基本情報
- CAS
21324-40-3- 標準SMILES
F[P-](F)(F)(F)(F)F.[Li+]- InChIKey
AXPLOJNSKRXQPA-UHFFFAOYSA-N- 分子式
- F6LiP
- 平均分子量
- 151.9 g/mol
- 単同位体質量
- 151.9801844
名称と識別子
- 優先名称
- Lithium hexafluorophosphate
- IUPAC
- lithium hexafluorophosphate
- 現地名
- ヘキサフルオロりん酸 リチウム
- 英語名
- Lithium hexafluorophosphate
- 分子式
- F6LiP
- 分子量
- 151.91
名称と別名
Lithium hexafluorophosphate21324-40-3Lithium hexafluorophosphate(V)LiPF6lithium,hexafluorophosphatelithium;hexafluorophosphatePhosphate(1-), hexafluoro-, lithiumT9T8DY51J3Lithium hexafluorophosphate(1-)MFCD00011096UNII-T9T8DY51J3Phosphate(1-), hexafluoro-, lithium (1:1)
名称をさらに表示
ヘキサフルオロりん酸 リチウムヘキサフルオロホスファート·リチウムヘキサフルオロりん酸リチウムリチウム·ヘキサフルオロホスファートヘキサフルオロ酸リチウム六フッ化リン酸リチウムヘキサフルオロリン酸リチウム 溶液ヘキサフルオロりん酸リチウム (99.9+%-Li)1.0 M LiPF6 DMCPurelytePowerlyte1.0 M LiPF6 PC1.0 M LiPF6 DEC1.0 M LiPF6 EMC1.0 M LiPF6 MEC1.0 M LiPF6 EC/DMC
EINECS 244-334-7Lithium hexafluorophosphate (Battery Grade)EC 244-334-7F6LiPLithium phosphorus fluorideLithiumhexafluorophosphate(V)hexafluorophosphate lithium saltDTXSID2066698
データベース識別子
- CAS
21324-40-3- PubChem CID
- 23688915
- DTXSID
DTXSID2066698- ChEBI
CHEBI:172376- UNII
- T9T8DY51J3
- EC Number
- 244-334-7
物性
構造計算による物性
- 極性表面積
- 0 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 7
- 回転可能結合数
- 0
- 重原子数
- 8
- 形式電荷
- 0
- 複雑度
- 67
実験および物理化学的性質
Density1.5 @25 °C
Melting Point200 °C
Physical Description
Liquid; CBI; Other Solid; Dry Powder
White to almost white hygroscopic powder; [Acros Organics MSDS]
物理化学的性質
- 融点
- 200 °C · 200 °C (dec.) (lit.)
- 沸点
- 90 °C · 90°C
- 比重(密度)
- 1.5 g/mL · 1.5 g/mL (lit.)
- 闪点
- 25 °C · 25 °C
- 貯蔵温度
- Inert atmosphere,Room Temperature
- 溶解性
- 2 O: · H2O: わずかに溶ける(lit.)
- 外見
- 粉
- 比重
- 1.5 · 1.50
- 色
- 50 · APHA: <50
- 水溶解度
- 溶ける
- 安定性
- 安定していますが、水や湿った空気にさらされると容易に加水分解します。強力な酸化剤、強酸とは相容れない。
- InChI
- 1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1
- InChIKey
- AXPLOJNSKRXQPA-UHFFFAOYSA-N
- SMILES
- [Li+].F[P-](F)(F)(F)(F)F
- CAS データベース
- 21324 · 21324-40-3(CAS DataBase Reference)
- EPAの化学物質情報
- Phosphate(1-), hexafluoro-, lithium (21324-40-3)
化学的性質
化学的特性white crystalline powder
安全と法規制
GHS分類
GHS Classification
Danger
H301 (79.7%): Toxic if swallowed [Danger Acute toxicity, oral]；H302 (20.3%): Harmful if swallowed [Warning Acute toxicity, oral]；H311 (16.2%): Toxic in contact with skin [Danger Acute toxicity, dermal]；H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H318 (69.9%): Causes serious eye damage [Danger Serious eye damage/eye irritation]；H372 (81.8%): Causes damage to organs through prolonged or repeated exposure [Danger Specific target organ toxicity, repeated exposure]
P260, P262, P264, P264+P265, P270, P280, P301+P316, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P321, P330, P361+P364, P363, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 296 reports by companies from 22 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
危険有害性情報
Regulatory Information
Chemical: Phosphate(1-), hexafluoro-, lithium
Phosphate(1-), hexafluoro-, lithium (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Phosphate(1-), hexafluoro-, lithium (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.
