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カドミウムジフルオリド

Cadmium fluoride

HCID 24634
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
7790-79-6
標準SMILES
[F][Cd][F]
InChIKey
LVEULQCPJDDSLD-UHFFFAOYSA-L
分子式
CdF2
平均分子量
150.41 g/mol
単同位体質量
151.900171

概要

Cadmium fluoride is a water-insoluble chemical compound of cadmium used in oxygen-sensitive applications, such as the production of metallic alloys. Cadmium is a transition metal and chemical element with the symbol Cd and atomic number 48. It is found naturally in the earth's crust, though rarely on it's own. (L6, L467)

名称と識別子

優先名称
Cadmium fluoride
IUPAC
difluorocadmium
現地名
カドミウムジフルオリド
英語名
Cadmium fluoride
分子式
CdF2
分子量
150.41

名称と別名

CADMIUM FLUORIDE7790-79-6difluorocadmiumCadmium fluoride (CdF2)Cadmium fluorureM0975E7Z8ZCadmium FluoratumRefChem:58742DTXCID2048086232-222-0Cadmium difluorideDTXSID6064878
名称をさらに表示
カドミウムフルオリドカドミウムジフルオリドふっ化カドミウムふっ化カドミウム, 99%ふっ化カドミウム (99.98%-Cd)cadmiumfluorureCadmium FlourideCadmiumfluoride,99%Cadmium fluoride≥98%cadmiumfluoride(cdf2)CADMIUM (II) FLUORIDE
Cadmium(II) fluorideCdF2Cadmium fluorure [French]EINECS 232-222-0SCHEMBL662658UNII-M0975E7Z8ZCadmium fluoride (99.98%-Cd)AKOS030228603

データベース識別子

CAS
7790-79-6
PubChem CID
24634
EC Number
232-222-0

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
2
回転可能結合数
0
重原子数
3
形式電荷
0
複雑度
2.8

実験および物理化学的性質

Chemical ClassesMetals -> Cadmium Compounds, Inorganic
SpringerMaterials Propertieselectron density of states
Density6.33 @ 20°C
Boiling Point1750 °C @760 [mm Hg]
Melting Point1075 °C
Vapor Pressure1 [mm Hg] @1112 °C
Physical DescriptionSolid; [Merck Index] White odorless chunks; [MSDSonline]

物理化学的性質

融点
1049 °C · 1049 °C
沸点
1748 °C · 1748 °C
比重(密度)
6.33 g/mL · 6.33 g/mL at 25 °C(lit.)
闪点
1758 °C · 1758°C
溶解性
soluble in acid solutions; insoluble in ethanol
外見
粉
比重
6.64 · 6.64
色
白い
水溶解度

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

Danger

H301: Toxic if swallowed [Danger Acute toxicity, oral]

P203, P260, P264, P270, P271, P273, P280, P284, P301+P316, P304+P340, P316, P318, P319, P320, P321, P330, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P203, P260, P264, P270, P271, P273, P280, P284, P301+P316, P304+P340, P316, P318, P319, P320, P321, P330, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

危険有害性情報

Regulatory Information · 4 件

Chemical: Cadmium fluoride (CdF2)

Hazard Traits - Carcinogenicity; Genotoxicity; Reproductive Toxicity

Restricted substance: Cadmium fluoride

Substance: Cadmium fluoride

Other Safety InformationIMAP assessments - Water soluble cadmium(2+) salts: Environment tier II assessment
Hazards SummaryVery toxic by inhalation; [eChemPortal: ESIS] An irritant; Very toxic by inhalation or ingestion; A reproductive toxin in animal experiments; [MSDSonline] See Cadmium and the linked diseases.
Hazard Classes and Categories · 3 件

Acute Tox. 3 (100%)

Acute toxicity - category 3

Carc. 1B

安全と保護具

Exposure Control and Personal Protection · 2 件

Biological Exposure Indices (BEI) [ACGIH] - Cd in urine = 5 ug/g creatinine; Cd in blood = 5 ug/L; sampling time not critical; Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Cadmium is absorbed from oral, inhalation, and dermal routes. Cadmium initially binds to metallothionein and albumin and is transported mainly to the kidney and liver. Toxic effects are observed once the concentration of cadmium exceeds that of available metallothionein, and it has also been shown that the cadmium-metallothionein complex may be damaging. Cadmium is not known to undergo any direct metabolic conversion and is excreted unchanged, mainly in the urine. (L6)

用途と製造

Uses · 3 件

Used in phosphors, glass, and nuclear reactor controls; [Merck Index] Used in high-temperature lubricants and to start crystals for lasers; [Hawley] Use is highly restricted in the EU; [eChemPortal: ESIS: EDEXIM]

Glass Manufacturing [Category: Industry]

Cadmium fluoride is used in the production of metallic alloys, for electronic and optical applications and as a starting material for laser crystals. (L467)

General Manufacturing InformationCadmium fluoride (CdF2): ACTIVE
応用分野 · 3 件

解説CdF2(150.41).金属カドミウムまたはカドミウムの酸化物,硫化物,塩化物などにフッ素を反応させると得られる.白色の粉末.等軸晶系.密度6.33 g cm-3.融点1100 ℃,沸点1748 ℃.水,フッ化水素酸,鉱酸に可溶,エタノールに不溶.ガラスの製造,半導体素子・光学装置・レーザー結晶の原料などに用いられる.[CAS 7790-79-6]森北出版「化学辞典(第2版)

用途研究用途、発行スクリーン用途の蛍光剤

使用Cadmium fluoride is used in phosphors, glass and nuclear reactor controls. It is also used in high-temperature lubricants and to start crystals for lasers. It is used in oxygen-sensitive applications such as the production of metallic alloys and it is also used in limited medical treatment protocols. In addition, it can be used in synthetic organic chemistry.

