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解説硫酸マグネシウム,化学式はMgSO4。比重2.66,融点1185℃。無色の結晶。水に溶け,水溶液からは1,6,7,12水和物などが得られる。7水和物が普通で,これは瀉利(しゃり)塩またはエプソム塩ともいい,比重1.68の無色の結晶。乾燥した空気中では風解し,水溶液は苦味がある。紙の充填(じゅうてん)剤,媒染剤,下剤として使用。天然には1水和物がキーゼリットとして岩塩鉱床から得られる。また海水中に存在し,苦汁(にがり)の成分。工業的には苦汁の濃縮,酸化マグネシウムや炭酸マグネシウムの硫酸処理によってつくる。
用途洗剤のビルダー、グラウト剤、固結防止剤
説明Magnesium sulfate is an inorganic salt (chemical compound) containing magnesium, sulfur and oxygen, with the formula MgSO4. It is strongly hygroscopic and often encountered as the heptahydrate sulfate mineral epsomite (MgSO4•7H2O), commonly called Epsom salt. And the monohydrate, MgSO4•H2O, is found as the mineral kieserite. In gardening and other agriculture, magnesium sulfate is used to correct a magnesium or sulfur deficiency in soil. In food preparation, magnesium sulfate is used as a brewing salt in beer production or used as a coagulant for making tofu. In chemistry, anhydrous magnesium sulfate is commonly used as a desiccant in organic synthesis due to its affinity for water. For Marine use, magnesium sulfate heptahydrate is used to maintain the magnesium concentration in marine aquaria which contain large amounts of stony corals. For medicine use, it is used in pregnant women to control seizures due to certain complications of pregnancy (eg, severe toxemia) and to control high blood pressure, severe brain function problems (encephalopathy), and seizures in children who have sudden, severe inflammation of the kidneys (acute nephritis). Besides, magnesium sulfate is also used as a laxative to relieve occasional constipation.
使用Magnesium sulfate is used widely in several industries including fertilizer, cement, textile, chemicals, and medicine. In the cement industry, it is used in manufacturing oxysulfate cement. In medicine, it is an analgesic and cathartic. An important application of anhydrous magnesium sulfate in the laboratory involves drying organic solvents required for syntheses and GC analysis. In the textile industry, magnesium sulfate is used in finishing composition for dressing cotton; for weighting and sizing silk; as a mordant for fixing basic dyestuffs on wool; and in fireproofing fabrics. It also is a component of certain types of electrolytic plating baths; of various photographic solutions; of cosmetic lotions. It is a catalyst carrier; a dietary supplement in cattle feed; a coagulant for rubber and plastic; and is used in making citric acid and several magnesium salts, such as magnesium stearate.
一般的な説明Magnesium sulfate is an anhydrous magnesium salt.
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化学的特性硫酸マグネシウムは化学式MgSO4で表される無機化合物です水に良く溶け無色の結晶または粉末の形で存在します自然界ではエプソム塩としても知られておりその名前はイギリスのエプソムという町から来ています
化学的特性Magnesium sulfate (MgS04) is a colorless crystal with a bitter, saline taste. It is soluble in glycerol and used in fireproofing, textile processes, ceramics, cosmetics, and fertilizers.
化学性质水に易溶。多くの水和物が存在する。
使用用途硫酸マグネシウムは、安全性の高い化学物質として広く使用されています。 1. 肥料 農薬としての用途には、1水和物が主に使用されます。 2. 入浴剤 欧米では、硫酸マグネシウムは入浴剤として古くから使用されてきました。温熱効果や痛みを和らげる効果が期待されています。 3. 下剤・浣腸剤 硫酸マグネシウムは、速効性のある塩類下剤です。医薬用として古くから用いられており、腸内の水分吸収を抑えます。 4. 有機合成化学 硫酸マグネシウムは水との親和性が高いことから、有機化学合成実験において乾燥剤として使用されます。 5. その他 硫酸マグネシウムは、海水中に含まれる成分の1つです。豆腐を凝固させるにがり中にも少量含まれています。
製造方法Hydrated magnesium sulfate occurs in nature as the minerals kieserite and epsomite. The salt is mined in large scale from these and other naturally occurring minerals. The salt also is prepared in the laboratory by the action of sulfuric acid on magnesium oxide, hydroxide, or carbonate followed by evaporation and crystallization: MgO + H2SO4 → MgSO4 + H2O Mg(OH)2 + H2SO4 → MgSO4 + 2H2O MgCO3 + H2SO4 → MgSO4 + CO2 + H2O Crystallization at temperatures between 1.8 and 48°C yields heptahydrate, MgSO4•7H2O. Below 1.8°C, a dodecahydrate , MgSO4•12H2O crystallizes out. Above 48°C crystals of lower hydrates form. The anhydrous salt is obtained by heating the heptahydrate at about 500°C in a rotary drum; or dehydrating above 150°C in the presence of sulfuric acid.
Magnesium sulfate is widely distributed in nature, e.g. in salt deposits as kieserite, as Epsom salt MgSO4 . 7H20, in the form of double salts such as kainite 4KCl . 4MgSO4 . 11H20 and langbeinite K2SO4 . 2MgSO4, and in brines. Large quantities of kieserite, Epsom salt and anhydrous magnesium sulfate are produced in the processing of potassium salts. Magnesium sulfate is also produced by reacting magnesium carbonate or seawatermagnesium hydroxide with sulfuric acid.
合成方法酸化マグネシウムまたは塩基性炭酸マグネシウムを硫酸に溶解し、結晶を析出させる
純化方法Crystallise it from warm H2O (1g/mL) by cooling. Dry the heptahydrate (Epsom salt) at ~250o until it loses 25% of its weight. Its solubility in H2O is 36% at 20o, 55% at 60o and 74% at 100o; above 110o the solubility decreases with rise of temperature. Store it in a sealed container.
定義本品は、硫酸(*)のマグネシウム塩であり、次の化学式で表される。参照表示名称:硫酸
定義ChEBI: A magnesium salt having sulfate as the counterion.