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りん酸トリアンモニウム

Ammonium dihydrogen phosphate

HCID 24402
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基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
10361-65-6
標準SMILES
O=P([O-])(O)O.[NH4+]
InChIKey
LFVGISIMTYGQHF-UHFFFAOYSA-N
分子式
H3N.H3O4P
平均分子量
115.03 g/mol
単同位体質量
115.00344467

概要

Ammonium dihydrogen phosphate is the ammonium salt of phosphoric acid (molar ratio 1:1). It has a role as a fertilizer. It contains a dihydrogenphosphate.

名称と識別子

優先名称
Ammonium dihydrogen phosphate
IUPAC
azanium dihydrogen phosphate
現地名
りん酸トリアンモニウム
英語名
TRI-AMMONIUM PHOSPHATE TRIHYDRATE
分子式
H6NO4P
分子量
115.02

名称と別名

Ammonium dihydrogen phosphate7722-76-1Ammonium biphosphateMONOAMMONIUM PHOSPHATEAmmonium dihydrogen orthophosphatePhosphoric acid, monoammonium saltAmmonium monophosphateMonoammonium orthophosphateMonoammonium acid phosphateAmmonium monobasic phosphateDihydrogen ammonium phosphateMonoammonium hydrogen phosphate
名称をさらに表示
りん酸トリアンモニウムりん酸三アンモニウム三水和物りん酸三アンモニウム三水和物(りん酸アンモニウム,第三)Einecs 233-793-9riazanium,phosphatetriazanium,phosphateAficamten Impurity 8triammmonium phosphatetriammoniumorthophosphateriammonium orthophosphateAMMONIUM PHOSPHATE TRIBASICAMMONIUM PHOSPHATE TRIHYDRATEphosphoricacid,triammoniumsalt
Ammonium primary phosphateMonoammonium dihydrogen phosphateAmmonium orthophosphate dihydrogenAmmonium phosphate, primaryMonoammonium dihydrogen orthophosphatePhosphoric acid, ammonium salt (1:1)09254QB17TCHEBI:62982

データベース識別子

CAS
10361-65-6、7722-76-1、7783-28-0
PubChem CID
24402
DTXSID
DTXSID5029689
ChEBI
CHEBI:62982
UNII
09254QB17T
EC Number
231-764-5

物性

構造計算による物性

極性表面積
81.6 Ų
水素結合供与体数
3
水素結合受容体数
4
回転可能結合数
0
重原子数
6
形式電荷
0
複雑度
49.8

実験および物理化学的性質

Chemical ClassesOther Classes -> Salts, Basic
Polymers · 2 件

Plastics -> N.a.

Plastics -> Flame retardants

CosmeticsBuffering; Oral care
pHpH of 0.2 Molar aq soln: 4.2
SpringerMaterials Propertiesthermal expansion coefficient
Odor · 2 件

Odorless

Faint acid

Food AdditivesLEAVENING AGENT, MALTING OR FERMENTING AID, PH CONTROL AGENT -> FDA Substance added to food
Density · 2 件

1.80 g/cu cm

1.803 @25 °C

Flame RetardantsFlame retardants
Color/Form · 2 件

White, tetrahedral crystals

Brilliant white crystals or powder

Solubility · 3 件

Slightly soluble in ethanol; insoluble in acetone

40.4 g/100 g water at 25 °C

1 g dissolves in about 2.5 mL water; slightly soluble in alcohol; practically insoluble in acetone

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 5 件

This chemical does not meet GHS hazard criteria for 85.8% (994 of 1158) of all reports.

Warning

H319 (12.1%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]

P264+P265, P280, P305+P351+P338, and P337+P317 (click each P-code to see the statement)

Aggregated GHS information provided per 1158 reports by companies from 16 notifications to the ECHA C&L Inventory.

