N-Methylmorpholine N-oxide monohydrate (HCID 2724197)

名称と識別子

優先名称: N-Methylmorpholine N-oxide monohydrate
IUPAC: 4-methyl-4-oxidomorpholin-4-ium;hydrate
現地名: 4‐メチルモルホリン4‐オキシド一水和物
英語名: 4-Methylmorpholine N-oxide monohydrate
分子式: C5H11NO2
分子量: 117.15

名称と別名

70187-32-5N-Methylmorpholine N-oxide monohydrate4-Methylmorpholine 4-oxide monohydrateN-methylmorpholine oxide monohydrateUNII-087WU2FTQ5087WU2FTQ54-methylmorpholine oxide monohydrateN-METHYLMORPHOLINE N-OXIDE MONOHYDRATE [MI]MORPHOLINE, 4-METHYL-, 4-OXIDE, HYDRATE (1:1)RefChem:163858231-391-84-Methylmorpholine N-oxide monohydrate

名称をさらに表示

4‐メチルモルホリン4‐オキシド一水和物4-メチルモルホリン4-オキシド一水和物4-メチルモルホリンN-オキシド一水和物nmmoNMO monohydrateLABOTEST-BB LT00848163ine N-oxide monohydrateN-Methylmorpholin-N-oxidN-METHYL MORPHOLIN OXIDEN-METHYLMORPHOLINE-N-OXIDE HYDRATE4-METHYLMORPHOLINE-OXIDE MONOHYDRATE

80913-66-24-Methylmorpholine N-oxide Hydrate4-Methylmorpholine 4-oxide hydrate4-Methylmorpholine 4-oxide xhydrateMFCD00149388N-methylmorpholine-N-oxide monohydrate4-methyl-4-oxidomorpholin-4-ium;hydrate4-methyl-1,4-oxazinan-4-ium-4-olate hydrate

データベース識別子

CAS: 70187-32-5、80913-66-2
PubChem CID: 2724197
DTXSID: DTXSID601338654
UNII: 087WU2FTQ5
EC Number: 676-991-4、849-361-3

物性

構造計算による物性

極性表面積: 28.3 Å²
水素結合供与体数: 1
水素結合受容体数: 3
回転可能結合数: 0
重原子数: 9
形式電荷: 0
複雑度: 78.5

実験および物理化学的性質

CosmeticsFoam boosting; Surfactant; Cleansing

物理化学的性質

融点: 71 · 71-75 °C
貯蔵温度: 30 °C · Store below +30°C.
外見: 粉
色: ホワイトからライトベージュ
水溶解度: 水に溶ける。
BRN: 5449441 · 5449441
InChI: InChI=1S/C5H11NO2/c1-6(7)2-4-8-5-3-6/h2-5H2,1H3
InChIKey: LFTLOKWAGJYHHR-UHFFFAOYSA-N
SMILES: [N+]1([O-])(C)CCOCC1
CAS データベース: 70187 · 70187-32-5(CAS DataBase Reference)

化学的性質

化学的特性White to beige crystalline powder

安全と法規制

GHS分類

GHS Classification · 6 件

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 7 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

危険有害性情報

Regulatory Information4-Methylmorpholine oxide monohydrate: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and Categories · 2 件

Skin Irrit. 2 (100%)

安全データ

wgk: 1
tsca: Yes
hs_code: 29339900
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-36-37/39
Hazard Classifications: Repr. 2
ストレージクラス: 11 - Combustible Solids

化学と産業

用途と製造

Use ClassificationCosmetics -> Foam boosting; Surfactant; Cleansing

応用分野 · 2 件

用途オスミウム酸の再酸化剤。

使用4-Methylmorpholine N-oxide monohydrate is used as a solvent to prepare cellulose fibers. It is an oxidant and involved in the catalytic OsO4 oxidation of olefins to cis-1,2-diols. It is also involved in ruthenium catalyzed oxidation of alcohols to aldehydes and ketones.