ホームMCPワークベンチSkills
ホームワークベンチ通知マイページ
化工社オープンプロジェクト：[email protected]AIアクセス：llms.txt · MCPガイドプライバシーポリシー · 利用規約 · サポートv1.7.8
戻る
化工社化工社 化学情報印刷レポート · 研究参考用
HCID 24939作成日：2026年11月2日

硫酸ナトリウムアルミニウム12水

硫酸アルミニウムナトリウム · 硫酸ナトリウムアルミニウム12水 · 硫酸ナトリウムアルミニウム・12水 · Sodium Aluminum Sulphate · SODIUM ALUM · ALUMINUM SODIUM SULFATE · aluminiumsodiumsulfate · SODIUMALUMINIUMSULPHATE

https://huagongshe.com/ja/chemical/24939

硫酸ナトリウムアルミニウム12水 の分子構造式

識別子と物理属性

CAS No.10102-71-3
分子式AlNaO8S2
平均分子量242.1 g/mol
単同位体質量241.874767 g/mol
SMILESO=S(=O)([O-])[O-].O=S(=O)([O-])[O-].[Al+3].[Na+]
InChIKeyGJPYYNMJTJNYTO-UHFFFAOYSA-J
PubChem CID24939
EC No.233-277-3
現地名硫酸ナトリウムアルミニウム12水

化学・物理的性質

極性表面積177
水素結合供与体数0
水素結合受容体数8
回転可能結合数0
重原子数12
形式電荷0
複雑度62.2
物質分類Metals -> Metals, Inorganic Compounds
密度Colorless crystals or white granules or powder. Density: 1.61mp about 60 °C. Soluble in 1 part water. Practically insoluble in alcohol. /Dodecahydrate/1.610
溶解度110 g anhydrous salt/100 cc of water at 15 °Cinsoluble in ethanolg無水/100gH2O：37.4(0℃)、39.7(20℃)、43.8(40℃)[LAN05]、アルコール不溶[MER06]
Physical DescriptionSodium aluminum sulphate appears as a colorless crystalline solid. Used in textiles, paper making, water purification, food processing.Dodecahydrate: Colorless solidEffloresces in air[Hawley] White odorless powderSoluble in water[MSDSonline]
Stability/Shelf LifeLow melting solids or colorless, volatile liquids. /Alkylaluminum halides/Less sensitive than trialkylaminums to oxidation upon exposure to air. /Alkylaluminum halides/
Other Experimental PropertiesSaline, astringent tasteeffloresces in air /Dodecahydrate/
融点~60℃ [MER06]
屈折率1.4388
外観・状態無色の結晶
色colorless crystals, crystalline
化粧品成分の機能制汗剤収斂性
InChIInChI=1S/Al.Na.2H2O4S/c2*1-5(2,3)4/h2*(H2,1,2,3,4)/q+3+1/p-4
InChIKeyGJPYYNMJTJNYTO-UHFFFAOYSA-J
SMILESS([O-])(=O)(=O)[O-].S([O-])([O-])(=O)=O.[Al+3].[Na+]
LogP（分配係数）-1.031 (est)
CAS データベース10102-71-3
EPAの化学物質情報Aluminum sodium disulfate (10102-71-3)

化学的特性

Colorless crystals; saline, astringent taste; effloresces in air. Soluble in water, insoluble in alcohol. Noncombustible.

安全性と法規制

GHS 分類This chemical does not meet GHS hazard criteria for 100% (2 of 2) of all reports.Not ClassifiedAggregated GHS information provided per 2 reports by companies from 1 notifications to the ECHA C&L Inventory.
規制情報Sulfuric acid, aluminum sodium salt (2:1:1): Does not have an individual approval but may be used under an appropriate group standard
輸送ラベル（DOT）Class 9
火災危険Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
火災の可能性Certain polymerization catalysts, such as aluminum alkyls, react & burn violently on contact with water. /Aluminum alkyls/Aluminum alkyls are organic aluminum compounds that are highly reactive and dangerous because of spontaneous burning in air. /Aluminum alkyls/Prophoric material in flammable solvent. Vapors are heavier than air & may travel to a source of ignition & flash back. /Aluminum alkyls/
健康有害性Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
有害性の概要May cause eye irritation[HSDB] May cause irritation[MSDSonline] The dodecahydrate is CAS # 7784-28-3 (sodium alum)See Aluminum potassium sulfate dodecahydrate. See Aluminum.
FDA 要件Sodium aluminum sulfate is an indirect food additive for use only as a component of adhesives.Aluminum sodium sulfate is generally recognized as safe when used in accordance with good manufacturing practice.Aluminum sodium sulfate used as a general purpose food additive in animal drugs, feeds, and related products is generally recognized as safe when used in accordance with good manufacturing or feeding practice.
反応性グループSalts, Acidic
Special ReportsAnonInformation profiles on Potential Occupaional Hazards: Aluminum & Compounds, 2nd Draft (Revised)GRA & I Issue 21 NTIS/PB89-216238 (1989)> TD3: Information profiles are working papers used by the National Institute for Occupational Safety and Health to assist the Institute in establishing priorities. The proile summarizes data on organic and inorganic substances containing aluminum as the only metal. Each summary presents data on known and suspected health effects, the extent of worker exposure, physical and chemical properties and the industrial importance of the following aluminum compounds: aluminum metal, aluminum ammonium sulfate, aluminum chlorhydrate, aluminum chloride anhydrous, aluminum chloride hydrous, aluminum distearate, aluminum ethoxide, aluminum fluoride, aluminum hydride, aluminum hydroxide, aluminum nitrate, aluminum oxide, aluminum ortho-phosphate, aluminum potassium sulfate, aluminum silicate, aluminum sodium sulfate, aluminum sulfate, calcium aluminum silicate, diethylaluminum chloride, sodium aluminate, tri-n-butylaluminum, triethylaluminum, tri-n-hexylaluminum, triisobutylaluminum, tri-n-octylaluminum. Detailed literature searches are conducted to identify information to be used in the profile sumaries. Sponsored by National Inst. for Occupational Safety and Health, Rockville, MD.

