硫酸鉛(II)

Lead sulfate

HCID 24008CAS 15739-80-7

基本情報

標準SMILES
O=S(=O)([O-])[O-].[Pb+2]
InChIKey
KEQXNNJHMWSZHK-UHFFFAOYSA-L
分子式
PbSO4
平均分子量
303 g/mol
単同位体質量
303.92838158

概要

Lead sulfate appears as a white crystalline solid. Insoluble in water and sinks in water. Contact may irritate skin, eyes, and mucous membranes. May be mildly toxic by ingestion, inhalation and skin absorption. Used to make other chemicals. Use: in lithography, battery acid solution treated fabrics, used in varnishes.

名称と識別子

優先名称
Lead sulfate
IUPAC
lead(2+) sulfate
現地名
硫酸鉛(II)
英語名
LEAD(II) SULFATE
分子式
O4PbS
分子量
303.26

名称と別名

LEAD SULFATELead sulphateAnglisliteanglesiteMulhouse WhiteLead BottomsLead monosulfateFast WhiteMilk WhiteNatural anglesiteFreemans White LeadLead(+2) sulfate
名称をさらに表示
ファーストホワイトアングレサイトアングリスリット鉛ボトムス硫酸鉛(II)C.I.ピグメントホワイト3ムルハウスホワイトミルクホワイト硫酸第一鉛フリーマンズホワイト鉛アングリスライト硫酸鉛(II),3N硫酸(II)硫酸鉛硫酸鉛(Ⅱ)三塩基性硫酸鉛硫酸鉛(II), 99%ci77630milkwhitec.i.77630fastwhiteC.I. 77630Bleisulfat
Tetrabasic lead sulfateSulfate de plombTS 100 (sulfate)Lead(II) Sulfate (1:1)Lead sulfate, tetrabasicHB 2000CI 77630PbSO4

データベース識別子

CAS
15739-80-7、52732-72-6、7446-14-2、90583-07-6
PubChem CID
24008
DTXSID
DTXSID50883502
UNII
C516H654O8
EC Number
231-198-9、239-831-0、258-142-6、292-204-3
Nikkaji
J3.738I

物性

構造計算による物性

極性表面積
88.6 Ų
水素結合供与体数
0
水素結合受容体数
4
回転可能結合数
0
重原子数
6

実験および物理化学的性質

Chemical Classes · 2 件

Metals -> Lead Compounds, Inorganic

Carcinogens

Density · 3 件

6.2 at 68 °F (USCG, 1999) - Denser than water; will sink

6.2 g/cu cm

6.2 @25 °C

Color/Form · 2 件

White, heavy crystal powder

White monoclinic or rhombic crystals

Solubility · 3 件

In water, 0.0404 g/100 mL at 25 °C; slightly soluble in alkaline solutions.

Soluble in about 2225 parts water; more soluble in nitric acid; soluble in sodium hydroxide, ammonium acetate or tartrate solution; soluble in concentrated hydriodic acid; insoluble in alcohol.

In water, 32 mg/L at 15 °C

DecompositionWhen heated to decomposition it emits very toxic fumes /of lead and sulfur oxides./
Melting Point · 3 件

2138 °F (USCG, 1999)

1170 °C

1087 °C

物理化学的性質

融点
1170 °C · 1170 °C
比重(密度)
6.2 g/mL · 6.2 g/mL at 25 °C(lit.)
溶解性
insoluble in acid solutions; slightly soluble in alkaline solutions
外見
粉末・塊
比重
6.2 · 6.2
色
白い

化学的性質

化学的特性white crystals or powder

安全と法規制

GHS分類

GHS Classification · 6 件

Danger

H302+H332 (59.1%): Harmful if swallowed or if inhaled [Warning Acute toxicity, oral; acute toxicity, inhalation]

P203, P260, P261, P264, P270, P271, P273, P280, P301+P317, P304+P340, P317, P318, P319, P330, P391, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 215 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H351: Suspected of causing cancer [Warning Carcinogenicity]

危険有害性情報

Regulatory Information · 6 件

Chemical: Sulfuric acid, lead(2+) salt (1:1)

Chemical: Sulfuric acid, lead salt

Chemical: Sulfuric acid, lead salt, tetrabasic

Sulfuric acid, lead(2+) salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, lead(2+) salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Sulfuric acid, lead salt, tetrabasic is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, lead salt, tetrabasic are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Sulfuric acid, lead salt (1:?) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, lead salt (1:?) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Other Safety Information · 3 件

