ネオン
ネオン · ネオンガス · Neガス · 10Ne · NEON · neongas · neon(0) · neon atom

識別子と物理属性
| CAS No. | 7440-01-9 |
|---|---|
| 分子式 | Ne |
| 平均分子量 | 20.18 g/mol |
| 単同位体質量 | 19.99244018 g/mol |
| SMILES | [Ne] |
| InChIKey | GKAOGPIIYCISHV-UHFFFAOYSA-N |
| PubChem CID | 23935 |
| ChEBI | CHEBI:33310 |
| EC No. | 231-110-9 |
| DTXSID | DTXSID0064678 |
| 現地名 | ネオン |
化学・物理的性質
| 極性表面積 | 0 |
|---|---|
| 水素結合供与体数 | 0 |
| 水素結合受容体数 | 0 |
| 回転可能結合数 | 0 |
| 重原子数 | 1 |
| 形式電荷 | 0 |
| 複雑度 | 0 |
| 物質分類 | Toxic Gases & Vapors -> Simple Asphyxiants |
| SpringerMaterials Properties | thermal expansion coefficient |
| LogP(分配係数) | log Kow = 0.28 |
| 臭い | Odorless |
| 味 | Tasteless |
| 密度 | 0.825 g/LGAS: density: 0.899994 kg/cu m at 0 °C (101.3 kPa): 9.552 kg/cu m (normal BP)SOLID: normal density: 1444 kg/cu m (triple point)Heat of vaporization: 2.139 kJ/mol (triple point)Heat of fusion: 0.335 kJ/mol (triple point)1.204 @ BP0.9002(0℃) |
| Color/Form | Colorless gasMonoatomic, inert ... Does not condense at the temperature of liquid airsolid at the temperature of liquid hydrogenthe solid form exists as face-centered cubic crystals at normal pressure |
| 溶解度 | NegligibleSolubility of gas in water (20 °C): 10.5 cu cm/kg waterSolubility in water: very poorslightly soluble in H2O10.5mL/100g H2O (20℃, 101.32kPa) [KIR78]ヘンリーの法則定数, k×104:13.023(70.0℃)、12.022(124.5℃)、9.805(174.5℃)、7.166(226.4℃)、4.160(283.7℃)【POT78】 |
| 沸点 | -246.053 °C-246.1 °C-245.9 °C @760 [mm Hg]−246 °C(lit.) |
| 融点 | -248.609 °C triple point (43 kPa)-248.7 °C-248.67 °C-248.67 °C(lit.) |
| 蒸気密度 | 0.6964 (Air = 1)Relative vapor density (air = 1): 0.690.7 (21 °C, vs air) |
| Physical Description | Neon appears as a colorless odorless noncombustible gas. Chemically inert. The vapors are lighter than air. Nontoxic, but can act as a simple asphyxiant. Exposure of the container to prolonged heat or fire may cause it to rupture violently and rocket. Principal use is to fill lamp bulbs and tubes.Neon, refrigerated liquid (cryogenic liquid) appears as a colorless, odorless, extremely cold liquid. Rapidly evolves into neon gas. Nontoxic and chemically inert. May act as an asphyxiate by displacement of oxygen. Contact with the liquid may cause frostbite. Exposure of container to prolonged heat or fire may cause violent rupture and rocket.A colorless odorless noncombustible gas[CAMEO]COLOURLESS ODOURLESS COMPRESSED GAS. |
| 外観・状態 | 無色のガス |
| 色 | colorless |
| 比熱容量 | Cp(gas): 1.03 J/(g·K), at 25℃ |
| Merck | 13,6483 |
| ヘンリー定数 | 4.5×10-6 mol/(m3Pa) at 25℃, Fernández-Prini et al. (2003) |
| 誘電率 | 1.000127(20.0℃) |
| 安定性 | 安定。非常に無反応。 |
| InChI | InChI=1S/Ne |
| InChIKey | GKAOGPIIYCISHV-UHFFFAOYSA-N |
| SMILES | [Ne] |
| EPAの化学物質情報 | Neon (7440-01-9) |
化学的特性
Neon is an inert, colorless, odorless, tasteless gas or liquid.
