Tetrahydrofurfurylamine (HCID 253298)

概要

Tetrahydrofurfurylamine appears as a colorless to light yellow liquid. Insoluble in water and less dense than water. Used to make other chemicals and as a photographic chemical.

名称と識別子

優先名称: Tetrahydrofurfurylamine
IUPAC: oxolan-2-ylmethanamine
現地名: テトラヒドロフルフリルアミン
英語名: 2-Tetrahydrofurfurylamine
分子式: C5H11NO
分子量: 101.15

名称と別名

Tetrahydrofurfurylamine4795-29-32-Tetrahydrofurfurylamine2-Furanmethanamine, tetrahydro-2-(Aminomethyl)tetrahydrofuranTetrahydro-2-furanmethanamine2-AminomethyltetrahydrofuranFurfurylamine, tetrahydro-USAF Q-2NSC 76037EINECS 225-351-9BRN 0102729

名称をさらに表示

テトラヒドロフルフリルアミン[(テトラヒドロフラン-2-イル)メチル]アミン(テトラヒドロフラン-2-イルメチル)アミン2-(アミノメチル)テトラヒドロフランテトラヒドロ-2-フランメタンアミンテトラヒドロフラン-2-イルメチルアミン(テトラヒドロフラン-2-イル)メチルアミンオキソラン-2-メタンアミンテトラヒドロフラン-2-メタンアミン2,3,4,5-テトラヒドロフラン-2-メタンアミン(テトラヒドロフラン-2-イル)メタンアミン2-アミノメチルテトラヒドロフラン2-テトラヒドロフルフリルアミン(tetrahydrofuran-2-yl)MethanaMineTHFAMFurosemide Impurity 61-(oxolan-2-yl)methanamineusafq-2AKOS BBS-000035872-TetrahydrofurfurylOxolane-2-methanamine

AI3-25429Tetrahydro-2-furanylmethylamine(tetrahydrofuran-2-ylmethyl)amine2-tetrahydrofuranmethanamine5-18-09-00488 (Beilstein Handbook Reference)(.+/-.)-TetrahydrofurfurylamineDTXSID40863454UN 2943

データベース識別子

CAS: 4795-29-3
PubChem CID: 253298
DTXSID: DTXSID40863454
EC Number: 225-351-9
Nikkaji: J1.830I

物性

構造計算による物性

XLogP: -0.3
極性表面積: 35.3 Å²
水素結合供与体数: 1
水素結合受容体数: 2
回転可能結合数: 1
重原子数: 7
形式電荷: 0
複雑度: 56

実験および物理化学的性質

Chemical ClassesFlammable agents - 2nd degree

SpringerMaterials PropertiesExcess enthalpy

Physical DescriptionTetrahydrofurfurylamine appears as a colorless to light yellow liquid. Insoluble in water and less dense than water. Used to make other chemicals and as a photographic chemical.

物理化学的性質

融点: 136 °C · 136 °C
沸点: 153 · 153-154 °C744 mm Hg(lit.)
比重(密度): 0.98 g/mL · 0.98 g/mL at 25 °C(lit.)
屈折率: 20 · n20/D 1.454(lit.)
闪点: 114 °F · 114 °F
貯蔵温度: Flammables area
溶解性: クロロホルム、メタノール
酸解離定数(Pka): 9.47 · 9.47±0.29(Predicted)
外見: 液体
色: 無色透明～薄黄色
爆発限界(explosive limit): 1.6 · 1.6-14.1%(V)
水溶解度: 混和性
BRN: 102729 · 102729
InChI: 1S/C5H11NO/c6-4-5-2-1-3-7-5/h5H,1-4,6H2
InChIKey: YNOGYQAEJGADFJ-UHFFFAOYSA-N
SMILES: NCC1CCCO1
LogP: -0.348 · -0.348 (est)
CAS データベース: 4795 · 4795-29-3(CAS DataBase Reference)
NISTの化学物質情報: 2 · 2-Furanmethanamine, tetrahydro-(4795-29-3)
EPAの化学物質情報: Tetrahydrofurfurylamine (4795-29-3)

化学的性質

化学的特性Colorless to light-yellow liquid. Distilling range 150– 156C, d 0.977 (20C/20C). Combustible.

安全と法規制

GHS分類

GHS Classification · 4 件

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 153 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 2 件

Status: Active Update: 28-06-2017 https://echa.europa.eu/registration-dossier/-/registered-dossier/19861

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelFlammable Liquid

Fire Hazards · 2 件

Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Health Hazards · 2 件

Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

· May cause toxic effects if inhaled or absorbed through skin.

DOT ID and Guide2943 129

Reactive GroupAmines, Phosphines, and Pyridines

安全と保護具

Fire FightingExcerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

Accidental Release Measures · 2 件

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 件

Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).

Nonfire Spill ResponseExcerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

Isolation and Evacuation · 2 件

Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

Immediate precautionary measure

安全データ

wgk: 3
tsca: TSCA listed
rtecs: LV0175000
ridadr: UN 2943
hs_code: 29321900
risk_code: 10-36/37/38
化審法: (9)-854
消防法: 危-4-2-III
hazard_code: Xi
safety_code: 26-36-37/39-16
hazard_class: 3
packing_group: III
Hazard Classifications: Eye Irrit. 2Flam. Liq. 3Skin Irrit. 2
ストレージクラス: 3 - Flammable liquids

化学と産業

用途と製造

General Manufacturing Information2-Furanmethanamine, tetrahydro-: ACTIVE

応用分野

使用Chemical intermediate, fine-grain photographic development, vulcanization accelerator.

一般的な説明A colorless to light yellow liquid. Insoluble in water and less dense than water. Flash point between 100 - 141°F. Used to make other chemicals and as a photographic chemical.