Status: Active Update: 02-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/13201
Hazards SummaryCauses burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; Harmful by ingestion; Toxic by skin absorption; [Acros Organics MSDS] See FLUORIDES.
Hazard Classes and CategoriesAcute Tox. 3 (79.7%)；Acute Tox. 4 (20.3%)；Acute Tox. 3 (16.2%)；Skin Corr. 1A (100%)；Eye Dam. 1 (69.9%)；STOT RE 1 (81.8%)
安全と保護具
Exposure Control and Personal Protection
Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)
1.0 [mg/m3], inhalable fraction, as F (0.2 mg/m3, inhalable fraction, as Li)[German Research Foundation (DFG)]
Threshold Limit Values (TLV)2.5 [mg/m3], as F
Permissible Exposure Limit (PEL)2.5 [mg/m3], as F
Protective Action Criteria (PAC)
0.90 [mg/m3]
9.9 [mg/m3]
59 [mg/m3]
Immediately Dangerous to Life or Health (IDLH)250.0 [mg/m3], as F
毒性情報
Adverse EffectsDermatotoxin - Skin burns.；Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors.
法規制情報
Regulatory Information
Chemical: Phosphate(1-), hexafluoro-, lithium
Phosphate(1-), hexafluoro-, lithium (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Phosphate(1-), hexafluoro-, lithium (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.
Status: Active Update: 02-11-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/13201
安全データ
- F
- 3-10
- wgk
- 3
- tsca
- TSCA listed
- ridadr
- UN 3260 8/PG 1
- hs_code
- 28269020
- risk_code
- 34-24-22-37-10-48/23/24/25-35-11
- 安衛法
- 57,57-2
- hazard_code
- C,Xi,T,F
- hazard_note
- Irritant/Hygroscopic
- safety_code
- 26-36/37/39-45-28A-16
- hazard_class
- 8
- packing_group
- II
- Hazard Classifications
- Acute Tox. 3 OralSkin Corr. 1ASTOT RE 1 Inhalation
- ストレージクラス
- 6.1B - Non-combustible acute toxic Cat. 1 and 2very toxic hazardous materials
化学と産業
用途と製造
U.S. Production2023: 10,000,000 - <25,000,000 lb；2022: 8,500,000 - <10,000,000 lb；2021: 4,000,000 - <5,500,000 lb；2020: 1,000,000 - <5,000,000 lb
Consumer UsesIon exchange agent；Conductive agent
Industry UsesConductive agent；Ion exchange agent
General Manufacturing Information
Services；Other (requires additional information)；All Other Chemical Product and Preparation Manufacturing；Transportation Equipment Manufacturing；Electrical Equipment, Appliance, and Component Manufacturing
Phosphate(1-), hexafluoro-, lithium (1:1): ACTIVE
応用分野
用途ヘキサフルオロリン酸リチウムは、炭酸プロピレンや 1,2-ジメトキシエタンなどの有機溶媒に溶け、リチウム電池の電解液として使われる。 有機合成において、3級アルコールのテトラヒドロピラニル化における触媒に用いることができる。
使用Lithium hexafluorophosphate (LiPF6) is the most widely used solute in liquid and gelled-type electrolytes，which has good solubility in various solvents such as PC (propylene carbonate) .
