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Zinc ammonium sulfate

HCID 24539
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
7783-24-6
標準SMILES
O.O.O.O.O.O.O=S(=O)([O-])[O-].O=S(=O)([O-])[O-].[NH4+].[NH4+].[Zn+2]
InChIKey
TXGQALXWGNPMKD-UHFFFAOYSA-L
分子式
H20N2O14S2Zn
平均分子量
401.7 g/mol
単同位体質量
399.964737

概要

Zinc ammonium sulfate is a sulfate of zinc and ammonium. Zinc is a metallic element with the atomic number 30. It is found in nature most often as the mineral sphalerite. Though excess zinc in harmful, in smaller amounts it is an essential element for life, as it is a cofactor for over 300 enzymes and is found in just as many transcription factors. (L48, L49)

名称と識別子

優先名称
Zinc ammonium sulfate
IUPAC
diazanium;zinc;disulfate;hexahydrate

名称と別名

Ammonium zinc sulfateDiammonium zinc disulfate hexahydrateF20U770J8G7783-24-6Ammonium zinc sulfate hexahydrateZinc diammonium disulfate hexahydrateSulfuric acid, ammonium zinc salt (2:2:1), hexahydrateRefChem:195989dizinc(2+) ion diammonium disulfate237-483-4Zinc ammonium sulfateUNII-F20U770J8G
名称をさらに表示
HSDB 1044ZINC AMMONIUM SULFATE [HSDB]DIAMMONIUM ZINC SULFATE HEXAHYDRATEQ27277524AMMONIUM ZINC SULFATE ((NH4)2ZN(SO4)2) HEXAHYDRATE

データベース識別子

CAS
7783-24-6
PubChem CID
24539
UNII
F20U770J8G

物性

構造計算による物性

極性表面積
185 Ų
水素結合供与体数
8
水素結合受容体数
14
回転可能結合数
0
重原子数
19
形式電荷
0
複雑度
62.2

実験および物理化学的性質

Chemical ClassesMetals -> Metals, Inorganic Compounds
Density1.931
Color/FormWHITE MONOCLINIC CRYSTALS
SolubilitySOLUBILITY (G/100 CC WATER): 7 G @ 0 °C, 42 G @ 80 °C /ANHYDROUS/
Refractive IndexINDEX OF REFRACTION: 1.489, 1.493, 1.499
Physical DescriptionWhite solid; [HSDB]
Other Experimental PropertiesDECOMP BEFORE REACHING MP

安全と法規制

安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。

危険有害性情報

Hazards SummaryIn laboratory experiments (dogs), 1 mg IV produced no adverse effects, while 100 mg IV caused hypotension, hypoxemia, and metabolic acidosis; No effects on human volunteers after short-term inhalation of aerosol; [HSDB] See Zinc.
Special Reports · 5 件

Zinc and Health. Current Bibliographies in Medicine 98-3. Public Services Division/National Library of Medicine. 3619 citations January, 1990-June, 1998. Available from: http://www.nlm.nih.gov/archive/20040831/pubs/cbm/zinc.html as of November 2, 1998.

USEPA; Ambient Water Quality Criteria Doc: Zinc (1980) EPA 400/5-80-079

USEPA; Ambient Water Quality Criteria Doc: Zinc (1987) EPA 400/5-87-003

Arvidson, B. A Review of Axonal Transport of Metals. Toxicology 88: 1-14 (19994) Recent findings regarding axonal transport of metals, including zinc.

For more Special Reports (Complete) data for ZINC AMMONIUM SULFATE (6 total), please visit the HSDB record page.

