2-(p-tert-ブチルフェノキシメチル)オキシラン

p-tert-Butylphenyl glycidyl ether

HCID 18360CAS 3101-60-8

基本情報

標準SMILES
CC(C)(C)c1ccc(OCC2CO2)cc1
InChIKey
HHRACYLRBOUBKM-UHFFFAOYSA-N
分子式
C13H18O2
平均分子量
206.28 g/mol
単同位体質量
206.13067982

概要

P-tert-butylphenyl glycidyl ether is a clear light yellow liquid. (NTP, 1992)

名称と識別子

優先名称
p-tert-Butylphenyl glycidyl ether
IUPAC
2-[(4-tert-butylphenoxy)methyl]oxirane
現地名
2-(p-tert-ブチルフェノキシメチル)オキシラン
英語名
ARALDITE M
分子式
C13H18O2
分子量
206.28

名称と別名

3101-60-84-tert-Butylphenyl glycidyl etherp-tert-Butylphenyl glycidyl ether2-[(4-tert-Butylphenoxy)methyl]oxiranetert-Butyl phenyl glycidyl ethertert-Butylphenol glycidyl ethertert-Butylphenyl glycidyl etherCCRIS 2638p-tert-Butylphenyl 1-(2,3-epoxy)propyl etherDTXSID10247023-(p-tert-Butylphenoxy)-1,2-epoxypropaneOxirane, [[4-(1,1-dimethylethyl)phenoxy]methyl]-
名称をさらに表示
4-tert-ブチルフェニルグリシジルエーテルグリシジル4-tert-ブチルフェニルエーテル2-[4-(1,1-ジメチルエチル)フェノキシメチル]オキシラングリシジル(4-tert-ブチルフェニル)エーテルp-tert-ブチルフェニルグリシジルエーテル2-(p-tert-ブチルフェノキシメチル)オキシラン2-[(p-tert-ブチルフェノキシ)メチル]オキシラン(4-tert-ブチルフェニル)(オキシラニルメチル)エーテル2-[(4-tert-ブチルフェノキシ)メチル]オキシラン(4-tert-ブチルフェニル)グリシジルエーテルptertブチルフェニルグリシジルエ-テルARALDITE® RESINS (MODIFIED EPOXY RESINS), GRADE 60051-tert-ブチル-4-(グリシジルオキシ)ベンゼン2-(4-tert-ブチルフェノキシメチル)オキシランr1007XY693Heloxy 65ARALDITE MARALDITE 502ARALDITE 506ARALDITE 507
EINECS 221-453-2DUA9665YBGPropane, 1-(p-tert-butylphenoxy)-2,3-epoxy-R 10072,3-Epoxypropyl-4-t-butylphenyl etherBRN 0007417Oxirane, ((4-(1,1-dimethylethyl)phenoxy)methyl)-AI3-52800

データベース識別子

CAS
3101-60-8
PubChem CID
18360
DTXSID
DTXSID1024702
ChEMBL
CHEMBL1890780
UNII
DUA9665YBG
EC Number
221-453-2、682-371-4
Nikkaji
J64.262B

物性

構造計算による物性

XLogP
3.3
極性表面積
21.8 Ų
水素結合供与体数
0
水素結合受容体数
2
回転可能結合数
4
重原子数
15

実験および物理化学的性質

PolymersPlastics & Rubber -> Glycidyl Ethers
Density1.038 at 68 °F (NTP, 1992) - Denser than water; will sink
Solubilityless than 1 mg/mL at 72 °F (NTP, 1992)
Flash Point215 °F (NTP, 1992)
Boiling Point329 to 338 °F at 14 mmHg (NTP, 1992)
Physical Description · 3 件

P-tert-butylphenyl glycidyl ether is a clear light yellow liquid. (NTP, 1992)

Liquid

Clear light yellow liquid; [CAMEO] Colorless liquid with a mild odor; [Sigma-Aldrich MSDS]

物理化学的性質

沸点
165 · 165-170 °C14 mm Hg(lit.)
比重(密度)
1.038 g/mL · 1.038 g/mL at 25 °C(lit.)
蒸気圧
0.025 Pa · 0.025Pa at 20℃
屈折率
20 · n20/D 1.515(lit.)
闪点
215 °F · 215 °F
貯蔵温度
Inert atmosphere,Room Temperature

安全と法規制

GHS分類

GHS Classification · 6 件

This chemical does not meet GHS hazard criteria for 0.7% (7 of 1042) of reports.

Danger

H314 (44.7%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P261, P264, P264+P265, P272, P273, P280, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P321, P332+P317, P333+P317, P337+P317, P362+P364, P363, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 1042 reports by companies from 16 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

危険有害性情報

Regulatory Information · 5 件

Chemical: Oxirane, [[4-(1,1-dimethylethyl)phenoxy]methyl]-

Oxirane, 2-[[4-(1,1-dimethylethyl)phenoxy]methyl]- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Oxirane, 2-[[4-(1,1-dimethylethyl)phenoxy]methyl]- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

TP - indicates a substance that is the subject of a proposed TSCA section 4 test rule.

Status: Active Update: 25-11-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/10438

Oxirane, 4-(1,1-dimethylethyl)phenoxymethyl-: Does not have an individual approval but may be used under an appropriate group standard

Fire HazardsThis chemical is combustible. (NTP, 1992)
Hazards SummaryMay form unstable peroxides; [CAMEO] A skin and strong eye irritant; May cause skin sensitization; [Sigma-Aldrich MSDS] Danger of skin sensitization; [MAK] See p-Cresyl glycidyl ether.
Reactive GroupEthers
Reactivity AlertsPeroxidizable Compound
Reactivity Profile · 1 件

P-TERT-BUTYLPHENYL GLYCIDYL ETHER, an ether, can act as a base. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.

安全と保護具

Fire FightingFires involving this chemical can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 件

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 件

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Personal Protective Equipment (PPE) · 1 件

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

毒性情報

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.

安全データ

wgk
3
tsca
TSCA listed
rtecs
TX4250000
hs_code
2910.90.2000
risk_code
36/37/38-43-36/38-22-62-51/53-61
化審法
(3)-575, (3)-594

化学と産業

用途と製造

U.S. Production2023: 250,000 - <400,000 lb
Consumer UsesNot Known or Reasonably Ascertainable
Industry UsesMonomers
Household ProductsInformation on 3 consumer products that contain 4-tert-Butylphenyl glycidyl ether in the following categories is provided:
General Manufacturing Information · 2 件

Custom Compounding of Purchased Resins

Oxirane, 2-[[4-(1,1-dimethylethyl)phenoxy]methyl]-: ACTIVE

応用分野

使用4-tert-Butylphenyl glycidyl ether is used in paint industry and serves as organic coating in Paint, boat Paint, building coating material. It is also used as an epoxy reactive diluent.

一般的な説明Clear light yellow liquid.

サプライヤー50 社

常州市弘裕化工有限公司0519-89996110 13813691203 · [email protected]
郑州阿尔法化工有限公司+86-18530059196 · [email protected]
苏州道澜生物医药科技有限公司15952404857 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

関連反応

15 件

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