基本情報
- 標準SMILES
C(OCC1CO1)C(COCC1CO1)OCC1CO1- InChIKey
SYEWHONLFGZGLK-UHFFFAOYSA-N- 分子式
- C12H20O6
- 平均分子量
- 260.28 g/mol
- 単同位体質量
- 260.12598836
概要
structure given in first source
名称と識別子
- 優先名称
- Triglycidylglycerol
- IUPAC
- 2-[1,3-bis(oxiran-2-ylmethoxy)propan-2-yloxymethyl]oxirane
- 現地名
- 2,2',2''-[1,2,3-プロパントリイルトリ(オキシメチレン)]トリスオキシラン
- 英語名
- Glycerol triglycidyl ether
- 分子式
- C12H20O6
- 分子量
- 260.28
名称と別名
名称をさらに表示
データベース識別子
- CAS
13236-02-7- PubChem CID
- 25795
- DTXSID
DTXSID00884584- UNII
- 0KVT2Q7Z17
- EC Number
- 236-211-1
- Nikkaji
- J213.768B
物性
構造計算による物性
- XLogP
- -1.1
- 極性表面積
- 65.3 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 6
- 回転可能結合数
- 11
- 重原子数
- 18
- 形式電荷
- 0
- 複雑度
- 243
実験および物理化学的性質
物理化学的性質
- 沸点
- 378.7 · 378.7±42.0 °C(Predicted)
- 比重(密度)
- 1.251 · 1.251±0.06 g/cm3(Predicted)
- 貯蔵温度
- 2 · 2-8°C, stored under nitrogen
- InChI
- InChI=1S/C12H20O6/c1(13-3-10-5-16-10)9(15-7-12-8-18-12)2-14-4-11-6-17-11/h9-12H,1-8H2
- InChIKey
- SYEWHONLFGZGLK-UHFFFAOYSA-N
- SMILES
- C(OCC1CO1)C(OCC1CO1)COCC1CO1
- CAS データベース
- 13236 · 13236-02-7
- EPAの化学物質情報
- Glycerol triglycidyl ether (13236-02-7)
安全と法規制
GHS分類
GHS Classification
Warning
H315 (97.1%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P272, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P333+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 70 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
危険有害性情報
Regulatory Information
Chemical: Oxirane, 2,2',2''-[1,2,3-propanetriyltris(oxymethylene)]tris-
TP - indicates a substance that is the subject of a proposed TSCA section 4 test rule.
Status: Active Update: 16-03-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/34059
Triglycidylglycerol: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
安全と保護具
Fire Fighting Procedures
Cool fire exposed containers with water... fight fire with chemical foam, water, carbon dioxide, or dry chemicals. /Glycidyl ethers/
Dry chemical extinguishers should be placed in areas where glycidyl ethers are loaded, unloaded, or stored. /Glycidyl ethers/
Storage Conditions
Should be stored in a cool place where they will be protected from extreme temperatures. /Glycidyl ethers/
Keep away from acids, bases, and salts. /Glycidyl ethers/
Preventive Measures
Leather articles such as belts or shoes which become contaminated with glycidyl ethers shall be discarded. /Glycidyl ethers/
Use only spark-proof tools in areas where glycidyl ethers are in use. /Glycidyl ethers/
No consumption of food or beverages in areas where glycidyl ethers are in use. /Glycidyl ethers/
Safety showers and eyewash fountains shall be provided in appropriate areas. /Glycidyl ethers/
For more Preventive Measures (Complete) data for TRIGLYCIDYLGLYCEROL (7 total), please visit the HSDB record page.
Personal Protective Equipment (PPE)
Protective clothing... gloves, aprons, suits, boots and face shields (8 in minimum) should be made of materials impervious to glycidyl ethers, eg., milled butyl rubber or polyvinyl alcohol... such clothing should be fire-resistant. /Glycidyl ethers/
Chemical safety goggles (splash proof) should be worn. /Glycidyl ethers/
Gloves shall be of sufficient length to protect forearms of workers. /Glycidyl ethers/
Unacceptable glove material include: natural rubber (latex), neoprene-natural rubber (latex), milled neoprene, neoprene with nylon, milled Buna-N, vinyl and polyethylene (disposable), and polyvinyl chloride. /Glycidyl ethers/
毒性情報
Medical Surveillance
Comprehensive medical and work histories...Emphasis directed to prior exposure to glycidyl ethers or other vinyl derivatives... History of sensitivities, allergies, and reproductive events. Physical examination.. Attention to the skin, eyes, and mucous membranes. Clinical tests: total and differential leukocyte counts, urinalysis, pulmonary function tests, tests of manual dexterity, and visual-motor coupling. /Glycidyl ethers/
Non-Human Toxicity Excerpts
THE MUTAGENIC ACTIVITIES OF EPOXIDE COMPOUNDS, INCLUDING GLYCERYL GLYCIDYL ETHER, WERE EXAMINED BY THE DNA REPAIR & REVERSION TESTS WITH STRAINS OF ESCHERICHIA COLI & SALMONELLA TYPHIMURIUM. WHEREIN SOME EPOXIDE COMPOUNDS OF RELATIVELY LOW MOLECULAR WEIGHT INDUCE MUTATION, THE MUTAGENICITY OF THE EPOXIDE RESINS MIGHT BE INFLUENCED BY THEIR SOLUBILITIES &(OR) TRANSPORTATION THROUGH CELLULAR MEMBRANES.
Glycidyl ethers are capable of producing testicular atrophy and hemopoietic abnormalities in various species of laboratory animals. /Glycidyl ethers/
Intramuscular injections of glycidyl ethers in Long-Evans rats ... produced ... up to 400 mg/kg ... CNS effects including muscular incoordination reduced motor activity, agitation, excitement, deep depression, /deep/ sleep, and coma. ... Route of administration ... important in the onset, duration, and severity of CNS effects. ... /Glycidyl ethers/
Glycidyl ethers produce widespread systemic effects ... necrosis, edema, inflammation, hyperemia, hemorrhaging, and tissue degeneration. /Glycidyl ethers/
Probable Routes of Human Exposure
Inhalation of glycidyl ethers in the manufacture or utilization of adhesives, tooling and molding operations, and the application of protective coatings containing epoxy resins. /Glycidyl ethers/
Skin contact in handling glycidyl ethers and uncured resins. /Glycidyl ethers/
法規制情報
安全データ
- tsca
- TSCA listed
- 有毒物質データの
- 13236-02-7(Hazardous Substances Data)
化学と産業
用途と製造
Uses
Used as reactive diluent and to make epoxy resins flexible; [HSDB]
Plastic Composites Manufacturing [Category: Industry]
Used as reactive diluents in epoxy manufacture and/or utilization systems. /Glycidyl ethers/
REACTIVE DILUENT & FLEXIBILIZER FOR EPOXY RESINS
U.S. Exports
(1979) No Data
(1981) No Data
U.S. Imports
(1979) No Data
(1981) No Data
U.S. Production
(1979) AT LEAST 4.54X10+6 GRAMS
(1981) No Data
応用分野
説明Glycerol triglycidyl ether is colorless to slight yellow transparent liquid.Glycerol triglycidyl ether is used in paint and coating applications such as appliance paint, boat paint, building coating, car paint, electrical insulating varnish, furniture paint, paper coating, plastic coating, road marking paint, rubber coating.
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