D-アルトロース
GlyTouCan:G09597LJ
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基本情報
- CAS
1990-29-0- 標準SMILES
O=CC(O)C(O)C(O)C(O)CO- InChIKey
GZCGUPFRVQAUEE-UHFFFAOYSA-N- 分子式
- C6H12O6
- 平均分子量
- 180.16 g/mol
- 単同位体質量
- 180.0633881
概要
Aldohexose is a hexose with a (potential) aldehyde group at one end. It is an aldose and a hexose.
名称と識別子
- 優先名称
- GlyTouCan:G09597LJ
- IUPAC
- 2,3,4,5,6-pentahydroxyhexanal
- 現地名
- D-アルトロース
- 英語名
- D-ALTROSE
- 分子式
- C6H12O6
- 分子量
- 180.16
名称と別名
RefChem:675366GlyTouCan:G09597LJG09597LJ2,3,4,5,6-pentahydroxyhexanal93780-23-53458-28-4Mannose, D-L-(-)-GalactoseD-Glucose-3,4-13C2D-(+)-GlucoseD-Glucose-2-d1D-(+) Glucose
名称をさらに表示
D-アルトロースD(+)-アルトロースD(+)‐アルトロースD-アルトロース, 99.5+%(HPLC)D-アルトロース, 99+%(HPLC)D-(+)-アルトロースアルトロース, D-D(-)-アルトロース(2S,3R,4R,5R)-2,3,4,5,6-ペンタヒドロキシヘキサナールAltd-[UL-13C6]altrose(2S,3R,4R,5R)-2,3,4,5,6-PentahydroxyhexanalaltroseD-ALTROSEB-D-AltroseALTROSE, D-α-D-AltroseD-(+)-ALTROSEALTROSE, D-(RG)
D-Mannose-3-13CL-(+)-Gulose67759-25-5Glucose, liquidAldohexoseGalactose, D-2,3,4,5,6-pentakis(oxidanyl)hexanalGalactose, L- (8CI)
データベース識別子
- CAS
1990-29-0、25191-16-6、2595-98-4、3458-28-4、45009-62-9、50-99-7、8027-56-3、93780-23-5- PubChem CID
- 24749
- DTXSID
DTXSID70860057- ChEMBL
CHEMBL1206211- ChEBI
CHEBI:33917- EC Number
- 222-392-4
- Nikkaji
- J2.733.971I
物性
構造計算による物性補完中
- XLogP
- -2.9
- 極性表面積
- 118 Ų
- 水素結合供与体数
- 5
- 水素結合受容体数
- 6
- 回転可能結合数
- 5
- 重原子数
- 12
- 形式電荷
- 0
- 複雑度
- 138
実験および物理化学的性質
Chemical ClassesBiological Agents -> Monosaccharides and Derivatives
DrugsPharmaceuticals
Vapor Pressure0.00000002 [mmHg]
Physical DescriptionWhite hygroscopic powder; [Alfa Aesar MSDS]
物理化学的性質
- 融点
- 106 · 106-108 °C
- 比旋光度
- 20 · D20 +32.6° (c = 7.6)
- 沸点
- 232.96 °C · 232.96°C (rough estimate)
- 比重(密度)
- 1.581 · 1.581
- 屈折率
- 1.586 · 1.5860 (estimate)
- 貯蔵温度
- 2 · 2-8°C
- 溶解性
- DMSO（微量）、メタノール（微量、加温）、水（微量）
- 外見
- 粉
- 酸解離定数(Pka)
- 12.45 · 12.45±0.20(Predicted)
- 色
- ホワイトからオフホワイト
- Merck
- 13 · 13,319
- BRN
- 1724621 · 1724621
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
This chemical does not meet GHS hazard criteria for 99.4% (158 of 159) of all reports.
Not Classified
Aggregated GHS information provided per 159 reports by companies from 3 notifications to the ECHA C&L Inventory.
危険有害性情報
Regulatory Information
Chemical: D-Mannose
Chemical: Liquid glucose
Status: Active Update: 15-06-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/23819
D-Mannose: Does not have an individual approval but may be used under an appropriate group standard
Liquid glucose: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Other Safety Information
IMAP assessments - D-Mannose: Human health tier I assessment
IMAP assessments - Liquid glucose: Human health tier I assessment
Hazards SummaryMay cause irritation; [Alfa Aesar MSDS]
Hazard Classes and CategoriesNot Classified
安全データ
- wgk
- 3
- hs_code
- 29400090
- risk_code
- 36/37/38
- hazard_code
- Xi
- safety_code
- 24/25-36-26
- ストレージクラス
- 11 - Combustible Solids
化学と産業
用途と製造
UsesIsomer of glucose; [ChemIDplus]
General Manufacturing InformationD-Mannose: ACTIVE
応用分野
使用D-Altrose is the epimer of D-glucose at C3 and have recently been discovered to possess antioxidant properties by the suppression of reactive oxygen species production in mitochondria due to competiti on with D-glucose at the cellular level.
調製方法
純化方法Crystallise D-altrose from aqueous EtOH. If it is obtained by the hydrolysis of the acetate, then it may contain sodium and acetate ions. Ions are best removed by dissolving in H2O, passing through suitable columns of ion-exchange resins, e.g. Amberlite IR-120 and Duolite A, and concentrating in a vacuum to a syrup. This is dissolved in MeOH, filtered and evaporated in a vacuum desiccator over granular CaCl2. The thick syrup is inoculated with seed crystals, stirred, and before it sets to a magma of crystals, transfer the crystals with MeOH to a Büchner funnel. Recrystallise them in the same way. -D-Altrofuranoside has initial [] D ~-69o (c 4, H2O) which mutarotates to +33o. [Richtmeyer Methods in Carbohydrate Chemistry I 107 Academic Press 1962, Beilstein 1 IV 4301, see Angyal Adv Carbohydrate Chem Biochem 42 15 1984 for ratio of anomers in solution.]
上流・下流製品情報
下流製品
補足説明
定義An aldohexose that is isomeric with glucose, tallose, allose, and others.
関連反応
120 件
化合物ノート
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