危険有害性情報

Regulatory Information · 4 件

Chemical: Phosphoric acid, ammonium salt (1:1)

Phosphoric acid, ammonium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Phosphoric acid, ammonium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Ammonium dihydrogenorthophosphate (EC: 231-764-5)

Monoammonium phosphate: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Phosphoric acid, monoammonium salt: Environment tier I assessment
Hazards SummaryA skin and eye irritant that may cause respiratory tract irritation; the diammonium form of ammonium phosphate may release enough ammonia in an enclosed space to cause pulmonary edema; [CAMEO]
FDA Requirements · 2 件

Substance added directly to human food affirmed as generally recognized as safe (GRAS).

Ammonium phosphate (mono-, and dibasic) used as a general purpose food additive in animal drugs, feeds, and related products is generally recognized as safe when used in accordance with good manufacturing or feeding practice.

Special ReportsWHO; Diseases Caused by Phosphorus and Its Toxic Compounds; Early Detection of Occupational Diseases pg 53-62 (1986). Review of diseases and health related effects resulting from exposure to phosphorus or phosphorus cmpd.

化学と産業

薬理情報

BionecessityPhosphate as nutrient is a limiting factor to plant growth. /Phosphate/
Metabolism/MetabolitesA defect in phosphate metabolism occurs in a variety of diseases. ... Rickets ... Osteomalacia ... Primary or Secondary Hyperparathyroidism ... Chronic Renal Failure. /Phosphates/
MeSH Pharmacological Classification · 2 件

Substances or mixtures that are added to the soil to supply nutrients or to make available nutrients already present in the soil, in order to increase plant growth and productivity.

Substances used in the processing or storage of foods or animal feed including ANTIOXIDANTS; FOOD PRESERVATIVES; FOOD COLORING AGENTS; FLAVORING AGENTS; ANTI-INFECTIVE AGENTS; EXCIPIENTS and other similarly used substances. Many of the same substances are used as PHARMACEUTIC AIDS.

Absorption, Distribution and Excretion · 1 件

/Ortho/ phosphate is absorbed from, and to a limited extent secreted into, the gastrointestinal tract. Transport of phosphate from the gut lumen is an active, energy-dependent process that is modified by several factors. ... Vitamin D stimulates phosphate absorption, an effect reported to precede its action on calcium ion transport. In adults, about two thirds of the ingested phosphate is absorbed, and that which is absorbed is almost entirely excreted into the urine. In growing children, phosphate balance is positive. Concentrations of phosphate in plasma are higher in children than in adults. This "hyperphosphatemia" decreases the affinity of hemoglobin for oxygen and is hypothesized to explain the physiological "anemia" of childhood. /Phosphates/

用途と製造

Uses · 6 件

Used in fertilizer, matches, baking powder, and fireproofing of paper and wood products; [HSDB]

Pulp and Paper Processing [Category: Industry]

As baking powder with sodium bicarbonate; in fermentations (yeast cultures, etc.); fireproofing of paper, wood, fiberboard, etc.

Fertilizer; to prevent afterglow in matches; plant nutrient soln; manufacture of bread improvers ... analytical chemistry

関連反応

12 件
反応記録を作成
HRID 223596 の反応式
HRID 223596反応物としてuspto-grants-1982_10
HRID 244269 の反応式
HRID 244269生成物としてuspto-grants-2014_02
HRID 617668 の反応式
HRID 617668反応物としてuspto-grants-1999_09
HRID 1153947 の反応式
HRID 1153947反応物としてuspto-grants-1984_12
HRID 1252657 の反応式
HRID 1252657生成物としてuspto-grants-1988_05
HRID 1252658 の反応式
HRID 1252658生成物としてuspto-grants-1988_05
HRID 1252659 の反応式
HRID 1252659生成物としてuspto-grants-1988_05
HRID 1252660 の反応式
HRID 1252660生成物としてuspto-grants-1988_05
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化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
その他の操作
ノートを作成反応を作成見積依頼を出す
DecompositionDecomposes to ammonia and phosphoric acid when heated.