調製方法 · 2 件

関連反応

0 件
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化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
4.3 g/100mL · 4.3g/100mL(25℃)
晶系
立方
Merck
14 · 14,1619
空间群
3 m · Fm3m
晶格常数
30.539 · a/nmb/nmc/nmα/oβ/oγ/oV/nm30.5390.5390.5399090900.1564
CAS データベース
7790 · 7790-79-6(CAS DataBase Reference)
NISTの化学物質情報
Cadmium difluoride(7790-79-6)
EPAの化学物質情報
Cadmium fluoride (CdF2) (7790-79-6)

化学的性質

化学的特性White powder

1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]

Minimum Risk LevelAcute Inhalation: 0.00003 mg/m3 (L134) Chronic Inhalation: 0.00001 mg/m3 (L134) Intermediate Oral: 0.0005 mg/kg/day (L134) Chronic Oral: 0.0001 mg/kg/day (L134)
Threshold Limit Values (TLV)0.01 [mg/m3], as Cd ( 0.002 mg/m3, as Cd, respirable fraction) [2.5 mg/m3, as F]
Permissible Exposure Limit (PEL)0.005 [mg/m3], as Cd, see 29 CFR 1910.1027 [2.5 mg/m3, as F]
Protective Action Criteria (PAC) · 3 件

0.61 [mg/m3]

6.7 [mg/m3]

40 [mg/m3]

Immediately Dangerous to Life or Health (IDLH)9.0 [mg/m3], as Cd

毒性情報

TreatmentCadmium poisoning is treated by removal from exposure and supportive care. If ingested, induced vomiting or gastric lavage may be performed. (L139)
Health EffectsChronic exposure to cadmium fumes can cause chemical pneumonitis, pulmonary edema, and lung diseases such as bronchitis and emphysema. Cadmium also accumulates in the kidneys, causing permanent damage. Loss of bone density also occurs. (L6)
Adverse EffectsNephrotoxin - The chemical is potentially toxic to the kidneys in the occupational setting.
Exposure RoutesOral (L6) ; inhalation (L6) ; dermal (L6)
Toxicity Summary · 1 件

Cadmium initially binds to metallothionein and is transported to the kidney. Toxic effects are observed once the concentration of cadmium exceeds that of available metallothionein, and it has also been shown that the cadmium-metallothionein complex may be damaging. Accumulation of cadmium in the kidney results in increased excretion of vital low and high weight molecular proteins. Cadmium is a high affinity zinc analog and can interfere in its biological processes. It also binds to and activates the estrogen receptor, likely stimulating the growth of certain types of cancer cells and causing other estrogenic effects, such as reproductive dysfunction. Cadmium causes cell apoptosis by activating mitogen-activated protein kinases. (L8, A18, A19, A28)

Signs and SymptomsAcute inhalation of cadmium fumes results in metal fume fever, which is characterized by chills, fever, headache, weakness, dryness of the nose and throat, chest pain, and coughing. Ingestion of cadmium causes vomiting and diarrhea. (L6)
Carcinogen Classification1, carcinogenic to humans. (L135)

安全データ

wgk
3
tsca
TSCA listed
rtecs
EV0700000
ridadr
UN 2570 6.1/PG 2
hs_code
28261990
risk_code
45-46-60-61-25-26-48/23/25-50/53
hazard_code
T+,N,T
hazard_note
Toxic
safety_code
53-45-60-61
hazard_class
6.1
packing_group
II

製造方法Cadmium fluoride is prepared by the reaction of gaseous fluorine or hydrogen fluoride with cadmium metal or its salt, such as chloride, oxide or sulfide:Cd + F2 → CdF2Cd + 2HF → CdF2 + H2CdO + 2HF → CdF2 + H2OIt also may be obtained by dissolving cadmium carbonate in 40% hydrofluoric acid solution, evaporating the solution and drying in vacuum at 150°C:CdCO3 + 2HF → CdF2 + H2O + CO2It also may be prepared by mixing cadmium chloride and ammonium fluoride solutions, followed by crystallization.

純化方法Crystallise it by dissolving it in hot water (25mL/g at room temperature) at 60o, filtering, then cooling. [Kwasnik in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 243 1963.]

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補足説明

定義Available as pure crystals, 99.89%, d 6.6, mp approx- imately 1110C, soluble in water and acids, insoluble in alkalies.