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トリヨードスチビン

Antimony Triiodide

HCID 24630
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
7790-44-5
標準SMILES
[I][Sb]([I])[I]
InChIKey
KWQLUUQBTAXYCB-UHFFFAOYSA-K
分子式
I3Sb
平均分子量
502.473 g/mol
単同位体質量
501.6172

概要

Antimony Triiodide is an antimony hydride and a mononuclear parent hydride that is used in many industrial processes. It is characterized as a toxic, colorless gas that is heavier than air with a disagreeable odor, and exposure occurs by inhalation, ingestion, or contact.

名称と識別子

優先名称
Antimony Triiodide
IUPAC
triiodostibane
現地名
トリヨードスチビン
英語名
ANTIMONY(III) IODIDE
分子式
I3Sb
分子量
502.47

名称と別名

ANTIMONY TRIIODIDEAntimon(III) iodidAntimony(III) TriiodideUNII-52ZE5Y9Y82HSDB 437EINECS 232-205-852ZE5Y9Y82Antimon(III) iodideRefChem:58739232-205-8Antimonium Iodatum7790-44-5
名称をさらに表示
トリヨードスチビンよう化第一アンチモンアンチモントリヨージド三よう化アンチモンよう化アンチモン(III)三よう化アンチモン(Ⅲ)よう化アンチモン(Ⅲ)ANTIMONY TRIGLYCOLATEtriiodo-stibinTriiodostibinetriiodo-StibineAntimony lodideAntimonousiodideAnmony(Ⅲ) Iodide
Antimony(III) iodideStibine, triiodo-triiodostibaneAntimony iodideAntimony iodide (SbI3)ANTIMONY(III)IODIDEAntimony(III) iodide, ultra dryAntimony (III) iodide

データベース識別子

CAS
7790-44-5
PubChem CID
24630
DTXSID
DTXSID1064875

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
0
回転可能結合数
0
重原子数
4
形式電荷
0
複雑度
8

実験および物理化学的性質

Chemical ClassesMetals -> Metalloid Compounds (Antimony)
SpringerMaterials Propertiesphonon wavenumber
Density · 3 件

4.92 g/cu cm at 25 °C

Density: 4.921 at 17 °C/4 °C

Density: 4.768

Color/Form · 3 件

Ruby-red, trigonal crystals (yellowish-green modifications have been observed)

Red rhombic crystals

Red-to-yellow crystals

Solubility · 4 件

Reacts with water

Decomposes in water with precipitation of oxyiodide

Soluble in ethanol, acetone; insoluble in carbon tetrachloride

Souble in alcohol; acetone; carbon disulfide, hydrochloric acid, solution of potassium iodide; insoluble in carbon tetrachloride

Boiling Point400 °C
Decomposition · 3 件

Hazardous decomposition products formed under fire conditions. - Hydrogen iodide, Antimony oxide

Decomposed by water and air to SbOI (antimony oxyiodide).

When heated to decomposition it emits highly toxic Sb fumes and /hydrogen iodide/.

Melting Point171 °C

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

Warning

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P270, P271, P273, P301+P317, P304+P340, P317, P330, P391, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 44 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

H302: Harmful if swallowed [Warning Acute toxicity, oral]

危険有害性情報

Regulatory InformationStibine, triiodo-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Hazards Summary · 1 件

Symptoms of iodide poisoning are mucous membrane irritation, rhinorrhea, headache, and skin rash; Antimony compounds can cause injury to the liver, kidneys, heart, and lungs; [HSDB] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline] See Antimony and linked occupational diseases. See Iodine for the TLV of Iodides.