用途

用途

一般分析。

使用

Sodium Aluminum Sulfate is a leavening agent that releases the majority of the gas during baking, and is not used alone but in com- bination with a faster-acting leavening agent such as monocalcium phosphate. this results in a double-acting baking powder. it is almost nonreactive until heat is applied. it is used in baked goods.

一般的な説明

A colorless crystalline solid. Used in textiles, paper making, water purification, food processing.

OSHA StandardsVacated 1989 OSHA PEL TWA 2 mg/cu m is still enforced in some states. /Aluminum (soluble salts & alkyls, as Al)/
Reactivity ProfileSODIUM ALUMINUM SULPHATE gives acidic solutions in water.
Air and Water ReactionsSolid effloresces in air. Water soluble.
消火Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
応急処置Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
消火手順Stop flow of liquid before extinguishing fire. Use dry chemical or carbon dioxide. DO NOT use water as straight stream directly on spilled material. Water fog can be used to control fire. DO NOT use halogenated extinguishing agents on spilled material. Violent reaction may result. Use water spray to keep fire-exposed containers cool. Fight fire from protected location or maximum possible distance. /Aluminum Alkyls/
保管条件Extremely reactive with air, moisture and compounds containing active hydrogen and therefore must be kept under a blanket of inert gas. /Aluminum alkyls/In general, materials ... toxic as stored or which can decompose into toxic components ... Should be stored in cool ... ventilated place, out of ... sun, away from ... fire hazard ... be periodically inspected and monitored. Incompatible materials should be isolated ...All possibility of contact with water must be avoided. Solution containing not more than 20% of these compounds in non-reactive solvents, however, can be handled without risk of spontaneous ignition. /Aluminum alkyls/Must be stored in an inert atmospheresensitive to oxidation and hydrolysis in air. /Trialkylaluminums/Separate from air, water, halocarbons, alcohols. Store in a cool, dry, well-ventilated location. Outside or detached storage is preferred. Inside storage should be in a standard flammable liquid storage warehouse, room, or cabinet. /Aluminum alkyls/
非火災時の漏出対応Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
処分方法Aluminum compounds are treated under anhydrous conditions to prevent violent reactions, recover solvent, and form Al compounds suitable for landfill by reaction with anhydrous hydrolysis agent, eg calcium hydroxide. /Aluminum compounds/SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational exposure or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air qualitypotential migration in soil or watereffects on animal, aquatic, and plant lifeand conformance with environmental and public health regulations.
Preventive MeasuresSRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.Work clothing that becomes wet or significantly contaminated should be removed and replaced. /Aluminum (soluble salts and alkyls, as Al)/Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises. /Aluminum (soluble salts and alkyls, as Al)/The worker should immediately wash the skin when it becomes contaminated. /Aluminum (soluble salts and alkyls, as Al)/SRP: Contaminated protective clothing should be segregated in such a manner so that there is no direct personal contact by personnel who handle, dispose, or clean the clothing. Quality assurance to ascertain the completeness of the cleaning procedures should be implemented before the decontaminated protective clothing is returned for reuse by the workers. Contaminated clothing should not be taken home at end of shift, but should remain at employee's place of work for cleaning.
Isolation and EvacuationExcerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
Minimum Risk LevelIntermediate Oral: 1.0 mg/kg/day (L134) Chronic Oral: 1.0 mg/kg/day (L134)
Threshold Limit Values (TLV)8 hr Time Weighted Avg (TWA): 1 mg/cu m, respirable fraction. /Aluminum metal and insoluable compounds/Excursion Limit Recommendation: Excursions in worker exposure levels may exceed 3 times the TLV-TWA for no more than a total of 30 minutes during a work day, and under no circumstances should they exceed 5 times the TLV-TWA, provided that the TLV-TWA is not exceeded. /Aluminum metal and insouble compounds/A4: Not classifiable as a human carcinogen. /Aluminum metal and insouble compound/