IMAP assessments - Selected lead-based pigments: Human health tier II assessment

IMAP assessments - Selected lead-based pigments: Human health tier II assessment

IMAP assessments - Selected lead-based pigments: Human health tier II assessment

DOT LabelCorrosive
Fire Hazards · 2 件

Special Hazards of Combustion Products: Toxic metal fumes (USCG, 1999)

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Fire PotentialNot flammable
Health Hazards · 2 件

INHALATION: Joint and muscle pains, headache, dizziness and insomnia. Weakness, frequently of extensor muscles of hand and wrist (unilateral or bilateral). Heavy contamination. Brain damage. Stupor progressing to coma - with or without convulsion, often death. Excitation, confusion, and mania less common. Cerebrospinal pressure may be increased. EYES: Caused a moderat purulent reaction and general inflammation of the rabbit eye. INGESTION: Abdominal pain, diarrhea, constipation, loss of appetite, muscular weakness, headache, blue line on gums, metallic taste, nausea and vomiting. (USCG, 1999)

· TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death.

安全と保護具

Fire FightingExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Accidental Release Measures · 2 件

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 件

Get medical aid.

General First Aid:

Exposure Control and Personal Protection · 2 件

· Wear positive pressure self-contained breathing apparatus (SCBA).

Biological Exposure Indices (BEI) [ACGIH] - Lead in blood = 200 ug/L (20 ug/100 ml); sampling time not critical; [ACGIH]

Fire Fighting Procedures · 3 件

If material involved in fire: Extinguish fire using agent suitable for type of surrounding fire (material itself does not burn or burns with difficulty). Use water in flooding quantities as fog. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible.

Use water in flooding quantities as fog. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. /Lead sulfate (containing more than 3% free acid)/

Lead sulfate is not combustible. Use dry chemical, carbon dioxide, water spray, or foam extinguishers ... If material or contaminated runoff enters waterways, notify downstream health and fire officials and pollution control agencies. From a secure, explosion-proof location, use water spray to cool exposed containers. If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of deforming), withdraw immediately to a secure position.

Storage Conditions · 1 件

Lead sulfate must be stored to avoid contact with oxidizers (such as perchlorates, peroxides, permanganates, chlorates, and nitrates) and chemically active metals (such as potassium, sodium, magnesium, and zinc) since violent reactions occur ... A regulated, marked area should be established with this chemical is handled, used, or stored ...

毒性情報

TreatmentLead poisoning is usually treated with chelation therapy using DMSA, EDTA, or dimercaprol. (L21)
Health Effects · 1 件

Lead is a neurotoxin and has been known to cause brain damage and reduced cognitive capacity, especially in children. Lead exposure can result in nephropathy, as well as blood disorders such as high blood pressure and anemia. Lead also exhibits reproductive toxicity and can results in miscarriages and reduced sperm production. (L21)

Ecotoxicity Values · 5 件

LC50; Species: Chlorella pyrenoidosa (Green algae, strain No. 366); Conditions: freshwater, static, 24 °C, pH 6.5; Concentration: 25 ug/L for 14 days /100% purity/

LC50; Species: Daphnia magna (Water flea, <24 hr neonate); Conditions: freshwater, static, pH 7.5-9.1; Concentration: 392 ug/L for 48 hr /100% purity finely ground dust/

LC50; Species: Daphnia magna (Water flea, <24 hr neonate); Conditions: freshwater, static, pH 7.5-9.1; Concentration: 3166000 ug/L for 48 hr /as total lead ion/

LC50; Species: Cynoglossus joyneri (Red Tongue Sole, larvae); Conditions: saltwater, static; Concentration: 1000 ug/L for 72 hr /total lead ion/

For more Ecotoxicity Values (Complete) data for LEAD SULFATE (7 total), please visit the HSDB record page.

Environmental Fate · 3 件

TERRESTRIAL FATE: It was reported that after adding 3,000-4,000 mg/kg of lead in the form of PbSO4 to soil, subsequent extractions revealed that the lead sulfate was rapidly transformed to other lead compounds in the soil(1).

AQUATIC FATE: If released into water, lead sulfate will mostly precipitate out due to its low solubility. (SRC)

ATMOSPHERIC FATE: In the atmosphere, lead most likely exists primarily as PbSO4 and PbCO3 and is deposited onto soil as lead sulfates and lead carbonates(1). Lead sulfate is a major species of lead in the atmosphere, either being emitted in that form or possibly being formed from the sulfide or other lead species with atmospheric SO2 and oxygen. Lead sulfate is expected to exist solely in the particulate phase in the ambient atmosphere, and will be subject to washout and gravitational settling. Transformations in the atmosphere to the carbonate and oxide may be expected(2).

