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ヨウ化カドミウム

Cadmium iodide

HCID 24635
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
7790-80-9
標準SMILES
[Cd+2].[I-].[I-]
InChIKey
OKIIEJOIXGHUKX-UHFFFAOYSA-L
分子式
CdI2
平均分子量
366.22 g/mol
単同位体質量
367.71231

概要

Cadmium iodide is an iodide of cadmium that can be made by heating cadmium with iodine. It is used in lithography, photography, electroplating and the manufacturing of phosphors. Cadmium is a transition metal and chemical element with the symbol Cd and atomic number 48. It is found naturally in the earth's crust, though rarely on it's own. (L6, L469)

名称と識別子

優先名称
Cadmium iodide
IUPAC
cadmium(2+) diiodide
現地名
ヨウ化カドミウム
英語名
Cadmium iodide
分子式
CdI2
分子量
366.22

名称と別名

CADMIUM IODIDE7790-80-9Cadmium diiodideCadmium iodide (CdI2)2F2UPU4KCWDTXSID20894887diiodocadmiumRefChem:122578DTXCID501324446232-223-6cadmium(2+);diiodideCadmium(II) iodide
名称をさらに表示
カドミウムジヨージドカドミウムヨージドヨウ化カドミウム(II)よう化カドミウム, 99%よう化カドミウムジヨードカドミウムCdI2CadmiumjodidIodo cadmiumCadium iodideCadmium lodidecadmiumdiiodideGermanium lodideCADMIUM IODIDE GRCadmiumiodide,99%
MFCD00010920CadmiumiodideCadmium diiodide, Cadmiumdiiodid, Cadmium iodide (CdI2), cadmium(2+) diiodide, CADMIUM(II) IODIDECadmium Iodide PowderCADMIUM IODATUMUltra Dry Cadmium IodideCADMIUM IODIDE [MI]SCHEMBL20297

データベース識別子

CAS
7790-80-9
PubChem CID
24635
DTXSID

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
2
回転可能結合数
0
重原子数
3
形式電荷
0
複雑度
0

実験および物理化学的性質

Chemical ClassesMetals -> Cadmium Compounds, Inorganic
SpringerMaterials Propertiesphonon wavenumber
Physical DescriptionWhite odorless solid; Turns yellow on contact with air and light; [Hawley] Light green odorless powder; [MSDSonline]

物理化学的性質

融点
388 °C · 388 °C (lit.)
沸点
787 °C · 787 °C (lit.)
比重(密度)
5.67 g/mL · 5.67 g/mL at 25 °C (lit.)
闪点
787 °C · 787°C
貯蔵温度
2 · 2-8°C, protect from light, stored under nitrogen
溶解性
エタノール、アセトン、エーテル、アンモニアに溶けます。
外見
ビーズ
色
白から黄色
比重
5.67 · 5.67
水溶解度
水に非常に溶けやすく、アセトン、エタノール、ジエチルエーテルに溶けにくい。
比熱容量
0.22 J/ · Cp(crystal): 0.22 J/(g·K), at 25℃
Merck
14 · 14,1621
InChI
1S/Cd.2HI/h;2*1H/q+2;;/p-2

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 6 件

Danger

H301: Toxic if swallowed [Danger Acute toxicity, oral]

P203, P260, P261, P264, P270, P271, P273, P280, P301+P316, P304+P340, P316, P318, P319, P321, P330, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P203, P260, P261, P264, P270, P271, P273, P280, P301+P316, P304+P340, P316, P318, P319, P321, P330, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

危険有害性情報

Regulatory Information · 3 件

Chemical: Cadmium iodide (CdI2)

Restricted substance: Cadmium iodide

Cadmium iodide: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Cadmium iodide (CdI2): Human health tier II assessment
Hazards SummaryAn irritant; Danger of cumulative effects after ingestion or inhalation; Oral LD50 (rat) = 222 mg/kg; [MSDSonline] See Cadmium and the linked diseases. See Iodine for the TLV of Iodides.
Hazard Classes and Categories · 4 件

Acute Tox. 3 (100%)

Acute toxicity - category 3

Acute toxicity (Oral) - Category 3

Carc. 2

安全と保護具

Exposure Control and Personal Protection · 1 件

Biological Exposure Indices (BEI) [ACGIH] - Cd in urine = 5 ug/g creatinine; Cd in blood = 5 ug/L; sampling time not critical; Monitoring in blood should be preferred during the initial year of exposure and whenever changes in the degree of exposure are suspected. [ACGIH]

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Cadmium is absorbed from oral, inhalation, and dermal routes. Cadmium initially binds to metallothionein and albumin and is transported mainly to the kidney and liver. Toxic effects are observed once the concentration of cadmium exceeds that of available metallothionein, and it has also been shown that the cadmium-metallothionein complex may be damaging. Cadmium is not known to undergo any direct metabolic conversion and is excreted unchanged, mainly in the urine. (L6)

