テトラブチルアンモニウムジフルオロトリフェニルすず

1-Butanaminium, N,N,N-tributyl-, (TB-5-11)-difluorotriphenylstannate(1-) (1:1)

HCID 178449042

ノート反応

部分構造検索類似構造を探す

基本情報

CAS: 139353-88-1
標準SMILES: CCCC[N+](CCCC)(CCCC)CCCC.[F-].[F-].[Sn+].[c]1ccccc1.[c]1ccccc1.[c]1ccccc1
InChIKey: ODMXVCNGZGLSRS-UHFFFAOYSA-L
分子式: C34H51F2NSn
平均分子量: 630.5 g/mol
単同位体質量: 631.30116

名称と識別子

優先名称: 1-Butanaminium, N,N,N-tributyl-, (TB-5-11)-difluorotriphenylstannate(1-) (1:1)
IUPAC: difluoro(triphenyl)stannanuide;tetrabutylazanium
現地名: テトラブチルアンモニウムジフルオロトリフェニルすず
英語名: Tetrabutylammonium difluorotriphenylstannate
分子式: C34H51F2NSn
分子量: 630.48

名称と別名

1-Butanaminium, N,N,N-tributyl-, (TB-5-11)-difluorotriphenylstannate(1-) (1:1)RefChem:430811623-960-8139353-88-1Tetrabutylammonium difluorotriphenylstannateTetrabutylammonium difluorotriphenylstannate(IV)difluoro(triphenyl)stannanuide;tetrabutylazaniumMFCD00192465Tetrabutylammonium difluorotriphenyltinDTXSID00369785ODMXVCNGZGLSRS-UHFFFAOYSA-Ltetrabutylammonium triphenyldifluorotin

名称をさらに表示

テトラブチルアンモニウムジフルオロトリフェニルすずジフルオロトリフェニルすず酸テトラブチルアンモニウムジフルオロトリフェニルスズテトラブチルアンモニウムｼﾞﾌﾙｵﾛﾄﾘﾌｪﾆﾙ錫酸ﾃﾄﾗﾌﾞﾁﾙｱﾝﾓﾆｳﾑTBAF-SNSKL1127Gingras'GINGRAS REAGENTTetrabutylammonium difluorotriphenylstaateTetrabutylammonium difluorotriphenylstannaneTETRABUTYLAMMONIUM TRIPHENYLDIFLUOROSTANNATE

AKOS015912125SY109499DB-042468tetrabutylam-monium triphenyldifluorostannatetetrabutylammonium difluorotriphenyl stannateTetrabutylammonium (difluorotriphenylstannate)tetra-n-butylammonium difluorotriphenylstannateTetrabutylammoniumdifluorotriphenylstannate(IV)

データベース識別子

CAS: 139353-88-1
PubChem CID: 2733194

物性

構造計算による物性

極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 3
回転可能結合数: 15
重原子数: 38
形式電荷: 0
複雑度: 401

物理化学的性質

融点: 192 · 192-193 °C (lit.)
溶解性: ほとんどの有機溶剤に溶けます。
外見: 個体
色: White to Almost white
BRN: 8668854 · 8668854
InChI: 1S/C16H36N.3C6H5.2FH.Sn/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;3*1-2-4-6-5-3-1;;;/h5-16H2,1-4H3;3*1-5H;2*1H;/q+1;;;;;;+1/p-2
InChIKey: ODMXVCNGZGLSRS-UHFFFAOYSA-L
SMILES: CCCC[N+](CCCC)(CCCC)CCCC.F[Sn-](F)(c1ccccc1)(c2ccccc2)c3ccccc3
CAS データベース: 139353 · 139353-88-1(CAS DataBase Reference)

化学的性質

化学的特性White crystalline powder

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H301 (88.9%): Toxic if swallowed [Danger Acute toxicity, oral]；H311 (88.9%): Toxic in contact with skin [Danger Acute toxicity, dermal]；H331 (88.9%): Toxic if inhaled [Danger Acute toxicity, inhalation]；H400 (97.8%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]；H410 (97.8%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

P261, P262, P264, P270, P271, P273, P280, P301+P316, P302+P352, P304+P340, P316, P321, P330, P361+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 45 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Hazard Classes and CategoriesAcute Tox. 3 (88.9%)；Acute Tox. 3 (88.9%)；Acute Tox. 3 (88.9%)；Aquatic Acute 1 (97.8%)；Aquatic Chronic 1 (97.8%)

安全データ

F: 9-21
wgk: 3
tsca: No
ridadr: UN 3146 6.1/PG 3
PRTR法: 第一種指定化学物質
hs_code: 29310099
risk_code: 23/24/25-50/53
安衛法: 57,57-2
hazard_code: T,N,Xi
safety_code: 26-27-28-45-60-61
hazard_class: 6.1
packing_group: III
毒劇物取締法: 劇物
Hazard Classifications: Acute Tox. 3 DermalAcute Tox. 3 InhalationAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1
ストレージクラス: 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects

化学と産業

応用分野 · 1 件

使用Tetrabutylammonium difluorotriphenylstannate is an organometallic reagent used in the preparation of disilene fluoride adducts. Tetrabutylammonium difluorotriphenylstannate has inorganic applications as well, used as a source of carbon or fluorine ligands via hypercoordination.