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エチルグリシジルエーテル

Ethyl glycidyl ether

HCID 19919
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
4016-11-9
標準SMILES
CCOCC1CO1
InChIKey
HQCSZRIVJVOYSU-UHFFFAOYSA-N
分子式
C5H10O2
平均分子量
102.13 g/mol
単同位体質量
102.06807956

概要

1,2-epoxy-3-ethoxypropane appears as a colorless liquid. Less dense than water. Contact may severely irritate skin, eyes and mucous membranes. May be toxic by ingestion, inhalation and skin absorption.

名称と識別子

優先名称
Ethyl glycidyl ether
IUPAC
2-(ethoxymethyl)oxirane
現地名
エチルグリシジルエーテル
英語名
Ethyl glycidyl ether
分子式
C5H10O2
分子量
102.13

名称と別名

ETHYL GLYCIDYL ETHER(Ethoxymethyl)oxirane1,2-Epoxy-3-ethoxypropaneOxirane, 2-(ethoxymethyl)-ZSP9639OMHNSC 71436glycidyl ethyl etherCCRIS 1018HSDB 6080EINECS 223-671-3NSC-71436UN2752
名称をさらに表示
エチルグリシジルエーテルグリシジルエチルエーテルオキシラニルメチルエチルエーテル(エトキシメチル)オキシラン2-(エトキシメチル)オキシランエチル グリシジル エ-テル1,2-エポキシ-3-エトキシプロパン1-エトキシ-2,3-エポキシプロパン2-(Ethoxymethyl)oxirane(ethoxymethyl)-oxiranEthylGlycidylEther>Ethyl glycidyl ether,98%1,2-epoxy-3-ethoxy-propanOxiranylmethylethyl ether3-Ethoxy-1,2-epoxypropane1-ETHOXY-2,3-EPOXYPROPANE
UNII-ZSP9639OMHBRN 01026692,3-epoxypropyl ethyl ether1,2-Epoxy-3-ethyloxy propaneDTXSID90871049UN 27525-17-03-00010 (Beilstein Handbook Reference)1,2Epoxy3ethoxypropane

データベース識別子

CAS
4016-11-9

物性

構造計算による物性

XLogP
0.1
極性表面積
21.8 Ų
水素結合供与体数
0
水素結合受容体数
2
回転可能結合数
3
重原子数
7
形式電荷
0
複雑度
54

実験および物理化学的性質

Chemical ClassesFlammable agents - 2nd degree
PolymersPlastics & Rubber -> Glycidyl Ethers
LogP0.27
Vapor Pressure31.5 [mmHg]
Physical Description · 2 件

1,2-epoxy-3-ethoxypropane appears as a colorless liquid. Less dense than water. Contact may severely irritate skin, eyes and mucous membranes. May be toxic by ingestion, inhalation and skin absorption.

Colorless liquid; [CAMEO]

物理化学的性質

沸点
128 °C · 128 °C
比重(密度)
0.94 · 0.94
屈折率
1.4075 · 1.4075-1.4095
闪点
47 °C · 47 °C
貯蔵温度
Flammables area
外見
液体
色
無色透明
EPAの化学物質情報
Ethyl glycidyl ether (4016-11-9)

化学的性質

安全と法規制

安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 4 件

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P264, P264+P265, P270, P273, P280, P301+P317, P303+P361+P353, P305+P351+P338, P330, P337+P317, P370+P378, P391, P403+P235, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 41 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 2 件

TP - indicates a substance that is the subject of a proposed TSCA section 4 test rule.

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelFlammable Liquid
Fire Hazards · 2 件

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:

· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Health Hazards · 2 件

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:

· Inhalation or contact with material may irritate or burn skin and eyes.

Hazards SummaryHighly flammable and polymerizable; May cause severe irritation; [CAMEO] An irritant; Inhalation of high concentrations can cause CNS depression; [MSDSonline] See GLYCIDYL ETHERS.
DOT ID and Guide2752 127
Reactive GroupEthers

化学と産業

用途と製造

Uses · 3 件

No known current commercial use or production in the US; [HSDB]

Plastic Composites Manufacturing [Category: Industry]

NO EVIDENCE OF CURRENT COMMERCIAL USE IN U.S.

U.S. Exports · 2 件

(1979) No Data

(1981) No Data

U.S. Imports · 2 件

(1979) No Data

(1981) No Data

U.S. Production · 2 件

(1979) NOT PRODUCED COMMERCIALLY IN U.S.

(1981) NOT PRODUCED COMMERCIALLY IN U.S.