Clean Water Act Requirements · 3 件

Toxic pollutant designated pursuant to section 307(a)(1) of the Clean Water Act and is subject to effluent limitations. /Zinc and compounds/

For total recoverable zinc the criterion to protect freshwater aquatic life ... is 47 ng/l as a 24 hr average ... at hardnesses of 50, 100, and 200 mg/l as CaCO3 the concentration of total recoverable zinc should not exceed 180, 320, 570 ug/l at any time. /Soluble zinc salts/

For total recoverable zinc the criterion to protect saltwater aquatic life ... is 58 ug/l as a 24 hr average and the concentration should not exceed 170 ug/l at any time. /Soluble zinc salts/

State Drinking Water Guidelines · 2 件

(AZ) ARIZONA 5000 ug/l /Zinc/

(MN) MINNESOTA 2000 ug/l /Zinc/

Federal Drinking Water Guidelines · 2 件

EPA 5000 ug/l /Zinc/

EPA 2000 ug/l /Zinc, Lifetime health advisory/

安全と保護具

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Zinc can enter the body through the lungs, skin, and gastrointestinal tract. Intestinal absorption of zinc is controlled by zinc carrier protein CRIP. Zinc also binds to metallothioneins, which help prevent absorption of excess zinc. Zinc is widely distributed and found in all tissues and tissues fluids, concentrating in the liver, gastrointestinal tract, kidney, skin, lung, brain, heart, and pancreas. In the bloodstream zinc is found bound to carbonic anhydrase in erythrocytes, as well as bound to albumin, _2-macroglobulin, and amino acids in the the plasma. Albumin and amino acid bound zinc can diffuse across tissue membranes. Zinc is excreted in the urine and faeces. (L49)

関連反応

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化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
Exposure Control and Personal Protection0.1 [mg/m3] (respirable fraction), 2 mg/m3 (inhalable fraction) for Zn inorg. cmpnds[German Research Foundation (DFG)]
Disposal Methods · 1 件

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Minimum Risk LevelIntermediate Oral: 0.3 mg/kg/day (L134) Chronic Oral: 0.3 mg/kg/day (L134)

毒性情報

TreatmentZinc poisoning is treated symptomatically, often by administering fluids such as water or milk, or with gastric lavage. (L49)
InteractionsISOPROTERENOL PREVENTED /RESPIRATORY/ CHANGES, SUGGESTING THAT THEY WERE DUE TO SMOOTH MUSCLE CONTRACTION.
Health EffectsChronic exposure to zinc causes anemia, atazia, lethargy, and decreases the level of good cholesterol in the body. It is also believed to cause pancreatic and reproductive damage. (L49)
Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.
Exposure RoutesOral (L49) ; inhalation (L49) ; dermal (L49)
Toxicity Summary · 1 件

Anaemia results from the excessive absorption of zinc suppressing copper and iron absorption, most likely through competitive binding of intestinal mucosal cells. Unbalanced levels of copper and zinc binding to Cu,Zn-superoxide dismutase has been linked to amyotrophic lateral sclerosis (ALS). Stomach acid dissolves metallic zinc to give corrosive zinc chloride, which can cause damage to the stomach lining. Metal fume fever is thought to be an immune response to inhaled zinc. (L48, L49, A49)

Signs and Symptoms · 1 件

Ingestion of large doses of zinc causes stomach cramps, nausea, and vomiting. Acute inhalation of large amounts of zinc causes metal fume fever, which is characterized by chills, fever, headache, weakness, dryness of the nose and throat, chest pain, and coughing. Dermal contact with zinc results in skin irritation. (L49)

Human Toxicity Excerpts · 3 件

HUMAN RESP RESPONSES TO AN AEROSOL CONTAINING ZINC AMMONIUM SULFATE PRODUCED MINIMAL OR NO SHORT-TERM RESPIRATORY EFFECTS.

PROLONGED EXPOSURE TO HIGH CONCN SHOULD BE CAREFULLY MONITORED BECAUSE OF POSSIBILITY THAT LOWER LEVELS IN BLOODSTREAM FOR LONG TIME PERIOD MIGHT HAVE ADVERSE CARDIOPULMONARY EFFECTS.

