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12011-97-1C.[Mo]CNEOGBIICRAWOH-UHFFFAOYSA-N12011-97-1、12627-57-5DTXSID10923231Polymorphism in stoichiometric and non-stoichiometric MO carbides is described. Up to 1190 ℃ the stable phase is orthohrombic α Mo-C, between 1190 ℃ and 1655℃ hexagonal βMo2C is stable. Above 1655 ℃ a non-stoichiometric MO-C phase exists, hexagonal up to 1960 ℃ and face centred cubic between 1960 and the melting point, 2580 ℃ . Heating MO and C in a solar furnace at 1600 ℃ resulted in synthesis of non-stoichiometic hexagonal MoC(1-x)in 30 minutes. It is suggested that there is a photochemical reaction.
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