General Manufacturing InformationOxirane, 2-(ethoxymethyl)-: ACTIVE

応用分野

一般的な説明A colorless liquid. Flash point near 100°F. Less dense than water. Contact may severely irritate skin, eyes and mucous membranes. May be toxic by ingestion, inhalation and skin absorption.

上流・下流製品情報

下流製品

1-クロロ-3-エトキシ-2-プロパノール1-ethoxy-3-(piperazin-1-yl)propan-2-ol

サプライヤー28 社

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
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関連反応

6 件
反応記録を作成
HRID 461577 の反応式
HRID 461577反応物としてuspto-grants-1977_12
HRID 825369 の反応式
HRID 825369反応物としてTest data from https://doi.org/10.1039/C8SC04228D
HRID 1111840 の反応式
HRID 1111840反応物としてuspto-grants-1978_10
HRID 1535436 の反応式
HRID 1535436反応物としてTraining data from https://doi.org/10.1039/C8SC04228D (1/10)
HRID 2071573 の反応式
HRID 2071573反応物としてuspto-grants-1977_09
HRID 2224229 の反応式
HRID 2224229反応物としてuspto-grants-2008_05

化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
PubChem CID
19919
DTXSID
DTXSID90871049
UNII
ZSP9639OMH
EC Number
223-671-3
Nikkaji
J35.203I

化学的特性clear colorless liquid

Reactivity Alerts
Highly Flammable
Reactivity Profile · 1 件

An epoxide and ether. Ethers can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert. Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

DOT Emergency Guidelines · 5 件

/GUIDE 127: FLAMMABLE LIQUIDS (POLAR/WATER-MISCIBLE)/ Fire or Explosion: HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

/GUIDE 127: FLAMMABLE LIQUIDS (POLAR/WATER-MISCIBLE)/ Health: Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control may cause pollution.

/GUIDE 127: FLAMMABLE LIQUIDS (POLAR/WATER-MISCIBLE)/ Public Safety: CALL Emergency Response Telephone Number ... . As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering.

/GUIDE 127: FLAMMABLE LIQUIDS (POLAR/WATER-MISCIBLE)/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection.

For more DOT Emergency Guidelines (Complete) data for ETHYL GLYCIDYL ETHER (8 total), please visit the HSDB record page.

DOT Hazard Classification · 4 件

1,2-Epoxy-3-ethoxypropane

UN2752

Class 3 Flammable and combustible liquid (49 eCFR § 173.120)

PG III: the degree of danger presented by the material is minor

Air and Water ReactionsHighly flammable. Soluble with possible partial decomposition in water.

安全と保護具

Fire FightingExcerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:
Accidental Release Measures · 2 件

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 件

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:
Isolation and Evacuation · 2 件

Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:

Immediate precautionary measure

Personal Protective Equipment (PPE)Excerpt from ERG Guide 127 [Flammable Liquids (Water-Miscible)]:
Emergency Response Planning GuidelinesCAUTION: The majority of these products have a very low flash point. Use of water spray when fighting fire may be inefficient.

毒性情報

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Non-Human Toxicity Excerpts · 2 件

ETHYLGLYCIDYL ETHER WAS TESTED FOR CARCINOGENICITY BY SKIN APPLICATION OF 30 ICR/HA FEMALE SWISS MICE (10% SOLN IN ACETONE) 3 TIMES WEEKLY FOR A DURATION OF 544 DAYS. MEDIAN SURVIVAL DAYS WAS 544 WITH NO SKIN DAMAGE AND NO EVIDENCE OF CARCINOGENESIS.

THE MUTAGENIC POTENTIALS OF GLYCIDYL ETHERS HAVING STRAIGHT ALKYL CHAINS OF 2,4,6,8,10,12, AND 14 CARBONS ATOMS WERE EXAMINED IN A BATTERY OF IN VITRO ASSAYS. THE BATTERY CONSISTS OF THE SALMONELLA MAMMALIAN MICROSOME ASSAY, THE L5178Y MOUSE LYMPHOMA ASSAY, AND UNSCHEDULED DNA SYNTHESIS USING W138 CELLS. ALL THE ETHERS THROUGH C-4 SHOWED A DEFINITE RESPONSE WHILE THE C-8 OR HIGHER ETHERS SHOWED VERY WEAK OR NO RESPONSES.

安全データ

tsca
TSCA listed
rtecs
TZ3200000
ridadr
UN 2752 (1,2-EPOXY-3-ETHOXYPROPANE)
hs_code
29109000
risk_code
36/37/38-10-51/53-36-22
化審法
(2)-391
消防法
危-4-2-III
hazard_code
Xi,N,Xn
safety_code
37/39-26-16-61
hazard_class
3
packing_group
III
有毒物質データの
4016-11-9(Hazardous Substances Data)
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