クロロフルオロ硫黄(VI)ジオキシド

Sulfuryl chloride fluoride

HCID 26159CAS 13637-84-8

部分構造検索類似構造を探す

基本情報

標準SMILES: O=S(=O)(F)Cl
InChIKey: IXPAAHZTOUOJJM-UHFFFAOYSA-N
分子式: ClFO2S
平均分子量: 118.52 g/mol
単同位体質量: 117.9291563

名称と識別子

優先名称: Sulfuryl chloride fluoride
IUPAC: sulfuryl chloride fluoride
現地名: クロロフルオロ硫黄(VI)ジオキシド
英語名: SULFURYL CHLORIDE FLUORIDE
分子式: ClFO2S
分子量: 118.52

名称と別名

SULFURYL CHLORIDE FLUORIDEChlorosulfonyl fluorideSulfonyl chloride fluorideChloro fluoro sulfoneFluorosulfonyl chlorideSulfuryl chlorofluorideSulfuryl fluorochlorideChlorosulphonyl fluorideSulfuryl fluoride chlorideSO2ClFSO2FClFluorosulfuryl chloride

名称をさらに表示

クロロフルオロ硫黄(VI)ジオキシドスルホニルクロリドフルオリド硫酸クロリドフルオリドスルフロイルクロリドフルオリドスルフロクロリド酸フルオリド硫酸クロリドfluorosulfonylchloridetl212chlorofluorosulfonechlorosulfonylfluoridesulfurylfluorochloride

TL 212Y7TT1LZ9SDEINECS 237-126-2chlorofluorodioxosulfurSClFO2AI3-27293UNII-Y7TT1LZ9SD[SClFO2]

データベース識別子

CAS: 13637-84-8
PubChem CID: 26159
DTXSID: DTXSID0065567
ChEBI: CHEBI:39445
UNII: Y7TT1LZ9SD
EC Number: 237-126-2
Nikkaji: J101.060C

物性

構造計算による物性

XLogP: 0.9
極性表面積: 42.5 Å²
水素結合供与体数: 0
水素結合受容体数: 3
回転可能結合数: 0
重原子数: 5
形式電荷: 0
複雑度: 95

実験および物理化学的性質

Physical DescriptionLiquefied gas; Reacts with water; [MSDSonline]

物理化学的性質

融点: -125 °C · -125 °C
沸点: 7 °C · 7 °C
比重(密度): 1.623 g/cm3 · 1.623 g/cm3(Temp: 0 °C)
闪点: 113 °C · 113 °C
貯蔵温度: -20 °C · -20°C
溶解性: 2 O · reacts with H2O
外見: gas
色: colorless
CAS データベース: 13637 · 13637-84-8(CAS DataBase Reference)
EPAの化学物質情報: Sulfuryl chloride fluoride (13637-84-8)

化学的性質

化学的特性clear colorless to light yellow liquid

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]；H311 (100%): Toxic in contact with skin [Danger Acute toxicity, dermal]；H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]；H318 (100%): Causes serious eye damage [Danger Serious eye damage/eye irritation]；H331 (100%): Toxic if inhaled [Danger Acute toxicity, inhalation]

P260, P261, P262, P264, P264+P265, P270, P271, P280, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P361+P364, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 39 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory InformationSulfuryl chloride fluoride: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryA corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause pulmonary edema; [MSDSonline]

Hazard Classes and CategoriesAcute Tox. 3 (100%)；Acute Tox. 3 (100%)；Skin Corr. 1B (100%)；Eye Dam. 1 (100%)；Acute Tox. 3 (100%)

安全と保護具

Exposure Control and Personal Protection · 2 件

TIH (Toxic Inhalation Hazard) - Term used to describe gases and volatile liquids that are toxic when inhaled. Some are TIH materials themselves, e.g., chlorine, and some release TIH gases when spilled in water, e.g., chlorosilanes. [ERG 2016].

1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]

Threshold Limit Values (TLV)2.5 [mg/m3], as F

Permissible Exposure Limit (PEL)2.5 [mg/m3], as F

毒性情報

Adverse EffectsDermatotoxin - Skin burns.；Toxic Pneumonitis - Inflammation of the lungs induced by inhalation of metal fumes or toxic gases and vapors.

Toxicity DataLCLo (mice) = 520 mg/m3/10min

法規制情報

Regulatory InformationSulfuryl chloride fluoride: Does not have an individual approval but may be used under an appropriate group standard

安全データ

wgk: 3
tsca: TSCA listed
rtecs: WT4900000
ridadr: UN 2922 8/PG 1
risk_code: 14-23/24/25-34
hazard_code: T,C
hazard_note: Corrosive/Toxic/Moisture sensitive
safety_code: 26-27-28-36/37/39-45
hazard_class: 2.3

化学と産業

用途と製造

UsesProduced by fluorination of SO2Cl2 with SbF3; [Ullmann]

General Manufacturing InformationSulfuryl chloride fluoride: INACTIVE

サプライヤー4 社

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