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Cesium bromide

HCID 24592
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
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基本情報

CAS
7787-69-1
標準SMILES
[Br-].[Cs+]
InChIKey
LYQFWZFBNBDLEO-UHFFFAOYSA-M
分子式
BrCs
平均分子量
212.81 g/mol
単同位体質量
211.82379

概要

Cesium bromide is an chemical compound of caesium and bromine. It is used in optics as a beamsplitter component in wide-band spectrophotometers. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. (L625, L645)

名称と識別子

優先名称
Cesium bromide
IUPAC
cesium bromide
英語名
Cesium bromide
分子式
BrCs
分子量
212.80945

名称と別名

CESIUM BROMIDE7787-69-1Caesium bromideCesium bromide (CsBr)Tricesium tribromideBromocaesium06M25EDM3FNSC-84269DTXSID8064854RefChem:124634DTXCID0048058232-130-0
名称をさらに表示
Cesiumbromidecesium;bromideCsBrBrCscesium monobromideEINECS 232-130-0cesium(I) bromideUNII-06M25EDM3F

データベース識別子

CAS
7787-69-1
PubChem CID
24592
DTXSID
DTXSID8064854
UNII
06M25EDM3F
EC Number
232-130-0
Nikkaji
J43.756E

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
1
回転可能結合数
0
重原子数
2
形式電荷
0
複雑度
2

実験および物理化学的性質

Chemical ClassesMetals -> Metals, Inorganic Compounds
SpringerMaterials Propertiesdielectric constant
Physical DescriptionSolid; [Merck Index] Hygroscopic beads; [Sigma-Aldrich MSDS]

物理化学的性質

融点
636 °C · 636 °C

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 5 件

This chemical does not meet GHS hazard criteria for 34.2% (26 of 76) of reports.

Warning

H302 (11.8%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 76 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 2 件

Chemical: Cesium bromide (CsBr)

Caesium bromide: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationEvaluation - Cesium salts
Hazards SummaryA skin and strong eye irritant; [Sigma-Aldrich MSDS] See Cesium.
Hazard Classes and CategoriesAcute Tox. 4 (11.8%)

毒性情報

Treatment · 1 件

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

用途と製造

Uses · 2 件

In x-ray fluorescent screens, spectrometer prisms, and absorption-cell windows. [Merck Index]

Caesium bromide is used in optics as a beamsplitter component in wide-band spectrophotometers. (L645)

General Manufacturing InformationCesium bromide (CsBr): ACTIVE

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関連反応

1 件
反応記録を作成
HRID 1077611 の反応式
HRID 1077611反応物としてuspto-grants-1996_08

化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
Health Effects · 1 件

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)

Exposure RoutesOral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1 件

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1 件

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).
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