Adverse EffectsNeurotoxin - Predominantly motor
Exposure RoutesOral (L136) ; inhalation (L136); dermal (L136)

法規制情報

RCRA Requirements · 2 件

D008; A solid waste containing lead may or may not become characterized as a hazardous waste when subjected to the Toxicity Characteristic Leaching Procedure listed in 40 CFR 261.24, and if so characterized, must be managed as a hazardous waste. /Lead/

The Environmental Protection Agency is ... /promulgated/ regulations concerning ground-water monitoring with regard to screening suspected contamination at land based hazardous waste treatment, storage, and disposal facilities. ... /There are/ new requirements to analyze for a specified core list of chemicals plus those chemicals specified by the Regional Administrator on a site-specific basis. ... /Total lead (all species) is included on this list./ /Total lead (all species)/

Atmospheric Standards · 2 件

National primary and secondary ambient air quality standards for lead and its compounds, measured as elemental lead by a reference method based on appendix G to this part, or by an equivalent method, are: 1.5 micrograms per cubic meter, maximum arithmetic mean averaged over a calendar quarter. /Lead and its compounds, as Pb/

Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Lead compounds are included on this list. /Lead compounds/

CERCLA Reportable Quantities · 1 件

Persons in charge of vessels or facilities are required to notify the National Response Center (NRC) immediately, when there is a release of this designated hazardous substance, in an amount equal to or greater than its reportable quantity of 10 lb or 4.54 kg. The toll free number of the NRC is (800) 424-8802. The rule for determining when notification is required is stated in 40 CFR 302.4 (section IV. D.3.b).

Clean Water Act Requirements · 2 件

Lead sulfate is designated as a hazardous substance under section 311(b)(2)(A) of the Federal Water Pollution Control Act and further regulated by the Clean Water Act Amendments of 1977 and 1978. These regulations apply to discharges of this substance. This designation includes any isomers and hydrates, as well as any solutions and mixtures containing this substance.

Toxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Lead and compounds/

State Drinking Water Standards(AZ) ARIZONA 50 ug/L /Lead/
State Drinking Water Guidelines · 2 件

(AZ) ARIZONA 20 ug/L /Lead/

(ME) MAINE 10 ug/L /Lead/

安全データ

wgk
3
tsca
TSCA listed
rtecs
OG4375000
ridadr
UN 1794 (LEAD SULPHATE with more than 3 % free acid)
PRTR法
特1-305
hs_code
28332960

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Lead is absorbed following inhalation, oral, and dermal exposure. It is then distributed mainly to the bones and red blood cells. In the blood lead may be found bound to serum albumin or the metal-binding protein metallothionein. Organic lead is metabolized by cytochrome P-450 enzymes, whereas inorganic lead forms complexes with delta-aminolevulinic acid dehydratase. Lead is excreted mainly in the urine and faeces. (L136)

Absorption, Distribution and Excretion · 1 件

... The lead content on the skin surface of 10 lead-battery workers was measured by the method of skin stripping, and urinary lead content of rats was measured with epicutaneous application of four lead compounds: lead sulfate, lead oxide, lead powder, and lead stearate. There were significant amounts of lead on the 9th and 10th skin strippings of the dorsal hand and the back of lead workers. The amount of lead on the dorsal hand was significantly correlated with the amount in the blood (n = 10, r 2 = 0.66, p < 0.05, linear regression). In rats, after lead compounds were applied for 12 days, total lead amount in urine significantly increased to 146.0 +/- 6.4 ng (SD) for lead stearate, 123.1 +/- 7.2 ng for lead sulfate, 115.9 +/- 5.3 ng for lead oxide, 47.8 +/- 6.9 ng for lead powder, and 10.3 ng for the control, which indicated significant skin absorption. It was concluded that significant amounts of inorganic lead compounds can be absorbed through the skin, and skin protection in lead-working or any contaminated environment should be carefully considered.

用途と製造

Uses · 6 件

Used to stabilize clay soils, and to weight fabrics; Also used in galvanic batteries and rapidly drying varnishes; Has been used in lithography and with silver bromide in photography; [HSDB] Used in storage batteries and paint (pigment); [Hawley] Workers are exposed in mines and smelters and during production of lead storage batteries; [HSDB]

Battery Manufacturing [Category: Industry]

Has been used in photography in combination with silver bromide and is used in the stabilization of clay soil for adobe structures, in earth-fill dams, and roads.

