基本情報
- CAS
14481-29-9- 標準SMILES
[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[Fe+2].[NH4+].[NH4+].[NH4+].[NH4+]- InChIKey
ZXQVPEBHZMCRMC-UHFFFAOYSA-R- 分子式
- C6H16FeN10
- 平均分子量
- 284.1 g/mol
- 単同位体質量
- 284.09087801
名称と識別子
- 優先名称
- Ammonium ferrocyanide
- IUPAC
- tetraazanium;iron(2+);hexacyanide
- 現地名
- フエロシアン化アンモニウム
- 英語名
- AMMONIUM FERROCYANIDE
- 分子式
- C6H16FeN10
- 分子量
- 284.1
名称と別名
AMMONIUM FERROCYANIDEtetraammonium ferrocyanideGHD63ZGL2LAmmonium hexacyanoferrate (II)DTXSID1051725AMMONIUM FERROCYANIDE [MI]Tetraammonium hexacyanoferrate(4-)(OC-6-11)-HEXAKIS(CYANO-.KAPPA.C)FERRATE(4-) AMMONIUM (1:4)RefChem:112158UNII-GHD63ZGL2LDTXCID1030280HSDB 2099
名称をさらに表示
ヘキサシアノ鉄(II)酸アンモニウムフエロシアン化アンモニウムヘキサシアノ鉄(II)酸アンモニウム水和物 SPOT TEST REAGENT,FOR THE DETERMINATION OF CA,≥92.0% ANHYDROUS BASIS (RT), 15% 水ヘキサシアノ鉄(II)酸アンモニウムN水和物ヘキサシアノ鉄(II)酸アンモニウム, 90%ﾍｷｻｼｱﾉ鉄酸四ｱﾝﾓﾆｳﾑFERROUS AMMONIUM CYANIDEAMMONIUM HEXACYANOFERRATE IItetraammoniumhexacyanoferrateammonium hexacyanoferrate(4-)IRON (II) AMMONIUM FERROCYANIDEtetraammoniumhexacyanoferrate(4-)hexacyano-ferrate(4-tetraammoniumAmmonium hexacyanoferrate hydrate
Tetraammonium hexacyanoferrate(4)EINECS 238-476-9Ferrate(4), hexacyano, tetraammoniumFerrate(4-), hexacyano-, tetraammoniumTriammonium hexakis-(cyano-C)ferrate(4-)AI3-28802Ammonium ferrocyanide ((NH4)4(Fe(CN)6))Ferrate(4-), hexakis(cyano-C)-, tetraammonium
物性
構造計算による物性
- 極性表面積
- 147 Ų
- 水素結合供与体数
- 4
- 水素結合受容体数
- 12
- 回転可能結合数
- 0
- 重原子数
- 17
- 形式電荷
- 0
- 複雑度
- 10
実験および物理化学的性質
Chemical ClassesNitrogen Compounds -> Ammonium Compounds
Color/Form
Yellow crystals
TURNS BLUE IN AIR
SolubilityFreely sol in water; practically insol in alcohol /Trihydrate/
Physical DescriptionYellow solid; Turns blue in air; [HSDB] Light green powder; [MSDSonline]
Stability/Shelf LifeLOSES NH3 ON EXPOSURE TO AIR & LIGHT; DECOMP ON HEATING /TRIHYDRATE/
Other Experimental PropertiesYellow crystalline powder /Trihydrate/
物理化学的性質
- 融点
- 300 °C · >300°C
- 溶解性
- 2 O; · soluble in H2O; insoluble in ethanol
- 外見
- 粉
- 色
- 黄色から緑色
- 水溶解度
- 2 O · 三水和物可溶性H2O [MER06]
- Merck
- 14 · 14,520
- CAS データベース
- 14481 · 14481-29-9(CAS DataBase Reference)
- EPAの化学物質情報
- Ferrate(4-), hexakis(cyano-.kappa.C)-, tetraammonium, (OC-6-11)- (14481-29-9)
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
This chemical does not meet GHS hazard criteria for 2.2% (1 of 45) of reports.
Warning
H302 (88.9%): Harmful if swallowed [Warning Acute toxicity, oral]
P261, P264, P270, P271, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 45 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
危険有害性情報
Regulatory InformationRestricted substance: Tetraammonium hexacyanoferrate
Hazards Summary
Emergency treatment: Irritants; [HSDB] Ferrocyanide complexes are stable and practically nontoxic because of the strong bonding between iron and cyanide. Cyanide ions may be formed slowly when the chemical is irradiated with UV light. [Ullmann] May cause irritation; [MSDSonline]
RCRA Requirements
/SRP:/ D003; A solid waste containing ammonium ferrocyanide may become characterized as a hazardous waste when subjected to testing for reactivity as stipulated in 40 CFR 261.23, and if so characterized, must be managed as a hazardous waste.
EPA Hazardous Waste NumberD003; /SRP:/ A waste containing ammonium ferrocyanide may (or may not) be characterized a hazardous waste following testing for the reactivity characteristics as prescribed by the Resource Conservation and Recovery Act (RCRA) regulations.
Clean Water Act RequirementsToxic pollutant designated pursuant to section 307(a)(1) of the Federal Water Pollution Control Act and is subject to effluent limitations. /Cyanides/
Hazard Classes and Categories
化学と産業
用途と製造
General Manufacturing InformationFerrate(4-), hexakis(cyano-.kappa.C)-, ammonium (1:4), (OC-6-11)-: ACTIVE
調製方法
純化方法The pale yellow trihydrate powder can be washed with 10% aqueous NH3, filtered, then washed several times with EtOH and Et2O, and dried at room temperature. It decomposes in a vacuum above 100o and should be stored away from light and under N2. In light and air it decomposes by losing NH3. [Lux in Handbook of Preparative Inorganic Chem (Ed. Brauer) Academic Press Vol II p 1509 1965.]
上流・下流製品情報
下流製品
サプライヤー40 社
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]
陕西缔都化学有限公司029-029-81123119 17391733320 · [email protected]
江苏艾康生物医药研发有限公司025-025-66113011 15955137747 · [email protected]
上海迈瑞尔生化科技有限公司4006356688 18621169109 · [email protected]
安耐吉化学&3A（安徽泽升科技股份有限公司）400-0056266 · [email protected]
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