OSHA StandardsPermissible Exposure Limit: Table Z-1 8-Hour Time Weighted Avg: 0.5 mg/cu m. /Antimony and compounds (as Sb)/
Atmospheric Standards · 1 件

Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Antimony compounds are included on this list. /Antimony Componds/

DOT Emergency Guidelines · 5 件

化学と産業

用途と製造

Uses · 3 件

Used in medicine; [HSDB]

The greatest use of antimony compounds is in flame retardants for plastics, paints, textiles, and rubber. Antimony compounds used in flame retardants are antimony pentoxide, sodium antimonate ... and, most importantly, antimony trioxide. These compounds, when used alone, are poor flame retardants; however, when combined with halogen compounds, they produce mixtures that are effective. ... Glass articles coated with oxides and oxynitrides of antimony have been reported. The layers of antimony block uv radiation and can be used for windows.... Antimony compounds are also used in catalysts, pesticides, ammunition, medicines and lubricating grease. /Antimony compounds/

Laboratory chemicals; Synthesis of substances.

Methods of Manufacturing · 2 件

Antimony triiodide is prepared by reacting iodine with antimony or antimony sulfide in an organic solvent.

Prepared by the interaction of antimony and iodine in boiling benzene or tetrachloroethane.

General Manufacturing Information · 2 件

Stibine, triiodo-: ACTIVE

Antimony can be trivalent or pentavalent in compounds. Both exist in antimony(IV) oxide, Sb2O4, and presumably in the deep violet haloantimonates (IV), such as Cs2(SbCl6). The pentavalent compounds, as well as most of the trivalent ones, are hydrolyzed by water to form antimony salts, e.g., SbOCl, and hydrated oxides. The only halides of antimony that have any industrial significance are the chlorides and fluorides. /Antimony compounds/

応用分野

使用Antimony(III) iodide is used as a dopant in the preparation of thermoelectric materials.

調製方法

製造方法It adds to ethers, aldehydes, and thiols. Antimony triiodide is prepared by reacting iodine with antimony or antimony sulfide in an organic solvent. The triiodide is used in medicine.

純化方法It sublimes under vacuum as a red solid with an orange vapour. It hydrolyses to the yellow oxyiodide with H2O. [Schenk in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 614 1963.]

関連反応

0 件
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現在のフィルター条件では反応記録がありません。

化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
EC Number
232-205-8
Vapor Pressure
1 mm Hg at163.6 °C
Heat of Vaporization68.6 kJ/mol at 401 °C (boiling point)
Physical DescriptionRuby-red solid; Yellowish-green modifications also exist; [Merck Index] Red crystalline solid; [MSDSonline]
Stability/Shelf LifeStable under recommended storage conditions.

物理化学的性質

融点
170 °C · 170 °C(lit.)
沸点
401 °C · 401 °C(lit.)
比重(密度)
4.92 g/mL · 4.92 g/mL at 25 °C(lit.)
闪点
420 °C · 420°C
貯蔵温度
Store at room temperature, keep dry and cool
溶解性
2 · ベンゼン、アルコール、アセトン、CS2、HCl、KI、SnCl4、C2H7N に可溶。 CHCl3、CCl4 に不溶。ベンゼン、エタノール、アセトン、二硫化炭素、塩酸、ヨウ化カリウム、三塩化スルホニウム、ジメチルアミンに可溶。エタノール、アセトンにやや溶ける。クロロホルム、四塩化炭素に不溶。
外見
粉
比重
4.917 · 4.917
色
赤
水溶解度
水によってSbOIに分解される。
Merck
14 · 14,710
InChI
1S/3HI.Sb/h3*1H;/q;;;+3/p-3
InChIKey
KWQLUUQBTAXYCB-UHFFFAOYSA-K
SMILES
I[Sb](I)I
CAS データベース
7790 · 7790-44-5(CAS DataBase Reference)
EPAの化学物質情報
Stibine, triiodo- (7790-44-5)

化学的性質

化学的特性light brown powder

/GUIDE 157 SUBSTANCES - TOXIC and/or CORROSIVE (Non-Combustible/Water-Sensitive)/ Fire or Explosion: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. For UN1796, UN1826, UN2031 at high concentrations and for UN2032, these may act as oxidizers, also consult GUIDE 140. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Substance may react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. /Antimony compound, inorganic, solid, n.o.s.; Antimony compound, inorganic, liquid, n.o.s./