Personal Protective Equipment (PPE)Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:Wear appropriate personal protective clothing to prevent skin contact. /Aluminum (soluble salts and alkyls, as Al/Wear appropriate eye protection to prevent eye contact. /Aluminum (soluble salts and alkyls, as Al)/Protective clothing and a high standard of training in the necessary precautionary measures are essential for the handling of the materials. /Aluminum alkyls/
TreatmentEYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.
相互作用Astringent gingival deflection agents such as alum, aluminum sulfate, & aluminum chloride exert no systemic effects. ... /Aluminum sulfate/
健康影響Aluminum targets the nervous system and causes decreased nervous system performance and is associated with altered function of the blood-brain barrier. The accumulation of aluminum in the body may cause bone or brain diseases. High levels of aluminum have been linked to Alzheimer's disease. A small percentage of people are allergic to aluminium and experience contact dermatitis, digestive disorders, vomiting or other symptoms upon contact or ingestion of products containing aluminium. (L739, L740)
暴露経路Oral (L739)inhalation (L739)
毒性の概要The main target organs of aluminum are the central nervous system and bone. Aluminum binds with dietary phosphorus and impairs gastrointestinal absorption of phosphorus. The decreased phosphate body burden results in osteomalacia (softening of the bones due to defective bone mineralization) and rickets. Aluminum's neurotoxicity is believed to involve several mechanisms. Changes in cytoskeletal protein functions as a results of altered phosphorylation, proteolysis, transport, and synthesis are believed to be one cause. Aluminum may induce neurobehavioral effects by affecting permeability of the blood-brain barrier, cholinergic activity, signal transduction pathways, lipid peroxidation, and impair neuronal glutamate nitric oxide-cyclic GMP pathway, as well as interfere with metabolism of essential trace elements because of similar coordination chemistries and consequent competitive interactions. It has been suggested that aluminum's interaction with estrogen receptors increases the expression of estrogen-related genes and thereby contributes to the progression of breast cancer (A235), but studies have not been able to establish a clear link between aluminum and increased risk of breast cancer (A15468). Certain aluminum salts induce immune responses by activating inflammasomes. (L739, A235, A236)
Signs and SymptomsInhalating aluminum dust causes coughing and abnormal chest X-rays. A small percentage of people are allergic to aluminium and experience contact dermatitis, digestive disorders, vomiting or other symptoms upon contact or ingestion of products containing aluminium. (L739, L740)
Natural Pollution SourcesOccurs naturally as the mineral mendozite
Carcinogen ClassificationNot listed by IARC. IARC classified aluminum production as carcinogenic to humans (Group 1), but did not implicate aluminum itself as a human carcinogen. (L135) A link between use of aluminum-containing antiperspirants and increased risk of breast cancer has been proposed (A235), but studies have not been able to establish a clear link (A15468).
Non-Human Toxicity Excerpts/LABORATORY ANIMALS: Acute Exposure/ ...For anhydrous sodium aluminum lethal oral dose for rabbit is about 2 g/kg.
Evidence for CarcinogenicityA4: Not classifiable as a human carcinogen. /Aluminum metal and insouble compound/
Probable Routes of Human ExposureWORKMEN ... CONTAMINATED WITH ALUM /THROUGH EYES/ ... . /ALUM/Production of aluminum sulfate and aluminum fluoride is associated with exposure to several irritant substances. Such production has been connected with reversible bronchial obstruction or asthma. In an aluminum plant in Sweden, 6 cases of asthma occurred in 1975, and 7 in 1976. The number of exposed workers was 35-40. The levels of aluminum fluoride (personal sampling) were measured during these two years, and the mean concentrations were 3-6 mg/cu m. In 1977, improvements were made at this plant thereby reducing the mean levels of aluminum fluoride to 0.4-1.0 mg/cu m. During the years 1978-1980, only two cases of asthma occurred. /Aluminum sulfate/
State Drinking Water Standards(CA) CALIFORNIA 1000 ug/l /Aluminum/
州飲料水ガイドライン(AZ) ARIZONA 73 ug/l /Aluminum/(CA) CALIFORNIA 200 ug/l /Aluminum/(ME) MAINE 1430 ug/l /Aluminum/
連邦飲料水ガイドラインEPA 50-200 ug/l /Aluminum/
TSCA 収載状態TSCA listed
有害物質データ10102-71-3(Hazardous Substances Data)