基本情報
- CAS
3942-54-9- 標準SMILES
CNC(=O)Oc1ccccc1Cl- InChIKey
ZAGNMMRDHSEOPE-UHFFFAOYSA-N- 分子式
- C8H8ClNO2
- 平均分子量
- 185.61 g/mol
- 単同位体質量
- 185.02435618
名称と識別子
- 優先名称
- o-Chlorophenyl methylcarbamate
- IUPAC
- (2-chlorophenyl) N-methylcarbamate
- 現地名
- N-メチルカルバミド酸2-クロロフェニル
- 英語名
- CPMC
- 分子式
- C8H8ClNO2
- 分子量
- 185.61
名称と別名
Etrofol2-Chlorophenyl methylcarbamate3942-54-9Hopcide2-chlorophenyl N-methylcarbamateHoppsideO-CHLOROPHENYL METHYLCARBAMATECarbamic acid, methyl-, 2-chlorophenyl esterRo 7-47802-Chlorophenyl-N-methylcarbamateHSDB 2609EINECS 223-524-3
名称をさらに表示
N-メチルカルバミド酸2-クロロフェニルエトロホールホプシドＮ－メチルカルバモイル－２－クロロフェノールN-メチルカルバミル-2-クロルフェノールＮメチルカルバモイル２クロロフェノルN-ﾒﾁﾙｶﾙﾊﾞﾐﾙ-2-ｸﾛﾙﾌｪﾉｰﾙCPMCHopsidero7-4780CPMC emulsionetrofol (cpmc)Hopcide emulsiono-chlorophenylmethylcarbamate
BRN 2048887R4I4K15V9BAI3-27692Carbamic acid, methyl-, o-chlorophenyl esterCarbamic acid, N-methyl-, 2-chlorophenyl ester4-06-00-00795 (Beilstein Handbook Reference)O-CHLOROPHENYL METHYLCARBAMATE [HSDB]RefChem:855221
データベース識別子
- CAS
3942-54-9- PubChem CID
- 19841
- DTXSID
DTXSID3058084- UNII
- R4I4K15V9B
- EC Number
- 223-524-3
- Nikkaji
- J8.277E
物性
構造計算による物性
- XLogP
- 1.6
- 極性表面積
- 38.3 Ų
- 水素結合供与体数
- 1
- 水素結合受容体数
- 2
- 回転可能結合数
- 2
- 重原子数
- 12
- 形式電荷
- 0
- 複雑度
- 163
実験および物理化学的性質
SpringerMaterials PropertiesFusion temperature
PesticidesPesticides -> Carbamate Insecticides
LogP1.64
Color/FormWHITE CRYSTALS
SolubilitySOL IN ACETONE, METHANOL, ETHANOL, DIMETHYLFORMAMIDE
Melting Point90-91 °C
Vapor Pressure0.00831 [mmHg]
Physical DescriptionWhite solid; [HSDB]
物理化学的性質
- 比重(密度)
- 1.2797 · 1.2797 (rough estimate)
- 屈折率
- 1.556 · 1.5560 (estimate)
- EPAの化学物質情報
- 2 · Carbamic acid, methyl-, 2-chlorophenyl ester (3942-54-9)
安全と法規制
GHS分類
GHS Classification
Warning
H302: Harmful if swallowed [Warning Acute toxicity, oral]
P264, P270, P301+P317, P330, and P501 (click each P-code to see the statement)
危険有害性情報
Hazards SummaryNo deaths in mice in doses up to 600 mg/kg by skin application; [HSDB] See CARBAMATE INSECTICIDES.
Hazard Classes and CategoriesAcute toxicity (Oral) - Category 4
安全と保護具
Exposure Control and Personal Protection
Biological Exposure Indices (BEI) [ACGIH] - Acetylcholinesterase activity in red blood cells = 70% of individual's baseline; Butylcholinesterase activity in serum or plasma = 60% of individual's baseline; Sample at end of shift; [TLVs and BEIs]
毒性情報
Ecotoxicity ValuesTLM: CARP 10.9 PPM/48 HR
Adverse EffectsOther Poison - Carbamate
Non-Human Toxicity Excerpts...MALE MOUSE...DERMAL TOXICITY--NO DEATH UP TO 600 MG/KG.
Antidote and Emergency Treatment
1) ESTABLISH CLEAR AIRWAY & TISSUE OXYGENATION BY ASPIRATION OF SECRETIONS & IF NECESSARY...ASSISTED PULMONARY VENTILATION WITH OXYGEN. DO NOT ADMIN ATROPINE UNTIL SATISFACTORY LEVEL OF OXYGENATION...ACHIEVED. ATROPINE MAY INDUCE VENTRICULAR FIBRILLATION IF VICTIM...SEVERELY ASPHYXIC. /CARBAMATES, CHOLINESTERASE INHIBITORS/
2) ADMIN ATROPINE SULFATE IV, OR IM IF IV INJECTION IS NOT POSSIBLE. ATROPINE PROTECTS END-ORGANS FROM EXCESSIVE CONCN OF ACETYLCHOLINE. IT DOES NOT REACTIVATE CHOLINESTERASE, & EFFECTS OF UNMETABOLIZED TOXICANT MAY APPEAR AS ATROPINIZATION WEARS OFF. /CARBAMATES, CHOLINESTERASE INHIBITORS/
2) IN MODERATELY SEVERE POISONING: ADULT DOSE (INCL CHILDREN OVER 12 YR): 0.4-2.0 MG/KG BODY WT (1.0-5.0 ML OF USUAL 0.4 MG/ML SOLN) REPEATED EVERY 15-30 MIN UNTIL ATROPINIZATION IS ACHIEVED (TACHYCARDIA, FLUSHING, DRY MOUTH, MYDRIASIS). MAINTAIN...BY REPEATED DOSES FOR 2-12 HR... /CARBAMATES, CHOLINESTERASE INHIBITORS/
2) CHILD'S DOSE: 0.01 MG/KG BODY WT (0.05 ML/KG OF USUAL 0.4 MG/ML SOLN) REPEATED EVERY 15-30 MIN UNTIL ATROPINIZATION IS ACHIEVED. IN SEVERE POISONING, USE TWICE THE DOSAGE OF ATROPINE RECOMMENDED ABOVE. /CARBAMATES, CHOLINESTERASE INHIBITORS/
For more Antidote and Emergency Treatment (Complete) data for O-CHLOROPHENYL METHYLCARBAMATE (10 total), please visit the HSDB record page.
安全データ
- tsca
- TSCA listed
- 有毒物質データの
- 3942-54-9(Hazardous Substances Data)
化学と産業
用途と製造
Uses
Formerly used as insecticide on rice; [HSDB]
Farming (Pesticides) [Category: Industry]
FORMERLY A SELECTIVE INSECTICIDE AGAINST SUCKING INSECTS, FOR PLANTHOPPERS AND LEAFHOPPERS ON RICE
U.S. Exports
(1972) No Data
(1975) No Data
U.S. Imports
(1972) No Data
(1975) No Data
U.S. Production(1972) PROBABLY GREATER THAN 4.54X10+5 GRAMS
Methods of ManufacturingFORMERLY BY REACTION OF ORTHO-ISOPROPYLPHENOL AND METHYL ISOCYANATE
Formulations/Preparations
WETTABLE POWDER 50%.
HOPCIDE (CPMC) EMULSIFIABLE CONCN CONTAINS 20% ACTIVE INGREDIENT & HOPCIDE (CPMC) WETTABLE POWDER CONTAINS 20%.
General Manufacturing InformationCarbamic acid, N-methyl-, 2-chlorophenyl ester: INACTIVE
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