物理化学的性質

溶解性
insoluble in acetone
外見
ソリッド(概算)
色
white prisms
水溶解度
25 at · 25.0 at 25℃
EPAの化学物質情報
Phosphoric acid, triammonium salt (10361-65-6)
FIFRA Requirements · 1 件

Residues of monoammonium phosphate are exempted from the requirement of a tolerance when used in accordance with good agricultural practice as inert (or occasionally active) ingredients in pesticide formulations applied to growing crops or to raw agricultural commodities after harvest. Use: Postharvest fumigation in formulation with aluminum phosphide. Limit: No more than 3.75% by weight in formulation.

Toxic Combustion ProductsToxic and irritating fumes of ammonia and oxides of nitrogen may form in fires.
Hazard Classes and CategoriesEye Irrit. 2 (12.1%)
Hazardous Reactivities and Incompatibilities · 2 件

A self-propagating reaction can occur when either sodium bicarbonate or potassium bicarbonate-based dry chemical extinguishing agent is mixed with monoammonium phosphate dry chemical extinguishing agent. Moisture will accelerate the reaction. Products are water, ammonia, carbon dioxide and various solid substances. In a fire extinguisher the pressure developed will blow out the valve.

An explosive reaction occurred when monoammonium phosphate was used to extinguish a sodium fire. No reactions were experienced when sodium bicarbonate or potassium bicarbonate was used in a sodium fire.

安全と保護具

Disposal Methods · 1 件

SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal and plant life; and conformance with environmental and public health regulations.

Allowable Tolerances · 1 件

Residues of monoammonium phosphate are exempted from the requirement of a tolerance when used in accordance with good agricultural practice as inert (or occasionally active) ingredients in pesticide formulations applied to growing crops or to raw agricultural commodities after harvest. Use: Postharvest fumigation in formulation with aluminum phosphide. Limit: No more than 3.75% by weight in formulation.

Protective Action Criteria (PAC) · 3 件

17 [mg/m3]

190 [mg/m3]

1100 [mg/m3]

毒性情報

Human Toxicity Excerpts · 2 件

/SIGNS AND SYMPTOMS/ Acute ... eye contact with concentrated alkali causes conjunctival edema and corneal destruction. Alkalies penetrate skin slowly. Extent of damage therefore depends on duration of contact. Chronic poisoning (from skin contact). Chronic dermatitis may follow repeated contact ... /Alkalies and Phosphates/

/OTHER TOXICITY INFORMATION/ ... With large doses of ... ammonium /salts/, there arises the possibility of sufficient absorption to produce diuresis and systemic ammonia poisoning, particularly if material is administered parenterally. /Ammonium Salts/

Non-Human Toxicity Excerpts · 1 件

/LABORATORY ANIMALS: Acute Exposure/... It has been shown that solutions containing 0.1 molar ... ammonium phosphate ... at pH 7-7.5 made up to 0.46 osmolar (1.5 times isotonic concentration) by addition of sodium chloride or sucrose and dripped continuously on eyes of rabbits caused edema of epithelium of the cornea within 3-3.5 hr. /Ammonium Phosphate/

Probable Routes of Human Exposure · 1 件

According to the 2006 TSCA Inventory Update Reporting data, the number of persons reasonably likely to be exposed in the industrial manufacturing, processing, and use of ammonium dihydrogen phosphate is 1000 or greater; the data may be greatly underestimated(1).

Antidote and Emergency Treatment · 5 件

/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on the left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Ammonia and related compounds/

/SRP:/ Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for signs of pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mg/kg up to 200 ml of water for dilution if the patent can swallow, has a strong gag reflex, and does not drool ... . Do not attempt to neutralize. /Ammonia and related compounds/

/SRP:/ Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in severe respiratory distress. Positive-pressure ventilation techniques with a bag-valve-mask device may be beneficial. Consider drug therapy for pulmonary edema ... . Consider administering a beta agonist such as albuterol for severe bronchospasm ... . Monitor cardiac rhythm and treat arrhythmias if necessary ... . Start IV administration of D5W /SRP: "To keep open", minimal flow rate/. Use 0.9% saline (NS) or lactated Ringer's (LR) if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors if patient is hypotensive with a normal fluid volume. Watch for signs of fluid overload ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Ammonium and related compounds/

/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Phosphorus and related compounds/

For more Antidote and Emergency Treatment (Complete) data for AMMONIUM DIHYDROGEN PHOSPHATE (6 total), please visit the HSDB record page.

