1,2-Epoxydodecane (HCID 17858)

概要

1,2-epoxydodecane is a clear colorless liquid. (NTP, 1992)

名称と識別子

優先名称: 1,2-Epoxydodecane
IUPAC: 2-decyloxirane
現地名: 1,2-エポキシドデカン
英語名: 1,2-Epoxydodecane
分子式: C12H24O
分子量: 184.32

名称と別名

1,2-EPOXYDODECANE2855-19-81-Dodecene oxideOxirane, decyl-Decyloxirane1,2-Dodecene oxideDecyl oxiraneDodecene epoxideDodecane, 1,2-epoxy-Nedox 12001,2-Dodecane oxide1,2-Epoxy-n-dodecene

名称をさらに表示

1,2-エポキシドデカンデシルオキシランビコロックス121,2-ドデセンオキシドネドックス12002-デシルオキシラン1,2-ドデシレンオキシド1-ドデセンエポキシド2-DecyloxiraneEDD1-DODECENE EPOXIDEDD5EDD1hHYDnedox1200Vikolox-12

1,2-Epoxy-N-dodecane1,2-Epoxydodekanalpha-Dodecene oxideNSC 6785CCRIS 2616DTXSID9025243HSDB 5538EINECS 220-667-3

データベース識別子

CAS: 2855-19-8
PubChem CID: 17858
DTXSID: DTXSID9025243
ChEMBL: CHEMBL3183029
UNII: 736974CF3U
EC Number: 220-667-3
Nikkaji: J13.742A

物性

構造計算による物性

XLogP: 5.2
極性表面積: 12.5 Å²
水素結合供与体数: 0
水素結合受容体数: 1
回転可能結合数: 9
重原子数: 13
形式電荷: 0
複雑度: 112

実験および物理化学的性質

PolymersPlastics & Rubber -> Epoxides

SpringerMaterials PropertiesOptical coefficient

Density0.844 (NTP, 1992) - Less dense than water; will float

Solubilityless than 1 mg/mL at 73 °F (NTP, 1992)

Flash Point · 2 件

112 °F (NTP, 1992)

44 °C

Boiling Point255 to 257 °F at 15 mmHg (NTP, 1992)

物理化学的性質

沸点: 124 · 124-125 °C/15 mmHg (lit.)
比重(密度): 0.844 g/mL · 0.844 g/mL at 25 °C (lit.)
蒸気圧: 2 mmHg · 2 mmHg ( 100 °C)
屈折率: 1.435 · 1.435-1.437
闪点: 105 °C · 105 °C
貯蔵温度: 2 · 2-8°C
外見: clear liquid
比重: 0.844 · 0.844
色: Colorless to Almost colorless
由来生物: goat
水溶解度: 水には混和しません。
BRN: 105569 · 105569
InChI: 1S/C12H24O/c1-2-3-4-5-6-7-8-9-10-12-11-13-12/h12H,2-11H2,1H3
InChIKey: MPGABYXKKCLIRW-UHFFFAOYSA-N
SMILES: CCCCCCCCCCC1CO1
LogP: 5.9 at · 5.9 at 20℃
CAS データベース: 2855 · 2855-19-8(CAS DataBase Reference)
NISTの化学物質情報: Oxirane, decyl-(2855-19-8)
EPAの化学物質情報: 1 · 1,2-Epoxydodecane (2855-19-8)

化学的性質

化学的特性clear colorless liquid

安全と法規制

GHS分類

GHS Classification · 6 件

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 174 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

H315: Causes skin irritation [Warning Skin corrosion/irritation]

危険有害性情報

Regulatory Information · 4 件

Chemical: Oxirane, decyl-

Oxirane, 2-decyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Oxirane, 2-decyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 15-03-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/12323

1,2-Epoxydodecane: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Long-chain alkyl oxiranes: Human health tier II assessment

DOT LabelFlammable Liquid

Fire HazardsThis chemical is combustible. (NTP, 1992)

Health HazardsSYMPTOMS: Symptoms of exposure to this compound may include irritation of the skin, eyes, mucous membranes and upper respiratory tract.

Hazards SummaryA tumorigen; [RTECS] A skin, eye, mucous membrane, and upper respiratory tract irritant; [CAMEO] An irritant; [MSDSonline]

安全と保護具

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. A water spray may also be used. (NTP, 1992)

First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 件

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 128 [Flammable Liquids (Water-Immiscible)]:

Personal Protective Equipment (PPE) · 1 件

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

毒性情報

Non-Human Toxicity ExcerptsCARCINOGENIC POTENTIAL OF 1,2-EPOXYDODECANE RESULTED IN 0/30 MICE AFTER DERMAL APPLICATION TO MICE. /FROM TABLE/

安全データ

F: 10-23
wgk: 1
tsca: TSCA listed
rtecs: JR2450000
hs_code: 29109000
risk_code: 36/37/38
化審法: (2)-220
消防法: 危-4-3-III
hazard_code: Xi
safety_code: 26-36-37/39
Hazard Classifications: Aquatic Acute 1Aquatic Chronic 1Skin Irrit. 2
ストレージクラス: 10 - Combustible liquids
有毒物質データの: 2855-19-8(Hazardous Substances Data)

化学と産業

用途と製造

Uses · 2 件

Used as a secondary heat stabilizer for polymers; No known commercial production in the US; [HSDB]

SECONDARY HEAT STABILIZER FOR POLYMERS

U.S. Exports · 2 件

(1979) No Data

(1981) No Data

U.S. Imports · 2 件

(1979) No Data

(1981) No Data

U.S. Production · 3 件

2023: 34,534 lb

(1979) NO EVIDENCE OF COMMERCIAL PRODN IN U.S.

(1981) NO EVIDENCE OF COMMERCIAL PRODN IN U.S.

Consumer UsesHeat transferring agent

Industry UsesHeat transferring agent

応用分野 · 3 件

用途有機合成原料。

使用In the production of epoxy resins, 1,2-Epoxydodecane is used as a reactive diluent and cross-linking agent which can help to improve the performance and versatility of these industrial materials. In the production of emulsions, foams, and dispersants, 1,2-Epoxydodecane can be used as a surfactant. In pharmaceutical industry, 1,2-Epoxydodecane can be used as a solvent in the production of certain pharmaceuticals, like pyrazolones. In the synthesis of hydroxyurea, 1,2-epoxydodecane is used as an intermediate in the production of a key starting material.

一般的な説明Clear colorless liquid.