安全性と法規制
| GHS 分類 | WarningH280 (62.6%): Contains gas under pressuremay explode if heated [Warning Gases under pressure]P282, P336+P317, P403, and P410+P403 (click each P-code to see the statement)Aggregated GHS information provided per 430 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| 規制情報 | Chemical: NeonNeon: Non hazardousThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| その他の安全情報 | IMAP assessments - Neon: Human health tier I assessment |
| 輸送ラベル(DOT) | Non-Flammable Gas |
| 火災危険 | Excerpt from ERG Guide 120 [Gases - Inert (Including Refrigerated Liquids)]:· Non-flammable gases.Not combustible. Heating will cause rise in pressure with risk of bursting. |
| 健康有害性 | Excerpt from ERG Guide 120 [Gases - Inert (Including Refrigerated Liquids)]:· Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas. |
| 有害性の概要 | Simple asphyxiantEvaporating liquid can cause frostbite[ICSC] |
| 輸送番号・ガイド(DOT) | 1065 1201913 120 |
| FDA 要件 | Diagnostic Devices. A neon gas analyzer is a device intended to measure the concentration of neon in a gas mixture exhaled by a patient. The device may use techniques such as mass spectrometry or thermal conductivity. |
| 反応性グループ | Not Chemically Reactive |
| UN 分類 | UN Hazard Class: 2.2 |
| Reactivity Profile | These substances undergo no chemical reactions under any known circumstances. They are nonflammable, noncombustible and nontoxic. They can asphyxiate.These substances undergo no chemical reactions under any known circumstances. They are nonflammable, noncombustible and nontoxic. They can asphyxiate. Contact of very cold liquefied gas with water may result in vigorous or violent boiling of the product and extremely rapid vaporization due to the large temperature differences involved. If the water is hot, there is the possibility that a liquid "superheat" explosion may occur. Pressures may build to dangerous levels if liquid gas contacts water in a closed container [Handling Chemicals Safely 1980]. |
用途
解説
元素記号 Ne ,原子番号 10,原子量 20.1797。周期表 18族,希ガス元素の1つ。ネオンは,大気中に 0.00182%含まれ,液体空気の分留によって得られる。1898年イギリスのW・ラムゼーらが液体空気の分留の過程でクリプトンに続いて発見し、新しい気体元素の意から、ギリシア語で「新しい」を意味するネオンneonに由来して命名した。乾燥大気中には容量で約1.8ppm含まれている。希ガス元素中ではヘリウムに次いで沸点・融点が低く、空気液化後の残存気体から加圧冷却、吸着などの操作によって精製される。単体は無色,無臭の単原子気体で,沸点-245.9℃,臨界温度-228.7℃,臨界圧 28.86気圧。化学的にきわめて安定。ガイスラー管で容易に放電し,赤色の輝線スペクトルを発するので,ネオン管用に広く使われている。低圧気体での放電によって赤色の輝線スペクトルを発し、他の希ガス気体あるいは水銀蒸気などとの混合気体での放電によってさまざまな色調の発光を示す。ネオンサイン、放電管、溶接保護ガスなどに利用される。
解説
Ne.原子番号10の元素.電子配置[He]2s22p6の周期表18族希ガス元素の一つ.原子量20.1797(6).質量数20(90.48(3)%),21(0.27(1)%),22(9.25(3)%)の3種の安定同位体と,質量数16~32,34の放射性同位体が知られている.ネオンは,1898年にW. Ramsay(ラムゼー)とM.W. Traversにより,液体空気中に発見され,ギリシア語の“新しい”を意味するνεοζ"(neos)から命名された.大気中に65000:1の割合で微量存在し,液体空気の分留により得られる.無色,無臭の気体.融点24.48 K,沸点27.10 K.臨界定数44.49 K,2.6786 MPa,0.48192 g mL-1.液体の密度1.2070 g cm-3(沸点).蒸発熱(沸点)1.7326 kJ mol-1.第一イオン化エネルギー21.564 eV.化学的には不活性である.普通の意味の化合物はフッ化物を含め,まだ確認されていない.理論的にも存在は疑問視されている.低圧放電により赤橙色に強く光るので,ネオンサイン用にもっとも多く用いられる.そのほか,指示灯,電子管用充填ガス,冷媒などとして用いられる.森北出版「化学辞典(第2版)
説明
In 1898, Dr William Ramsay and Morris M. Travers, a Scottish scientist and a British scientist, respectively, discovered neon as a condensation product in liquefied air, as in a process similar to that used to collect neon today. Neon’s use in lighting evolved from discoveries that gases under low pressure conduct electricity. When some flowing electrons collide with residual gas in an evacuated glass tube, the resulting ions emit light as they return to their nonexcited state. The color of the light depends on the residual gas; neon gas produces a red color and argon, another inert gas often used in tubes (which are frequently and incorrectly called neon lights), produces a blue color. These two basic colors are often modified into many different hues by the addition of such elements as mercury and cadmium. The neon found on the Earth is considered to be primordial in origin. Most of the neon is sequestered in the Earth’s rocks or dissolved in water, with small amounts escaping into the atmosphere during geologic weathering. The escaped gas is slowly lost into space faster than it is replenished. Consequently, neon constitutes only a small part (0.0018%) of the Earth’s atmosphere, although this element is estimated to be the fourth most abundant in the universe.
天然物の起源
Neon is the fourth most abundant element in the universe, but it makes up only 18.18ppm of the Earth’s atmosphere. It is the 82nd most abundant element on Earth. Neon is believed to be produced by radioactive decay deep in the Earth. As it rises to thesurface, it escapes into the atmosphere and is soon dissipated. Some neon is found mixed withnatural gas and several minerals. Neon is produced as a secondary product of the fractional distillation of liquid nitrogenand oxygen. Air is liquefied, and as it warms, nitrogen and oxygen boil off, leaving behindseveral other colder gases, including about 75% neon, which is then passed through activatedcharcoal to remove hydrogen and other gases.
製法・合成法
純化方法
Pass the gas through a copper coil packed with 60/80 mesh 13X molecular sieves which is cooled in liquid N2, or through a column of Ascarite (NaOH-coated silica adsorbent).