RAIS Toxicity Values · 4 件

48.6

PPRTV Archive

0.09

PPRTV Current

Acceptable Daily Intakes · 1 件

FAO/WHO Expert Committee on Food Additives ... recommended ... /levels/ for total dietary phosphorus ... unconditional acceptance level /of less than 30 mg/kg body wt/ is considered safe in any type of diet ... conditional acceptance level /of 30-70 mg/kg body wt/ is acceptable only when dietary calcium level is high. /Phosphates/

Non-Human Toxicity Values · 2 件

LD50 Rabbit dermal >7940 mg/kg bw

LD50 Rat oral 5750 mg/kg bw

EPA Provisional Peer-Reviewed Toxicity Values · 5 件

Monoammonium phosphate

9 x 10^-2 mg/kg-day

PDF Document

Inadequate information to assess carcinogenic potential

2021

法規制情報

FDA Requirements · 2 件

Substance added directly to human food affirmed as generally recognized as safe (GRAS).

Ammonium phosphate (mono-, and dibasic) used as a general purpose food additive in animal drugs, feeds, and related products is generally recognized as safe when used in accordance with good manufacturing or feeding practice.

FIFRA Requirements · 1 件

Residues of monoammonium phosphate are exempted from the requirement of a tolerance when used in accordance with good agricultural practice as inert (or occasionally active) ingredients in pesticide formulations applied to growing crops or to raw agricultural commodities after harvest. Use: Postharvest fumigation in formulation with aluminum phosphide. Limit: No more than 3.75% by weight in formulation.

安全データ

tsca
TSCA listed

A common fire-extinguishing ingredient in ABC-type dry-powder extinguishers ... Used as flame retardants for cellulosic materials, including plywood, papers, and fabrics, to prevent afterglow in and to control forest fires /Ammonium phosphates/

Pure ... is used as /a/ fertilizer in irrigated greenhouses (completely water-soluble)

U.S. ExportsAbout 5.8 million tons (P2O5 basis) for crop year 1995 /Ammonium phosphates/
U.S. ImportsCrop year 1995, negligible /Ammonium phosphates/
U.S. Production · 6 件

2023: 10,000,000,000 - <15,000,000,000 lb

Ammonium phosphates. Demand: 1985-1986 (Fertilizer year): 10.07 million tons; 1986-1987 /projected/: 10.32 million tons; 1990-1991 /projected/: 12.1 million tons. /Ammonium phosphates/

Ammonium phosphates. 100% fertilizers: diammonium phosphate 85%; monoammonium phosphates 15%. Exports account for 50% of total ammonium phosphates production. /Ammonium phosphates/

Ammonium phosphates. Demand: 1988-1989 (fertilizer year): 15.25 million tons; 1989-1990 /projected/: 15.55 million tons; 1993-1994 /projected/: 17.0 million tons. (Includes exports, but not imports, which are negligible.) /Ammonium phosphates/

Production (year) in thousands of tons: (1987) 1,679; (1988) 1,818; (1989) 1,862; (1990) 2,252; (1991) 2,227; (1992) 2,342; (1993) 2,693; (1994) 2,869; (1995) 2,715; (1996) 3,332; (1997) 3,286.

For more U.S. Production (Complete) data for AMMONIUM DIHYDROGEN PHOSPHATE (8 total), please visit the HSDB record page.

Consumption Patterns · 2 件

Ammonium Phosphates. 100% fertilizers: diammonium phosphate 87% (49% domestic, 51% export); monoammonium phosphate 13% (60% domestic, 40% export). /Ammonium phosphates/

Fertilizer, 98% (DAP, 70%; MAP 23%, other solid ammonium phosphates, 5%); industrial uses, 1.5%; animal feed, 0.5%. /Ammonium phosphates/

Consumer UsesLaboratory chemicals
Industry UsesFire extinguishing agent
Methods of Manufacturing · 3 件

Monoammonium phosphate ... is produced by reaction of anhydrous ammonia and phosphoric acid in batch or continuous reactors and crystallized in conventional crystallizers because the partial pressure of ammonia over this acidic solution is relatively low. Crystals are centrifuged and dried below 100 °C in a rotary dryer, and mother liquor is returned to the reactor.

