基本情報
- CAS
10476-81-0- 標準SMILES
[Br-].[Br-].[Sr+2]- InChIKey
YJPVTCSBVRMESK-UHFFFAOYSA-L- 分子式
- Br2Sr
- 平均分子量
- 247.43 g/mol
- 単同位体質量
- 245.74229
概要
Strontium bromide is a chemical compound of strontium and bromine. It is used in flares and also has some pharmaceutical uses. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. (L625, L666)
名称と識別子
- 優先名称
- Strontium bromide
- IUPAC
- strontium dibromide
- 現地名
- ストロンチウムジブロミド
- 英語名
- Strontium bromide
- 分子式
- Br2Sr
- 分子量
- 247.43
名称と別名
EINECS 233-969-5UNII-1NG558X5VJ1NG558X5VJRefChem:56054DTXCID001326928233-969-5DTXSID30897581Strontium BromatumStrontium bromideSTRONTIUM BROMIDE, ANHYDROUSStrontium bromide (SrBr2)strontium;dibromide
名称をさらに表示
臭化ストロンチウムストロンチウムブロミドストロンチウムジブロミド臭化ストロンチウム, 無水臭化ストロンチウム ANHYDROUS POWDER臭化ストロンチウム/ 99.99%臭化ストロンチウム, 無水, 99%Strontium dibromideSTRONTIUM (II) BROMIDEstrontiumbromide(srbr2)STRONTIUMBROMIDE,PURIFIEDStrontium bromide, GR 99%+
SrBr2Strontium bromide anhydrous powderstrontium(II) bromideStrontiumbromidStrontium bromide, ultra drySCHEMBL15366617D95735
データベース識別子
- CAS
10476-81-0- PubChem CID
- 25302
- EC Number
- 233-969-5
物性
構造計算による物性
- 極性表面積
- 0 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 2
- 回転可能結合数
- 0
- 重原子数
- 3
- 形式電荷
- 0
- 複雑度
- 2.8
実験および物理化学的性質
Chemical ClassesMetals -> Metals, Inorganic Compounds
Physical DescriptionHexahydrate: Colorless deliquescent crystals or white solid; [Merck Index] White powder; [Sigma-Aldrich MSDS]
物理化学的性質
- 融点
- 643 °C · 643°C
- 比重(密度)
- 4 · 4,216 g/cm3
- 外見
- 粉
- 色
- 白い
- 比重
- 4.216 · 4.216
- 水溶解度
- 水、カルビノール、エタノール、アミルアルコールに可溶。エーテルに不溶。
- 比熱容量
- 0.3 J/ · Cp(crystal): 0.3 J/(g·K), at 25℃
- Merck
- 14 · 14,8837
- 安定性
- 吸湿性
- 主な用途
- 電気めっき材料合成前駆体
- InChI
- 1S/2BrH.Sr/h2*1H;/q;;+2/p-2
- InChIKey
- YJPVTCSBVRMESK-UHFFFAOYSA-L
- SMILES
- Br[Sr]Br
- CAS データベース
- 10476 · 10476-81-0(CAS DataBase Reference)
- EPAの化学物質情報
- Strontium bromide (SrBr2) (10476-81-0)
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
Warning
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 45 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
危険有害性情報
Hazards SummaryIntraperitoneal LD50 (rat) = 1,000 mg/kg; [RTECS] A skin and strong eye irritant; Heavy exposure may cause CNS depression; [Sigma-Aldrich MSDS] See Calcium bromide and Magnesium bromide.
Hazard Classes and CategoriesSkin Irrit. 2 (100%)
毒性情報
Treatment
EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.
Health Effects
Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)
化学と産業
薬理情報
Metabolism/Metabolites
Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)
用途と製造
UsesHas been used as an anticonvulsant and sedative; [Merck Index]
応用分野
解説臭化ストロンチウム．炭酸ストロンチウムを臭化水素酸に溶かし，濃縮すると六水和物が得られる．六水和物は無色の六方晶系針状結晶．吸湿性があり，水に易溶．密度2.39 g cm－3．88.2 ℃ で融解して二水和物となり，さらに高温で一水和物となる．無水物は炭酸ストロンチウムと臭化アンモニウムとを強熱して得られる．無色の六方晶系針状結晶．密度4.22 g cm－3．融点657 ℃．融点以上に熱すると分解する．吸湿性があり，水に易溶．医薬品(鎮静剤，抗てんかん剤)，分析試薬などに用いられる．
説明Strontium bromide has the formula SrBr2. At room temperature, it is a white, odorless, crystalline powder with the molecular weight of 247.43 g/mol. Strontium bromide burns bright red in a flame test. It is used in flares and also has some pharmaceutical uses. Several hydrates have been characterized including the monohydrate and the hexahydrate, SrBr2·6H2O. This salt is a white, hygroscopic powder soluble in water and alcohol. It loses water at 180°C, melts at 643°C and is used in medicine and as an analytical reagent. The anhydrate, SrBr2, is a colorless, transparent, crystal, odorless, having a bitter, saline taste. It is very deliquescent and soluble in water and is readily soluble in alcohol and amyl alcohol. The specific gravity of SrBr2 is 4.210 g/cm3. It can be prepared by treating SrCO3 with a hydrogen bromide solution. Alternatively, a strontium salt (carbonate, sulfate, chloride, etc.) is treated with bromine or hydrobromic acid in presence of a reducing agent.
使用Strontium bromide are colorless crystals made by neutralizing hydrobromic acid with strontium hydrate. The crystals are soluble in water but less so in alcohol. Strontium bromide was occasionally used to increase contrast in collodion emulsions.
調製方法
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