化工社化工社 化学情報印刷レポート · 研究参考用
クロロフルオロ硫黄(VI)ジオキシド
クロロフルオロ硫黄(VI)ジオキシド · スルホニルクロリドフルオリド · 硫酸クロリドフルオリド · スルフロイル クロリド フルオリド · スルフロクロリド酸 · フルオリド硫酸クロリド · SO2ClF · fluorosulfonylchloride
識別子と物理属性
| CAS No. | 13637-84-8 |
|---|---|
| 分子式 | ClFO2S |
| 平均分子量 | 118.52 g/mol |
| 単同位体質量 | 117.9291563 g/mol |
| SMILES | O=S(=O)(F)Cl |
| InChIKey | IXPAAHZTOUOJJM-UHFFFAOYSA-N |
| PubChem CID | 26159 |
| ChEBI | CHEBI:39445 |
| EC No. | 237-126-2 |
| DTXSID | DTXSID0065567 |
| 現地名 | クロロフルオロ硫黄(VI)ジオキシド |
化学・物理的性質
| XLogP | 0.9 |
|---|---|
| 極性表面積 | 42.5 |
| 水素結合供与体数 | 0 |
| 水素結合受容体数 | 3 |
| 回転可能結合数 | 0 |
| 重原子数 | 5 |
| 形式電荷 | 0 |
| 複雑度 | 95 |
| Physical Description | Liquefied gasReacts with water[MSDSonline] |
| 融点 | -125 °C |
| 沸点 | 7 °C |
| 密度 | 1.623 g/cm3(Temp: 0 °C) |
| 引火点 | 113 °C |
| 貯蔵条件 | -20°C |
| 溶解度 | reacts with H2O |
| 外観・状態 | gas |
| 色 | colorless |
| CAS データベース | 13637-84-8(CAS DataBase Reference) |
| EPAの化学物質情報 | Sulfuryl chloride fluoride (13637-84-8) |
化学的特性
clear colorless to light yellow liquid
安全性と法規制
| GHS 分類 | DangerH301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]H311 (100%): Toxic in contact with skin [Danger Acute toxicity, dermal]H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]H318 (100%): Causes serious eye damage [Danger Serious eye damage/eye irritation]H331 (100%): Toxic if inhaled [Danger Acute toxicity, inhalation]P260, P261, P262, P264, P264+P265, P270, P271, P280, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P361+P364, P363, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 39 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. |
|---|---|
| 規制情報 | Sulfuryl chloride fluoride: Does not have an individual approval but may be used under an appropriate group standard |
| 有害性の概要 | A corrosive substance that can cause injury to the skin, eyes, and respiratory tractInhalation may cause pulmonary edema[MSDSonline] |
| Hazard Classes and Categories | Acute Tox. 3 (100%)Skin Corr. 1B (100%)Eye Dam. 1 (100%) |
| 暴露管理・個人防護 | TIH (Toxic Inhalation Hazard) - Term used to describe gases and volatile liquids that are toxic when inhaled. Some are TIH materials themselves, e.g., chlorine, and some release TIH gases when spilled in water, e.g., chlorosilanes. [ERG 2016].1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)] |
| Threshold Limit Values (TLV) | 2.5 [mg/m3], as F |
| Permissible Exposure Limit (PEL) | 2.5 [mg/m3], as F |
| 有害作用 | Dermatotoxin - Skin burns.Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors. |
| Toxicity Data | LCLo (mice) = 520 mg/m3/10min |
| 水環境危害等級（WGK） | 3 |
| TSCA 収載状態 | TSCA listed |
| RTECS 番号 | WT4900000 |
| 輸送番号（UN） | UN 2922 8/PG 1 |
| 危険文句（R） | 14-23/24/25-34 |
| 危険表示 | T,C |
| hazard_note | Corrosive/Toxic/Moisture sensitive |
| 安全措置（S） | 26-27-28-36/37/39-45 |
| 危険等級 | 2.3 |