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亜硝酸アンモニウム

Ammonium nitrite

HCID 26004
ノート反応
基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
部分構造検索類似構造を探す

基本情報

CAS
13446-48-5
標準SMILES
O=N[O-].[NH4+]
InChIKey
CAMXVZOXBADHNJ-UHFFFAOYSA-N
分子式
H4N2O2
平均分子量
64.044 g/mol
単同位体質量
64.02727737

概要

Ammonium nitrite is a chemical compound of ammonium and nitrite ions. It is used as a rodenticide, microbiocide and agricultural pesticide, and is acutely toxic to both humans and aquatic organisms. Nitrite is a toxic compound known to cause methemoglobinemia. (L1137, L1614)

名称と識別子

優先名称
Ammonium nitrite
IUPAC
azanium nitrite
現地名
亜硝酸アンモニウム
英語名
AMMONIUM NITRITE, 20% SOLN
分子式
H4N2O2
分子量
64.04396

名称と別名

Ammonium nitriteNitrous acid, ammonium salt (1:1)Nitrous acid, ammonium saltCaswell No. 044CEINECS 236-598-771ZQG69956EPA Pesticide Chemical Code 076201DTXSID7065461UNII-71ZQG69956EC 236-598-7AMMONIUM NITRITE (NH4NO2)RefChem:112184
名称をさらに表示
亜硝酸アンモニウムアザニウミル ニトリットazanium,nitritenitrousacid,ammoniumsaltAMMONIUM NITRITE, 20% SOLNAMMONIUM NITRITE, 20% SOLN ISO 9001:2015 REACH
Nitrous acid ammonium saltDTXCID6034213Nitrous acid ammonium salt (1:1)UN3219236-598-713446-48-5azanium;nitriteAmmoniumnitrit

データベース識別子

CAS
13446-48-5
PubChem CID
26004
DTXSID
DTXSID7065461
UNII
71ZQG69956
EC Number
236-598-7

物性

構造計算による物性

極性表面積
53.5 Ų
水素結合供与体数
1
水素結合受容体数
3
回転可能結合数
0
重原子数
4
形式電荷
0
複雑度
7.5

実験および物理化学的性質

Chemical ClassesNitrogen Compounds -> Nitrates and Nitrites
Physical DescriptionAvailable as 20% solution: clear to yellow liquid; [MSDSonline] Very unstable and almost always handled as aqueous solution; [Ullmann]

物理化学的性質

融点
60 · explodes at 60–70, producing N2, H2O, and other products [KIR78] [CIC73]
沸点
30 °C · 30°C
比重(密度)
1.69 · 1.690
溶解性
insoluble in ethyl ether
色
白色から黄色の結晶
水溶解度
100 g · g/100g 水溶液: 56.0 (1.4°C), 64.3 (19.15°C); 平衡固相 NH4NO2 [KRU93]
CAS データベース
13446 · 13446-48-5
EPAの化学物質情報
Ammonium nitrite (13446-48-5)

化学的性質

化学的特性white-yellowish crystal(s); uncertain stability; can be made by adding a solution of barium nitrite to ammonium sulfate solution [KIR78] [CRC10]

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS ClassificationNot Classified

危険有害性情報

Regulatory InformationStatus: Cease Manufacture Update: 28-03-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/23380
Hazards SummaryA skin, eye, and respiratory tract irritant; May be harmful if swallowed; [MSDSonline] See NITRATES and NITRITES.
DOT Hazard Classification · 2 件

Ammonium nitrite

Forbidden explosives/materials (49 eCFR § 173.54/§ 173.21)

Hazard Classes and CategoriesNot Classified

毒性情報

Treatment · 1 件

Methemoglobinemia can be treated with supplemental oxygen and methylene blue 1% solution administered intravenously slowly over five minutes followed by IV flush with normal saline. Methylene blue restores the iron in hemoglobin to its normal (reduced) oxygen-carrying state. (L1613)

Health EffectsNitrite poisoning causes methemoglobinemia. Nitrites may cause pregnancy complications and developmental effects. They may also be carcinogenic. (L1137)
Adverse EffectsMethemoglobinemia - The presence of increased methemoglobin in the blood; the compound is classified as secondary toxic effect
Exposure RoutesOral (L1137) ;inhalation (L1137)
Toxicity Summary · 1 件

化学と産業

薬理情報

Metabolism/MetabolitesNitrites and their metabolites are excreted in the urine. (L1137)

用途と製造

Uses · 2 件

Used to passivate boiler equipment and chemical plants; Used as a blowing agent in the production of hollow rubber materials; [Ullmann]

Ammonium nitrite is used as a rodenticide, microbiocide and agricultural pesticide. (L1614)

General Manufacturing InformationNitrous acid, ammonium salt (1:1): ACTIVE

上流・下流製品情報

下流製品

3-メチル-1-フェニル-5-ピラゾロン

サプライヤー7 社

陕西缔都新材料有限公司029-63373950 17392216152 · [email protected]
上海湄水化工科技有限公司021-60549325 18616193163
陕西缔都医药化工有限公司+86-29-87569262 +86-15003564040 · [email protected]
厦门盈融达化工有限公司+86-0592-6210733 · [email protected]
XIAMEN AMITY INDUSTRY AND TRADE CO., LTD.+8618950047208 · [email protected]
上海宝杨宝欣生物科技有限公司021-56698539 19921169802 · [email protected]

関連反応

1 件
反応記録を作成
HRID 1773244 の反応式
HRID 1773244反応物としてuspto-grants-2016_02

化合物ノート

読み込み中…

このページの内容基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート

Nitrite causes the autocatalytic oxidation of oxyhemoglobin to hydrogen peroxide and methemoglobin. This elevation of methemoglobin levels is a condition known as methemoglobinemia, and is characterized by tissue hypoxia, as methemoglobin cannot bind oxygen. (A2450, L1613)

Signs and Symptoms · 1 件

Nitrite poisoning causes methemoglobinemia. Symptoms include cyanosis, cardiac dysrhythmias and circulatory failure, and progressive central nervous system (CNS) effects. CNS effects can range from mild dizziness and lethargy to coma and convulsions. (L1137)

Carcinogen ClassificationIngested nitrate or nitrite under conditions that result in endogenous nitrosation is probably carcinogenic to humans (Group 2A). (L135)

安全データ

tsca
TSCA listed
DAYANG CHEM (HANGZHOU) CO.,LTD+86-88938639 +86-17705817739 · [email protected]