/GUIDE 157 SUBSTANCES - TOXIC and/or CORROSIVE (Non-Combustible/Water-Sensitive)/ Health: TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Reaction with water or moist air may release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. /Antimony compound, inorganic, solid, n.o.s.; Antimony compound, inorganic, liquid, n.o.s./

/GUIDE 157 SUBSTANCES - TOXIC and/or CORROSIVE (Non-Combustible/Water-Sensitive)/ Public Safety: CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover. As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Keep unauthorized personnel away. Stay upwind, uphill and/or upstream. Ventilate enclosed areas. /Antimony compound, inorganic, solid, n.o.s.; Antimony compound, inorganic, liquid, n.o.s./

/GUIDE 157 SUBSTANCES - TOXIC and/or CORROSIVE (Non-Combustible/Water-Sensitive)/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. /Antimony compound, inorganic, solid, n.o.s.; Antimony compound, inorganic, liquid, n.o.s./

For more DOT Emergency Guidelines (Complete) data for Antimony triiodide (8 total), please visit the HSDB record page.

NIOSH RecommendationsRecommended Exposure Limit: 10 hr Time-Weighted avg 0.5 mg/cu m. /Antimony/
Clean Water Act RequirementsToxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Antimony and compounds/
Hazard Classes and CategoriesAcute Tox. 4 (100%)
Shipment Methods and Regulations · 3 件

No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./

The International Air Transport Association (IATA) Dangerous Goods Regulations are published by the IATA Dangerous Goods Board pursuant to IATA Resolutions 618 and 619 and constitute a manual of industry carrier regulations to be followed by all IATA Member airlines when transporting hazardous materials. Antimony compound, inorganic, solid, not otherwise specified and antimony compound, inorganic, liquid, not otherwise specified are included on the dangerous goods list. /Antimony compound, inorganic, solid, not otherwise specified; Antimony compound, inorganic, liquid, not otherwise specified/

The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article. Antimony compound, inorganic, solid, not otherwise specified and antimony compound, inorganic, liquid, not otherwise specified are included on the dangerous goods list. /Antimony compound, inorganic, solid, not otherwise specified; Antimony compound, inorganic, liquid, not otherwise specified/

Shipping Name/ Number DOT/UN/NA/IMO · 3 件

UN 3141; Antimony compound, inorganic, liquid, not otherwise specified

UN 1549; Antimony compound, inorganic, solid, not otherwise specified

IMO 6.1; Antimony compound, inorganic, solid, not otherwise specified; Antimony compound, inorganic, liquid, not otherwise specified

Critical Temperature and PressureCritical temperature: 1101 °C; critical pressure: 55 atm
Hazardous Reactivities and Incompatibilities · 5 件

A mixture of potassium and ... the metallic halide ... antimony triiodide ... produces a strong explosion on impact.

Incompatible with sodium, potassium.

... Antimony triiodide ... readily hydrolyzes, forms complex halide ions and forms a wide variety of adducts with ethers, aldehydes, mercaptans ... .

Acids, Water, Strong bases, Sodium/sodium oxides, Potassium

Strong oxidizers, acids, halogenated acids [Note: Stibine is formed when antimony is exposed to nascent (freshly formed) hydrogen.] /Antimony/

安全と保護具

Fire Fighting ProceduresSuitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Advice for firefighters: Wear self-contained breathing apparatus for firefighting if necessary.
Storage ConditionsKeep container tightly closed in a dry and well-ventilated place. Air sensitive. Storage class (TRGS 510): 13: Non Combustible Solids
Cleanup Methods · 1 件

ACCIDENTAL RELEASE MEASURES; Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Avoid breathing dust. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials: for containment and cleaning up: Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.