Ammonium monophosphates are produced by neutralization of phosphoric acid with ammonia. Crude or partially purified wet phosphoric acid is mostly used for fertilizer applications. However, pure thermal phosphoric acid is used preferentially for the production of commercial ammonium phosphates with an assay >99 %. /Ammonium phosphates/

By pumping dried ammonia gas into an 80% solution of phosphoric acid. Product composition is controlled by maintaining the pH at 3.8 to 4.5. When the mixture is cooled, crystals of monoammonium phosphate precipitate.

Formulations/Preparations · 5 件

Grades: Technical; CP /chemically pure: a grade designation signifying a minimum of impurities, but not 100% purity/; FCC /Food Chemicals Codex/; single crystals.

Granular product, made with wet-process acid, has a grade of about 10-53-0. Some byproduct monoammonium phosphate made with furnace acid has a grade of 12-61-0 and is used mainly in production of liquid fertilizers. Nongranular (powder) monoammonium phosphate is used in formulations for granular NP and NPK fertilizers, which it can react with additional ammonia and aid granulation.

Fertilizer grade, min 13% N, 52% P.

... Granular and nongranular (powder) forms.

Phosphoric acid is infinitely miscible with water. It is commercially available in three standard concentrations: 75% H3PO4 with 54.3% P2O5, mp -20 °C; 80% H3PO4 with 58.0% P2O5, mp 0 °C; 85% H3PO4 with 61.6% P2O5, mp +21 °C.

Household ProductsInformation on 157 consumer products that contain Ammonium phosphate, monobasic in the following categories is provided:
Use Classification · 6 件

Food Additives -> ACIDITY_REGULATOR; FLOUR_TREATMENT_AGENT; LEAVENING_AGENT; RAISING_AGENT -> JECFA Functional Classes

Food Additives -> ACIDITY_REGULATOR; FLOUR_TREATMENT_AGENT; LEAVENING_AGENT; RAISING_AGENT -> JECFA Functional Classes

Food Additives -> ACIDITY_REGULATOR; FLOUR_TREATMENT_AGENT; LEAVENING_AGENT; RAISING_AGENT -> JECFA Functional Classes

Food Additives -> ACIDITY_REGULATOR; FLOUR_TREATMENT_AGENT; LEAVENING_AGENT; RAISING_AGENT -> JECFA Functional Classes

Food Additives -> ACIDITY_REGULATOR; FLOUR_TREATMENT_AGENT; LEAVENING_AGENT; RAISING_AGENT -> JECFA Functional Classes

Plastics -> Polymer Type -> N.a.

General Manufacturing Information · 6 件

Not Known or Reasonably Ascertainable

Phosphoric acid, ammonium salt (1:1): ACTIVE

Produced in large scale as fertilizer

Pure monoammonium phosphate has a grade 12.1-61.7-0 (nitrogen-phosphorus-potassium), but is never made for fertilizer use. Made from wet-process acid, the grade for fertilizer use is typically 10-54-0 to 11-52-0, but may be as low as 10-50-0, depending on the impurity level of the starting acid.

Granular MAP can be produced in a plant similar to that used for diammonium phosphate with little process modification.

The thermal route (for making phosphoric acid starting material) results in a food-grade acid of high purity and is too expensive for fertilizer production. Essentially all the acid used in fertilizer production is made by wet processes.

上流・下流製品情報

上流原料

りん酸水素ジアンモニウムアンモニア水りん酸TRI-AMMONIUM ORTHOPHOSPHATEアンモニア

下流製品

Cyanuramide cladding ammonium polyphosphateMixed and compound fertilizerCompound fertilizer of potassium sulfate