基本情報
- 標準SMILES
CC(C)(C)c1ccc(OCC2CO2)cc1- InChIKey
HHRACYLRBOUBKM-UHFFFAOYSA-N- 分子式
- C13H18O2
- 平均分子量
- 206.28 g/mol
- 単同位体質量
- 206.13067982
概要
P-tert-butylphenyl glycidyl ether is a clear light yellow liquid. (NTP, 1992)
名称と識別子
- 優先名称
- p-tert-Butylphenyl glycidyl ether
- IUPAC
- 2-[(4-tert-butylphenoxy)methyl]oxirane
- 現地名
- 2-(p-tert-ブチルフェノキシメチル)オキシラン
- 英語名
- ARALDITE M
- 分子式
- C13H18O2
- 分子量
- 206.28
名称と別名
名称をさらに表示
データベース識別子
- CAS
3101-60-8- PubChem CID
- 18360
- DTXSID
DTXSID1024702- ChEMBL
CHEMBL1890780- UNII
- DUA9665YBG
- EC Number
- 221-453-2、682-371-4
- Nikkaji
- J64.262B
物性
構造計算による物性
- XLogP
- 3.3
- 極性表面積
- 21.8 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 2
- 回転可能結合数
- 4
- 重原子数
- 15
- 形式電荷
- 0
- 複雑度
- 199
実験および物理化学的性質
Physical Description
P-tert-butylphenyl glycidyl ether is a clear light yellow liquid. (NTP, 1992)
Liquid
Clear light yellow liquid; [CAMEO] Colorless liquid with a mild odor; [Sigma-Aldrich MSDS]
物理化学的性質
- 沸点
- 165 · 165-170 °C14 mm Hg(lit.)
- 比重(密度)
- 1.038 g/mL · 1.038 g/mL at 25 °C(lit.)
- 蒸気圧
- 0.025 Pa · 0.025Pa at 20℃
- 屈折率
- 20 · n20/D 1.515(lit.)
- 闪点
- 215 °F · 215 °F
- 貯蔵温度
- Inert atmosphere,Room Temperature
- 外見
- 液体
- 色
- Colorless to Almost colorless
- 水溶解度
- 水にわずかに溶ける。
- LogP
- 3.59 at · 3.59 at 20℃
- EPAの化学物質情報
- p-tert-Butylphenyl glycidyl ether (3101-60-8)
安全と法規制
GHS分類
GHS Classification
This chemical does not meet GHS hazard criteria for 0.7% (7 of 1042) of reports.
Danger
H314 (44.7%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
P260, P261, P264, P264+P265, P272, P273, P280, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P321, P332+P317, P333+P317, P337+P317, P362+P364, P363, P391, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 1042 reports by companies from 16 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Warning
危険有害性情報
Regulatory Information
Chemical: Oxirane, [[4-(1,1-dimethylethyl)phenoxy]methyl]-
Oxirane, 2-[[4-(1,1-dimethylethyl)phenoxy]methyl]- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Oxirane, 2-[[4-(1,1-dimethylethyl)phenoxy]methyl]- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
TP - indicates a substance that is the subject of a proposed TSCA section 4 test rule.
Status: Active Update: 25-11-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/10438
Oxirane, 4-(1,1-dimethylethyl)phenoxymethyl-: Does not have an individual approval but may be used under an appropriate group standard
Reactivity Profile
P-TERT-BUTYLPHENYL GLYCIDYL ETHER, an ether, can act as a base. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
Air and Water Reactions
Ethers tend to form unstable peroxides when exposed to oxygen. Ethyl, isobutyl, ethyl tert-butyl, and ethyl tert-pentyl ether are particularly hazardous in this respect. Ether peroxides can sometimes be observed as clear crystals deposited on containers or along the surface of the liquid. Insoluble in water.
安全と保護具
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
Nonfire Spill Response
SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
Personal Protective Equipment (PPE)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)
毒性情報
安全データ
- wgk
- 3
- tsca
- TSCA listed
- rtecs
- TX4250000
- hs_code
- 2910.90.2000
- risk_code
- 36/37/38-43-36/38-22-62-51/53-61
- 化審法
- (3)-575, (3)-594
- 安衛法
- 変異原性物質
- 消防法
- 危-4-3-III
- hazard_code
- Xi,Xn,N,T
- safety_code
- 26-36/37/39-39-36-61-45-36/37-53
化学と産業
用途と製造
General Manufacturing Information
Custom Compounding of Purchased Resins
Oxirane, 2-[[4-(1,1-dimethylethyl)phenoxy]methyl]-: ACTIVE
応用分野
使用4-tert-Butylphenyl glycidyl ether is used in paint industry and serves as organic coating in Paint, boat Paint, building coating material. It is also used as an epoxy reactive diluent.
一般的な説明Clear light yellow liquid.
上流・下流製品情報
下流製品
サプライヤー50 社
関連反応
関連ノート
読み込み中…