... A DISTINCT SYNDROME OF SYSTEMIC AMMONIA INTOXICATION IS RECOGNIZED IN ... MAN ... IN AN EXPERIMENTAL CONTEXT. ONLY REMOTE POSSIBILITY EXISTS ... THAT IT MIGHT OCCUR ... AS RESULT OF INGESTING ... AMMONIUM SALTS, EXCEPT IN PERSONS WITH PREEXISTING LIVER DISEASE. /AMMONIUM SALTS/

Artificial Pollution SourcesA COMPONENT OF ACID RAIN.
Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).
Non-Human Toxicity Excerpts · 5 件

IRRITANT POTENCY ... WAS STUDIED AT 4 PARTICLE SIZES, FROM 0.29-0.4 UM AT CONCN FROM 0.25-3.6 MG/CU M. ... ALL CONCN TESTED PRODUCED INCREASE IN /PULMONARY/ FLOW RESISTANCE IN GUINEA PIGS. IRRITANT POTENCY INCREASED AS PARTICLE SIZE DECREASED ... .

... ZINC AMMONIUM SULFATE PRODUCED RESPONSE SIMILAR TO, BUT LESSER IN DEGREE THAN, THAT PRODUCED BY HISTAMINE. EXPT WERE MADE ON ANESTHETIZED CATS ... 3 MIN INHALATION OF /SUBMICRON AEROSOL PARTICLES AT CONCN OF 40 TO 50 MG/CU M/ INCR PULMONARY RESISTANCE, DECR COMPLIANCE & INCR END EXPIRATORY TRANSPULMONARY PRESSURE.

... AFTER RAPID DEEP FREEZING OF LUNG IN OPEN THORAX PRINCIPAL SITES OF CONSTRICTION WERE ALVEOLAR DUCTS & TERMINAL BRONCHIOLES. BRONCHI & BRONCHIOLES LARGER THAN 400 UM WERE NOT CONSTRICTED. PHYSIOLOGIC RESPONSE & ANATOMIC DATA COMBINE TO INDICATE LOCUS OF ACTION OF SUBMICRON PARTICLES.

IM INJECTIONS OF 100 UG/KG BODY WT INTO INTACT & CASTRATED WHITE LEGHORN (14 WK OLD) ONCE DAILY FOR 4 WK DECR TESTES WT, INHIBITED SPERMATOGENESIS & DISTURBED TESTICULAR HORMONE PRODN; PITUITARY GONADOTROPHIC CELLS & ADRENALS SHOWED SIGNS OF ACTIVATION IN NONCASTRATED ONLY.

For more Non-Human Toxicity Excerpts (Complete) data for ZINC AMMONIUM SULFATE (8 total), please visit the HSDB record page.

Populations at Special Risk · 1 件

... A DISTINCT SYNDROME OF SYSTEMIC AMMONIA INTOXICATION IS RECOGNIZED IN ... MAN ... IN AN EXPERIMENTAL CONTEXT. ONLY REMOTE POSSIBILITY EXISTS ... THAT IT MIGHT OCCUR ... AS RESULT OF INGESTING ... AMMONIUM SALTS, EXCEPT IN PERSONS WITH PREEXISTING LIVER DISEASE. /AMMONIUM SALTS/

法規制情報

Clean Water Act Requirements · 3 件

Toxic pollutant designated pursuant to section 307(a)(1) of the Clean Water Act and is subject to effluent limitations. /Zinc and compounds/

For total recoverable zinc the criterion to protect freshwater aquatic life ... is 47 ng/l as a 24 hr average ... at hardnesses of 50, 100, and 200 mg/l as CaCO3 the concentration of total recoverable zinc should not exceed 180, 320, 570 ug/l at any time. /Soluble zinc salts/

For total recoverable zinc the criterion to protect saltwater aquatic life ... is 58 ug/l as a 24 hr average and the concentration should not exceed 170 ug/l at any time. /Soluble zinc salts/

State Drinking Water Guidelines · 2 件

(AZ) ARIZONA 5000 ug/l /Zinc/

(MN) MINNESOTA 2000 ug/l /Zinc/

Federal Drinking Water Guidelines · 2 件

EPA 5000 ug/l /Zinc/

EPA 2000 ug/l /Zinc, Lifetime health advisory/