2-Pyridinamine, N-methyl- (HCID 20727)

名称と識別子

優先名称: 2-Pyridinamine, N-methyl-
IUPAC: N-methylpyridin-2-amine
現地名: 2-(メチルアミノ)ピリジン
英語名: 2-(Methylamino)pyridine
分子式: C6H8N2
分子量: 108.14

名称と別名

2-(Methylamino)pyridine4597-87-92-Methylaminopyridine2-Pyridinamine, N-methyl-Methylamino-2 pyridineN-2-PyridylmethylamineEINECS 224-997-9NSC 122871PYRIDINE, 2-METHYLAMINO-DTXSID60196670N2PyridylmethylamineMethylamino2 pyridine

名称をさらに表示

2-(メチルアミノ)ピリジン2-メチルアミノピリジンN-メチルピリジン-2-アミンN-メチル-2-ピリジンアミンメチル(2-ピリジル)アミンN-METHYLPYRIDIN-2-AMINEPiroxicam Impurity 9methylamino-2pyridine2-methylamino-pyridinn-methyl-2-pyridinaminMethyl(2-pyridyl)amineN-METHYL-2-PYRIDINAMINE

2(Methylamino)pyridinePyridine, 2methylamino2Pyridinamine, NmethylRefChem:4833452Pyridinamine, Nmethyl (9CI)DTXCID001191612-Pyridinamine, N-methyl-(9CI)224-997-9

データベース識別子

CAS: 4597-87-9
PubChem CID: 20727
DTXSID: DTXSID60196670
EC Number: 224-997-9
Nikkaji: J51.330J

物性

構造計算による物性

XLogP: 1.1
極性表面積: 24.9 Å²
水素結合供与体数: 1
水素結合受容体数: 2
回転可能結合数: 1
重原子数: 8
形式電荷: 0
複雑度: 63.5

実験および物理化学的性質

Chemical ClassesNitrogen Compounds -> Pyridines

SpringerMaterials PropertiesBoiling point

LogP1.07

Vapor Pressure1.11 [mmHg]

Physical DescriptionLight yellow liquid; mp = 14-15 deg C; [Alfa Aesar MSDS]

物理化学的性質

融点: 15 °C · 15 °C(lit.)
沸点: 200 · 200-201 °C(lit.)
比重(密度): 1.052 g/mL · 1.052 g/mL at 25 °C(lit.)
屈折率: 20 · n20/D 1.578(lit.)
闪点: 190 °F · 190 °F
貯蔵温度: 2 · 2-8°C, protect from light
酸解離定数(Pka): 6.73 · 6.73±0.10(Predicted)
外見: powder to lump to clear liquid
色: White or Colorless to Light yellow
BRN: 108188 · 108188
InChI: InChI=1S/C6H8N2/c1-7-6-4-2-3-5-8-6/h2-5H,1H3,(H,7,8)
InChIKey: SVEUVITYHIHZQE-UHFFFAOYSA-N
SMILES: C1(NC)=NC=CC=C1
CAS データベース: 4597 · 4597-87-9(CAS DataBase Reference)
NISTの化学物質情報: 2 · 2-Pyridinamine, N-methyl-(4597-87-9)

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H302 (93.6%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazards SummaryCauses excitement in intravenous lethal-dose studies of mice (LD50 = 270 mg/kg); [RTECS] A skin and strong eye irritant; Harmful by ingestion, inhalation, and skin absorption; [Alfa Aesar MSDS] See 2-Aminopyridine.

Hazard Classes and CategoriesAcute Tox. 4 (93.6%)

安全データ

wgk: 3
rtecs: UT5500000
ridadr: UN2810
hs_code: 29333990
risk_code: 20/21/22-36/37/38
消防法: 危-4-3-III
hazard_code: Xn
safety_code: 26-36/37/39
hazard_class: 6.1
packing_group: III
Hazard Classifications: Acute Tox. 4 DermalAcute Tox. 4 InhalationAcute Tox. 4 OralEye Irrit. 2Skin Irrit. 2STOT SE 3
ストレージクラス: 10 - Combustible liquids

化学と産業

応用分野 · 1 件

一般的な説明Photoreaction of 2-(methylamino)pyridine in low-temperature argon matrix has been investigated by infrared spectroscopy and density functional theory calculation. 2-(Methylamino)pyridine forms copper(II) complexes containing various anions (Cl-, Br-, NO3-, SCN-, ClO4-, or SO42-).