Disposal Methods · 2 件

SRP: Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in air, soil or water; effects on animal, aquatic and plant life; and conformance with environmental and public health regulations. If it is possible or reasonable use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination.

Product: Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Contaminated packaging: Dispose of as unused product.

Preventive Measures · 5 件

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.

ACCIDENTAL RELEASE MEASURES; Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Avoid breathing dust. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

For more Preventive Measures (Complete) data for Antimony triiodide (8 total), please visit the HSDB record page.

Threshold Limit Values (TLV) · 3 件

0.5 [mg/m3], as Sb (0.01 ppm, inhalable fraction and vapor (iodides))

8 hr Time Weighted Avg (TWA): 0.5 mg/cu m. /Antimony and compounds, as Sb/

Peak Exposure Recommendation: Transient increases in workers' exposure levels may exceed 3 times the value of the TLV-TWA level for no more than 15 minutes at a time, on no more than 4 occasions spaced 1 hour apart during a workday, and under no circumstances should they exceed 5 times the value of the TLV-TWA level. In addition, the 8-hour TWA is not to be exceeded for an 8-hour work period. /Antimony and compounds, as Sb/

Permissible Exposure Limit (PEL)0.5 [mg/m3], as Sb
Personal Protective Equipment (PPE) · 5 件

Eye/face protection: Face shield and safety glasses. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection: Handle with gloves.

Body Protection: Complete suit protecting against chemicals. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection: For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator. For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

For more Personal Protective Equipment (PPE) (Complete) data for Antimony triiodide (12 total), please visit the HSDB record page.

Immediately Dangerous to Life or Health (IDLH) · 2 件

50.0 [mg/m3]

50 mg/cu m, as Sb /Antimony/

毒性情報

Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.
Toxicity Summary · 1 件

IDENTIFICATION AND USE: Antimony triiodide is a solid. It is used as laboratory chemical and in the synthesis of substances. HUMAN STUDIES: Antimony halides are hydrolyzed to oxides which are not absorbed but cause severe irritation and caustic action on alimentary mucosa. Antimony halides produce irritant effects on the mucous membranes of the eyes, nose, mouth, throat, and upper respiratory tract. ANIMAL STUDIES: Chronic inhalation of subtoxic doses of antimony salts causes interstitial pneumonitis, intraalveolar lipoid deposits, and liver and cardiac damage.

Antidote and Emergency Treatment · 5 件

/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on the left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Poisons A and B/

/SRP:/ Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if needed. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . Cover skin burns with dry sterile dressings after decontamination ... . /Poisons A and B/

/SRP:/ Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in severe respiratory distress. Positive-pressure ventilation techniques with a bag valve mask device may be beneficial. Consider drug therapy for pulmonary edema ... . Consider administering a beta agonist such as albuterol for severe bronchospasm ... . Monitor cardiac rhythm and treat arrhythmias as necessary ... . Start IV administration of D5W TKO /SRP: "To keep open", minimal flow rate/. Use 0.9% saline (NS) or lactated Ringer's (LR) if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Watch for signs of fluid overload ... . Treat seizures with diazepam or lorazepam ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Poisons A and B/

/SRP:/ Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Iodine and related compounds/

For more Antidote and Emergency Treatment (Complete) data for Antimony triiodide (6 total), please visit the HSDB record page.

法規制情報

Atmospheric Standards · 1 件

Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Antimony compounds are included on this list. /Antimony Componds/

Clean Water Act RequirementsToxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Antimony and compounds/

安全データ

F
1-8-10
wgk
2
tsca
TSCA listed
ridadr
UN 3260 8/PG 2
hs_code
28276000
risk_code
20/22-51/53-50/53-43
hazard_code
Xn,N
safety_code
61-36/37
hazard_class
8
packing_group
II
Hazard Classifications
Acute Tox. 4 InhalationAcute Tox. 4 OralAquatic Chronic 2Skin Sens. 1
ストレージクラス
11 - Combustible Solids
有毒物質データの
7790-44-5(Hazardous Substances Data)

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