用途と製造

Uses · 4 件

Used in photography, process engraving, lithography, analytical chemistry, and electroplating; Also used as in lubricants, phosphors, and nematocides; [Hawley] Used for cadmium electrodeposition and in photoconductors; [Merck Index] Use is highly restricted in the EU; [eChemPortal: ESIS: EDEXIM]

Electroplating [Category: Plate]

Lithography printing [Category: Hobbies]

Cadmium iodide is used in lithography, photography, electroplating and the manufacturing of phosphors. (L469)

General Manufacturing InformationCadmium iodide (CdI2): ACTIVE

応用分野

解説ヨウ化カドミウム,無色の光沢ある六方晶系結晶.密度5.67 g cm-3.融点385 ℃,沸点713 ℃.水に易溶,エタノール,エーテル,アセトンに可溶.森北出版「化学辞典(第2版)

使用Cadmium iodide is used in lithography, photography, electroplating and the manufacturing of phosphors, in engraving process, and was used as an antiseptic and astringent.

調製方法 · 2 件

製造方法Cadmium iodide is prepared by the addition of cadmium metal, or its oxide, hydroxide, nitrate or carbonate to hydriodic acid: CdO + 2HI → CdI2 + H2O Also, the compound can be made by heating cadmium with iodine: Cd +I2 → CdI2 A brownish crystalline β-form of the salt may be obtained by slow crystallization from solutions or fused salt mixtures.

関連反応

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化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
DTXSID20894887
UNII
2F2UPU4KCW
EC Number
232-223-6
Nikkaji
J43.714J
InChIKey
OKIIEJOIXGHUKX-UHFFFAOYSA-L
SMILES
I[Cd]I
CAS データベース
7790 · 7790-80-9(CAS DataBase Reference)
EPAの化学物質情報
Cadmium iodide (7790-80-9)

化学的性質

化学的特性Pearly white flakes or a crystalline powder

Minimum Risk LevelAcute Inhalation: 0.00003 mg/m3 (L134) Chronic Inhalation: 0.00001 mg/m3 (L134) Intermediate Oral: 0.0005 mg/kg/day (L134) Chronic Oral: 0.0001 mg/kg/day (L134)
Threshold Limit Values (TLV)0.01 [mg/m3], as Cd ( 0.002 mg/m3, as Cd, respirable fraction) [0.01 ppm, inhalable fraction and vapor (iodides)]
Permissible Exposure Limit (PEL)0.005 [mg/m3], as Cd, see 29 CFR 1910.1027
Immediately Dangerous to Life or Health (IDLH)9.0 [mg/m3], as Cd

毒性情報

TreatmentCadmium poisoning is treated by removal from exposure and supportive care. If ingested, induced vomiting or gastric lavage may be performed. (L139)
Health EffectsChronic exposure to cadmium fumes can cause chemical pneumonitis, pulmonary edema, and lung diseases such as bronchitis and emphysema. Cadmium also accumulates in the kidneys, causing permanent damage. Loss of bone density also occurs. (L6)
Adverse EffectsNephrotoxin - The chemical is potentially toxic to the kidneys in the occupational setting.
Exposure RoutesOral (L6) ; inhalation (L6) ; dermal (L6)
Toxicity Summary · 1 件

Cadmium initially binds to metallothionein and is transported to the kidney. Toxic effects are observed once the concentration of cadmium exceeds that of available metallothionein, and it has also been shown that the cadmium-metallothionein complex may be damaging. Accumulation of cadmium in the kidney results in increased excretion of vital low and high weight molecular proteins. Cadmium is a high affinity zinc analog and can interfere in its biological processes. It also binds to and activates the estrogen receptor, likely stimulating the growth of certain types of cancer cells and causing other estrogenic effects, such as reproductive dysfunction. Cadmium causes cell apoptosis by activating mitogen-activated protein kinases. (L8, A18, A19, A28)

Signs and SymptomsAcute inhalation of cadmium fumes results in metal fume fever, which is characterized by chills, fever, headache, weakness, dryness of the nose and throat, chest pain, and coughing. Ingestion of cadmium causes vomiting and diarrhea. (L6)
Carcinogen Classification1, carcinogenic to humans. (L135)
Toxicity DataLD50: 4708 mg/kg (Oral, Rat) (L470)

安全データ

wgk
3
tsca
TSCA listed
rtecs
EV1290000
ridadr
UN 2570 6.1/PG 3
PRTR法
特1-75
hs_code
28276000
risk_code
23/25-33-50/53-68/20/22-68
安衛法
特定化学物質障害予防規則:第2類物質,57,57-2
hazard_code
T,N
safety_code
22-45-60-61
hazard_class
6.1
packing_group
III
毒劇物取締法
III
Hazard Classifications
Acute Tox. 3 InhalationAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1Carc. 2STOT RE 2
ストレージクラス
6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
危険度評価(NFPA 704基準/消防庁データ)
人的[青]=2

純化方法Crystallise it from ethanol (2mL/g) by partial evaporation. [Wagenknecht & Juza in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1096 1965.]

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