Sulfonium, triphenyl-, 7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonate (1:1)

HCID 21930749

ノート反応

部分構造検索類似構造を探す

基本情報

CAS: 227199-92-0
標準SMILES: CC1(C)C2CCC1(CS(=O)(=O)[O-])C(=O)C2.c1ccc([S+](c2ccccc2)c2ccccc2)cc1
InChIKey: FJALTVCJBKZXKY-UHFFFAOYSA-M
分子式: C28H30O4S2
平均分子量: 494.7 g/mol
単同位体質量: 494.15855178

名称と識別子

優先名称: Sulfonium, triphenyl-, 7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonate (1:1)
IUPAC: (7,7-dimethyl-2-oxo-1-bicyclo[2.2.1]heptanyl)methanesulfonate;triphenylsulfanium
英語名: Triphenylsulfonium 10-Camphorsulfonate
分子式: C28H30O4S2
分子量: 494.66

名称と別名

227199-92-0SULFONIUM, TRIPHENYL-, 7,7-DIMETHYL-2-OXOBICYCLO[2.2.1]HEPTANE-1-METHANESULFONATE (1:1)DTXSID70889142Sulfonium, triphenyl-, 7,7-dimethyl-2-oxobicyclo(2.2.1)heptane-1-methanesulfonate (1:1)RefChem:186597DTXCID501028410Triphenylsulfonium 10-CamphorsulfonateMFCD34597914Triphenylsulfonium (7,7-dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonatetriphenylsulfonium camphorsulfonateSCHEMBL135905C28H30O4S2

名称をさらに表示

TPS- CSDYPR0429photoacid generator IIITriphenylthionyl camphorsulfonatetriphenylsulfonium camphorsul fonatetriphenylsulfanium {7,7-dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl}methanesulfonateTriphenylsulfonium 7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonate(1:1)triphenylsulfanium {7,7-dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl}methanesulfonate TPS- CS

SY251955E85417F852471(7,7-dimethyl-2-oxidanylidene-1-bicyclo[2.2.1]heptanyl)methanesulfonate;triphenylsulfanium(7,7-dimethyl-2-oxo-1-bicyclo[2.2.1]heptanyl)methanesulfonate;triphenylsulfaniumTriphenylsulfanium (7,7-dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonate

データベース識別子

CAS: 227199-92-0
PubChem CID: 21930749
DTXSID: DTXSID70889142
EC Number: 682-848-7

物性

構造計算による物性

極性表面積: 83.7 Å²
水素結合供与体数: 0
水素結合受容体数: 4
回転可能結合数: 4
重原子数: 34
形式電荷: 0
複雑度: 592

物理化学的性質

InChIKey: FJALTVCJBKZXKY-UHFFFAOYSA-M
SMILES: [S+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.C(C12CCC(CC1=O)C2(C)C)S([O-])(=O)=O
EPAの化学物質情報: 7 · Sulfonium, triphenyl-, 7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonate (1:1) (227199-92-0)

化学的性質

化学的特性White to Light yellow powder to crystal

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H301 (98.6%): Toxic if swallowed [Danger Acute toxicity, oral]；H314 (98.6%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H318 (98.6%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

P260, P264, P264+P265, P270, P280, P301+P316, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 74 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory InformationPMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

Hazard Classes and CategoriesAcute Tox. 3 (98.6%)；Skin Corr. 1B (98.6%)；Eye Dam. 1 (98.6%)

法規制情報

Regulatory InformationPMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.

安全データ

tsca: TSCA listed

化学と産業

用途と製造

General Manufacturing InformationSulfonium, triphenyl-, 7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonate (1:1): ACTIVE

応用分野 · 1 件

一般的な説明Triphenylsulfonium 10-Camphorsulfonate (TPS-CS) is a Triphenylsulfonium (TPS) based photo acid generator (PAG) that release strong sulfonic acid. In addition, the order of acidity of TPS based PAGs is Triphenylsulfonium trifluoromethane sulfonate> Triphenylsulfonium ptoluenesulfonate > Triphenylsulfonium 10-camphorsulfonate[1].

サプライヤー44 社

湖北鑫立恒化工有限公司13164644252

上海大然化学有限公司021-64478606 · [email protected]

中节能万润股份有限公司0535-6101880 · [email protected]

上海遐瑞医药科技有限公司+86-021-61551413 · [email protected]

江苏艾康生物医药研发有限公司025-66061636 19370895928 · [email protected]

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