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Nitrogen fluoride (N2F4)

HCID 24845
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
10036-47-2
標準SMILES
FN(F)N(F)F
InChIKey
GFADZIUESKAXAK-UHFFFAOYSA-N
分子式
F4N2
平均分子量
104.007 g/mol
単同位体質量
103.99976066

概要

Tetrafluorohydrazine appears as a colorless toxic irritant gas. Nonflammable. Prolonged exposure of the container to high heat may cause it to rupture violently and rocket. Used in organic synthesis and as an oxidizing agent in fuel for rockets.

名称と識別子

優先名称
Nitrogen fluoride (N2F4)
IUPAC
1,1,2,2-tetrafluorohydrazine
英語名
1,1,2,2-tetrafluorohydrazine
分子式
F4N2
分子量
0

名称と別名

TetrafluorohydrazinePerfluorohydrazineNitrogen fluoride (N2F4)10086-47-2EINECS 233-114-6DTXSID9064922Hydrazine, tetrafluoroRefChem:854341DTXCID0032522Dinitrogen tetrafluoride1,1,2,2-Tetrafluorohydrazine10036-47-2
名称をさらに表示
Hydrazine, tetrafluoro-RR3J2QP9MGN2F4UNII-RR3J2QP9MGSCHEMBL1793267NS00047360Q382867

データベース識別子

CAS
10036-47-2、10086-47-2
PubChem CID
24845
DTXSID
DTXSID9064922
UNII
RR3J2QP9MG
EC Number
233-114-6
Nikkaji
J95.128E

物性

構造計算による物性

XLogP
0.8
極性表面積
6.5 Ų
水素結合供与体数
0
水素結合受容体数
6
回転可能結合数
0
重原子数
6
形式電荷
0
複雑度
26.5

実験および物理化学的性質

Chemical ClassesNitrogen Compounds -> Hydrazines
SpringerMaterials PropertiesSchoenflies notation
Density1.5 @ -100°C
Boiling Point-73 °C @760 [mm Hg]
Melting Point-163 °C
Physical Description · 2 件

Tetrafluorohydrazine appears as a colorless toxic irritant gas. Nonflammable. Prolonged exposure of the container to high heat may cause it to rupture violently and rocket. Used in organic synthesis and as an oxidizing agent in fuel for rockets.

Colorless gas; [CAMEO]

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

危険有害性情報

DOT LabelPoison Gas
Fire HazardsExcerpt from ERG Guide 123 [Gases - Toxic]:
Health HazardsExcerpt from ERG Guide 123 [Gases - Toxic]:
Hazards Summary · 1 件

Causes conjunctival irritation, cyanosis, and weight loss in inhalation lethal-concentration studies of guinea pigs (LC50 = 900 ppm/1hr); Causes convulsions and acute pulmonary edema in inhalation lethal-concentration studies of mice (LC50 = 440 mg/m3); Causes dyspnea and methemoglobinemia in intraperitoneal lethal-dose studies of rats; [RTECS] A strong oxidizing agent; Explosive, toxic, and irritating; [CAMEO] See Hydrazine.

Reactive GroupOxidizing Agents, Strong
Reactivity AlertsExplosive
Reactivity Profile · 1 件

TETRAFLUOROHYDRAZINE is an oxidizing agent. Explodes or ignites on contact with reducing agents at normal temperatures, including alcohols, amines, ammonia, beryllium alkyls, boranes, dicyanogen, hydrazines, hydrocarbons, hydrogen, nitroalkanes, powdered metals, silanes, or thiols [Bretherick 1979 p.174]. Can explode at high temperatures. Can explode with shock or blast when under pressure. Emits highly toxic fumes of fluorine and oxides of nitrogen when heated to decomposition. Several grams of a crude mixture containing tetrafluorohydrazine and nitrogen trifluoride had been allowed to collect in a stainless steel cylinder. During opening of valves to check the pressure, the cylinder exploded, killing one man and injuring another [MCA Case History 683 1966].

Air and Water ReactionsNo rapid reaction with air. No rapid reaction with water.
Highly Hazardous SubstanceChemical: Tetrafluorohydrazine

化学と産業

用途と製造

UsesUsed in organic synthesis and as an oxidizer in rocket fuels; [CAMEO]
General Manufacturing InformationNitrogen fluoride (N2F4): ACTIVE

サプライヤー2 社

Shaanxi Didu New Materials Co. Ltd+86-86-17392712779 +86-13289823923 · [email protected]
厦门盈融达化工有限公司+86-0592-6210733 · [email protected]

関連反応

2 件
反応記録を作成
HRID 179080 の反応式
HRID 179080反応物としてTraining data from https://doi.org/10.1039/C8SC04228D (6/10)
HRID 616520 の反応式
HRID 616520反応物としてuspto-grants-1978_02

化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート

安全と保護具

Fire FightingExcerpt from ERG Guide 123 [Gases - Toxic]:
First AidExcerpt from ERG Guide 123 [Gases - Toxic]:
Nonfire Spill ResponseExcerpt from ERG Guide 123 [Gases - Toxic]:
Isolation and EvacuationExcerpt from ERG Guide 123 [Gases - Toxic]:
Protective Action Criteria (PAC) · 3 件

0.38 [ppm]

4.2 [ppm]

25 [ppm]

Personal Protective Equipment (PPE)Excerpt from ERG Guide 123 [Gases - Toxic]:

毒性情報

Adverse EffectsNeurotoxin - Other CNS neurotoxin
Toxicity DataLC50 (rat) = 300 mg/m3/2hr