Instead of white lead as pigment; with zinc in galvanic batteries; manuf minium, in lithography; preparing rapidly drying oil varnishes; weighting fabrics.[The Merck Index, Fourteenth Edition (2006)

Storage batteries, paints, ceramics, pigments, electrical and other vinyl compounds requiring high heat stability.

Lead sulphate is found in lead-acid batteries. (L416)

U.S. Production · 4 件

2023: 100,000,000 - <500,000,000 lb

2023: 10,953,825 lb

2023: 178,623,686 lb

Production volume for non-confidential chemicals reported under the 2006 Inventory Update Rule. Chemical: Sulfuric acid, lead(2+) salt (1:1). Aggreated National Production Volume: 500 million to <1 billion pounds.

Consumer Uses · 3 件

Chemical reaction regulator

Intermediate

Intermediate

Industry Uses · 3 件

Intermediate

Other

Intermediate

Methods of Manufacturing · 2 件

Treating lead oxide, hydroxide, or carbonate with warm sulfuric acid, or by treating a soluble lead salt with sulfuric acid.

Interaction of solutions of lead nitrate and sodium sulfate.

General Manufacturing Information · 6 件

Other (requires additional information)

Electrical Equipment, Appliance, and Component Manufacturing

Electrical Equipment, Appliance, and Component Manufacturing

Sulfuric acid, lead(2+) salt (1:1): ACTIVE

Sulfuric acid, lead salt (1:?): ACTIVE

Sulfuric acid, lead salt, tetrabasic: ACTIVE

応用分野 · 5 件

解説硫酸鉛とは、化学式PbSO4で表される硫酸イオンと鉛イオンが結合した無機物です。 物質量は303.26g/mol、密度は6.29 g/cm3、密度は1170℃です。常温常圧では、白色の固体の外見をしています。

用途ペイント顔料,釉薬,触媒,樹脂安定剤

使用Lead(II) sulfate is used in pigments, galvanic batteries, lithography, weighting fabrics. It is also used as intermediates.

一般的な説明A white crystalline solid. Insoluble in water and sinks in water. Contact may irritate skin, eyes, and mucous membranes. May be mildly toxic by ingestion, inhalation and skin absorption. Used to make other chemicals. Use: in lithography, battery acid solution treated fabrics, used in varnishes.

使用用途1. 鉛蓄電池 硫酸鉛は、の電極材料となる正極および負極活物質として用いられています。電極材料となる鉛が比較的安価であることから、コストパフォーマンスの高いを製造することができます。正極では二酸化鉛が、負極では鉛が電極として用いられており、どちらでも硫酸が電解液として使用されてきました。 希硫酸は水によりSO₄²⁻とH⁺に電離しており、負極では鉛が酸化されて生じた鉛イオンと硫酸イオンが反応して硫酸鉛PbSO₄を生成します。この硫酸鉛は負極表面に固体になって付着していくため、負極の質量はどんどん増加していきます。また、鉛が酸化されることで発生した電子は、導線を通って正極に送られます。 さらに、電解液中には水素イオンも放出され、水素イオンは自由電子が集まった正極に向かい、電解液中を移動することが電池の原理です。一方、正極板では負極からやって来た自由電子および水素イオンを受け入れて、二酸化鉛と希硫酸とで化学反応を起こします。その結果硫酸鉛と水が生成し、負極板と同じように硫酸鉛は正極板に付着していきます。 また、放電によって両極板の表面に付着した硫酸鉛などを利用して充電反応を起こすことで、放電する前の状態に戻して電池を繰り返し使用できるようにします。充電により正極は酸化されに、負極はされ単体の鉛となることが鉛蓄電池の性質です。 2. 顔料 硫酸鉛は、白色を示すことから古代より白色の顔料としてさまざまな場面で用いられてきました。奈良にある正倉院の宝物からも硫酸鉛が用いられている物品が発見されています。 また、硫酸鉛は、黄鉛やモリブデートオレンジのような着色顔料の原材料の1つとしても使用されることが特徴です。 3. その他 その他の用途として、釉薬、触媒、樹脂安定剤などが挙げられます。

調製方法

Lead sulfate, PbSO4, is soluble in concentrated acids and alkalies, forming hydroxyplumbites. It is prepared by treating lead oxide, hydroxide, or carbonate with warm sulfuric acid, or by treating a soluble lead salt with sulfuric acid.

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補足説明

定義anglesite: A mineral form oflead(II) sulphate, PbSO4.

関連反応

2 件

関連ノート

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