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トリブロモインジウム(III)

Indium tribromide

HCID 26046
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基本情報概要名称と識別子物性安全と法規制化学と産業関連反応化合物ノート
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基本情報

CAS
13465-09-3
標準SMILES
[Br][In]([Br])[Br]
InChIKey
JKNHZOAONLKYQL-UHFFFAOYSA-K
分子式
Br3In
平均分子量
354.53 g/mol
単同位体質量
351.65889

概要

Indium(III) bromide is a chemical compound of indium and bromine. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. (L625)

名称と識別子

優先名称
Indium tribromide
IUPAC
tribromoindigane
現地名
トリブロモインジウム(III)
英語名
INDIUM(III) BROMIDE
分子式
Br3In
分子量
354.53

名称と別名

Indium tribromidetribromoindiganeIndium bromide (InBr3)DTXSID50654850099V88160RefChem:1087290DTXCID8034243236-692-813465-09-3Indium(III) bromidetribromoindiumInBr3
名称をさらに表示
トリブロモインジウム(III)三臭化インジウムインジウム(III)トリブロミド臭化インジウム(III)臭化インジウム臭化インジウム(III)無水臭化インジウム(III), 無水, 99.99% (metals basis)INDIUM BROMIDEIndium(Ⅲ) bromideindiumbromide(inbr3)Indium(III) tribromideIII)Indium(III bromide
MFCD00011057Indium(III) bromide, anhydrousIndium bromideIndium(III) bromide, 99%SCHEMBL151438EINECS 236-692-8UNII-0099V88160AKOS040765860

データベース識別子

CAS
13465-09-3
PubChem CID
26046
DTXSID
DTXSID5065485
EC Number
236-692-8

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
0
回転可能結合数
0
重原子数
4
形式電荷
0
複雑度
8

実験および物理化学的性質

Chemical ClassesMetals -> Metals, Inorganic Compounds
Physical DescriptionWhite solid; [Merck Index] Yellowish odorless crystalline powder; [MSDSonline]

物理化学的性質

融点
220 °C · 220 °C(lit.)
沸点
656 °C · 656 °C(lit.)
比重(密度)
4.96 g/mL · 4.96 g/mL at 25 °C(lit.)
蒸気密度
1 · >1 (vs air)
貯蔵温度
Inert atmosphere,Room Temperature
外見
結晶性粉末
色
白から黄色
比重
4.74 · 4.74
水溶解度
水に溶ける。
安定性
吸湿性
InChI
InChI=1S/3BrH.In/h3*1H;/q;;;+3/p-3
InChIKey
JKNHZOAONLKYQL-UHFFFAOYSA-K
SMILES
[In](Br)(Br)Br
EPAの化学物質情報
Indium bromide (InBr3) (13465-09-3)

化学的性質

化学的特性Off-white to greenish powder

安全と法規制

安全情報は参考情報です。供給元の安全データシート(SDS)、適用法令、専門家による評価に代わるものではありません。

GHS分類

GHS Classification · 4 件

Danger

H314 (14%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P261, P264, P264+P265, P271, P280, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P319, P321, P332+P317, P337+P317, P362+P364, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 50 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Hazards SummaryA corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline] See Bromine. See Indium.
Hazard Classes and CategoriesSkin Corr. 1B (14%)

安全と保護具

Threshold Limit Values (TLV)0.1 [mg/m3], as In

毒性情報

Treatment · 1 件

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1 件

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)

Adverse EffectsDermatotoxin - Skin burns.
Exposure RoutesOral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1 件

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1 件

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

安全データ

wgk
3
tsca
TSCA listed
ridadr
UN3260
hs_code
28275900
risk_code
36/37/38
hazard_code
Xi
safety_code
26-36
hazard_class
8
packing_group
III
Hazard Classifications
Eye Irrit. 2Skin Irrit. 2STOT SE 3
ストレージクラス
11 - Combustible Solids

化学と産業

薬理情報

Metabolism/Metabolites · 1 件

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

用途と製造

UsesUsed as regio-, chemo-, and stereoselective Lewis acid catalyst in organic synthesis; [Merck Index]
General Manufacturing InformationIndium bromide (InBr3): ACTIVE
応用分野 · 1 件

使用"Indium(III) bromide is used in organic synthesis as a water tolerant Lewis acid.It efficiently catalyzes the three-component coupling of β-keto esters, aldehydes and urea (or thiourea) to afford the corresponding dihydropyrimidinones. It is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells."

調製方法 · 1 件

製造方法According to Thiel, metallic In is heated in a fast air-free stream of CO2, which is saturated with Br2 vapor by passage through a wash bottle containing Br2 (the bottle should be placed in a warm water bath). A melt of InBr and InBr3 forms first. This melt is brown at first, but gradually becomes lighter. Finally it turns to solid InBr3. The latter can be readily sublimed to form lustrous crystalline spangles.

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