,N-diethyl-, hydrofluoride (1:3): ACTIVE

応用分野 · 2 件

使用Triethylamine trihydrofluoride acts as a mild and selective fluorinating agent used in the synthesis of acid fluorides and alkyl fluorides. It is also used in the synthesis of vicinal difluorides from epoxides, 3-fluoroazetidine. It is utilized as a selective reagent for the cleavage of O-silyl groups in carbohydrates, nucleotides and cyanohydrins. It is actively involved in the electrochemical fluorodeiodination of alkyl iodides and fluorodesilylation in beta-lactams.

一般的な説明Triethylamine trihydrofluoride (TREAT-HF) is a mild and selective reagent for the fluorination of a wide variety of compounds.