一般的な説明Lithium hexafluorophosphate solution in ethylene carbonate and ethyl methyl carbonate is a class of electrolytic solution that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
上流・下流製品情報
上流原料
下流製品
サプライヤー100 社
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
河北创海生物科技有限公司+86-86-13131129325 · [email protected]
湖南嘉航医药科技有限公司85521272 15200744171 · [email protected]
T&W GROUP021-61551611 13296011611 · [email protected]
Hebei Yanxi Chemical Co., Ltd.+86-17531190177 · [email protected]
科瑞迪化学400-821-5857 021-64326257 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
阿法埃莎（中国）化学有限公司400-6106006 · [email protected]
太原市瑞和丰科贸有限公司+86 351 7031519 · [email protected]
上海德默医药科技有限公司400-021-7337 2355568890 · [email protected]
安耐吉化学&3A（安徽泽升科技股份有限公司）400-0056266 · [email protected]
Allfluoro Pharmaceutical Company Limited+86-400-0216110 +86-15958047586 · [email protected]
上海钰康生物科技有限公司+86-18930848214 +86-021-56762820 · [email protected]
嘉兴市艾森化工有限公司0573-85285100 18627885956 · [email protected]
Pure Chemistry Scientific Inc.001-857-928-2050 or 1-888-588-9418 · [email protected]
孝感深远化工有限公司15527621225; 15527621225 · [email protected]
山东西亚化学有限公司13355009207 13355009207 · [email protected]
玛雅试剂+86 (573) 82222445 (0)18006601000 452520369 · [email protected]
四川库利南科技有限公司400-1166-196 18981987031 · [email protected]
天津希恩思生化科技有限公司400 638 7771 · [email protected]
赛默飞世尔科技（中国）有限公司800-810-5118 · [email protected]
上海遐瑞医药科技有限公司+86 21 61551611
TCI AMERICA800-4238616 · [email protected]
TOKYO CHEMICAL INDUSTRY CO., LTD.03-36680489 · [email protected]
TCI Europe320-37350700 · [email protected]
成都麦卡希化工有限公司028-85632863 18108198598 · [email protected]
Xunteng International Trading Co.,Limited—
上海将来实业股份有限公司021-61552785 · [email protected]
安徽科迪达化工有限公司0554-2106669 · [email protected]
HBCChem, Inc.+1-510-219-6317 · [email protected]
上海笛柏生物科技有限公司400-008-9730,021-54359730 400-008-9730 · [email protected]
成都零六生物科技有限公司400-1166-196 13458535857 · [email protected]
上海御略医药科技有限公司021-60345187 13671753212 · [email protected]
上海麦克林生化科技股份有限公司15221275939 15221275939 · [email protected]
济南朗化化工有限公司0531-85906691 18660816586 · [email protected]
上海有朋化工有限公司021-69005955 13701776567 · [email protected]
北京海力扬化学科技有限公司13718199399 · [email protected]
北京欣赛维化学科技有限公司010-56218822 13717722232 · [email protected]
四川海诺威科技有限公司13708085536 13708085536 · [email protected]
上海凯赛化工有限公司021-33516722 13701817765 · [email protected]
上海彤源化工有限公司021-021-69182866 13701855675 · [email protected]
成都润泽本土化工有限公司13096311329 028-88469284 616445927 · [email protected]
北京华扬致成科技有限公司13716033033 · [email protected]
上海蓝润化学有限公司021-69515658 ; 69515628 13701998368 · [email protected]
上海容立化学科技有限公司021-69992220 13701886816 · [email protected]
上海康拓化工有限公司021-69185552 13701777608 · [email protected]
湖北巨胜科技有限公司027-59599241 18871490274 · [email protected]
池州凯隆进出口贸易有限公司[email protected]
Sigma-Aldrich西格玛奥德里奇(上海)贸易有限公司021-61415566 800-8193336 · [email protected]
桦特昇生物科技（武汉）有限公司027-59207879 1972026995 18140587686 · [email protected]
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