Hydrazinium, 1,1,1-trimethyl-, iodide (1:1) (HCID 18683)

名称と識別子

優先名称: Hydrazinium, 1,1,1-trimethyl-, iodide (1:1)
IUPAC: amino(trimethyl)azanium iodide
現地名: 1,1,1-トリメチルヒドラジニウムヨージド
英語名: 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE
分子式: C3H11IN2
分子量: 202.04

名称と別名

3288-80-0Trimethylhydrazonium iodideHYDRAZINIUM, 1,1,1-TRIMETHYL-, IODIDENSC 33596NSC 123999Hydrazonium, 1,1,1-trimethyl-, iodideHydrazinium, 1,1,1-trimethyl-, iodide (1:1)RefChem:147028628-240-71,1,1-Trimethylhydrazinium iodideMFCD00464984amino(trimethyl)azanium;iodide

名称をさらに表示

1,1,1-トリメチルヒドラジニウムヨージドMildronate Impurity 1Allopurinol Impurity 13amino(trimethyl)azanium:iodide1,1,1-trimethyl-hydrazoniuiodide1,1,1-trimethyl-hydraziniuiodide1,1,1-TRIMETHYLHYDRAZONIUM IODIDE1,1,1-Trimethyl-1-hydrazinium Iodide1,1,1-TriMethylhydraziniuM iodide 97%

trimethylhydrazinium iodide1,1,1-TRIMETHYLHYDRAZINIUMIODIDE1,1-Trimethylhydrazinium iodide1,1,1-Trimethylhydrazin-1-ium iodideHydrazinium,1,1-trimethyl-, iodideHydrazonium,1,1-trimethyl-, iodideamino(trimethyl)azaniumamino(trimethyl)azanium,iodide

データベース識別子

CAS: 3288-80-0
PubChem CID: 18683
DTXSID: DTXSID00954539
EC Number: 628-240-7

物性

構造計算による物性

極性表面積: 26 Å²
水素結合供与体数: 1
水素結合受容体数: 2
回転可能結合数: 0
重原子数: 6
形式電荷: 0
複雑度: 26

実験および物理化学的性質

Physical DescriptionWhite powder; [Sigma-Aldrich MSDS]

物理化学的性質

融点: 225 · 225-230 °C (dec.) (lit.)
貯蔵温度: 2 · 2-8°C, sealed storage, away from moisture and light
InChI: 1S/C3H11N2.HI/c1-5(2,3)4;/h4H2,1-3H3;1H/q+1;/p-1
InChIKey: HLNPDVKKRBWQAA-UHFFFAOYSA-M
SMILES: [I-].C[N+](C)(C)N
EPAの化学物質情報: 1 · 1,1,1-trimethylhydrazinium iodide (3288-80-0)

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]；H360 (100%): May damage fertility or the unborn child [Danger Reproductive toxicity]

P203, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P318, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Hazards Summary · 1 件

Causes convulsions and cardiac changes in intraperitoneal lethal-dose studies of mice; LD50 = 255 mg/kg; [RTECS] A skin and strong eye irritant; Possible reproductive toxicant and teratogen; [Sigma-Aldrich MSDS] See 1,2-Dimethylhydrazine. See Iodine for the TLV of Iodides.

Hazard Classes and CategoriesSkin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (100%)；Repr. 1B (100%)

毒性情報

Adverse EffectsNeurotoxin - Other CNS neurotoxin

安全データ

wgk: 3
tsca: TSCA listed
rtecs: MW0349100
hs_code: 2928009090
risk_code: 61-36/37/38
hazard_code: T
safety_code: 53-36/37/39-45
Hazard Classifications: Eye Irrit. 2Repr. 1BSkin Irrit. 2STOT SE 3
ストレージクラス: 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects

化学と産業

用途と製造

General Manufacturing InformationHydrazinium, 1,1,1-trimethyl-, iodide (1:1): ACTIVE

応用分野 · 2 件

使用1,1,1-Trimethylhydrazinium iodide (TMHI) may be employed for the amination of 1-X-3,5-dinitrobenzenes.

一般的な説明1,1,1-Trimethylhydrazinium iodide ([(CH3)3N-NH2]I, TMHI) is widely employed as a vicarious nucleophilic substitution (VNS) reagent for various aromatic amination reactions. On reaction with silver salt, it affords the following salts: nitrate (([(CH3)3N-NH2][NO3]), perchlorate ([(CH3)3N-NH2][ClO4]), azide ([(CH3)3N-NH2][N3]), 5-amino-1H-tetrazolate ([(CH3)3N-NH2][H2N-CN4]) and sulfate ([(CH3)3N-NH2]2[SO4].2H2O).