CAS 15629-92-2 Dichloro(1,1'-(1,3-propanediyl)bis(1,1-diphenylphosphine-kappaP))nickel (HCID 2724937)

名称と識別子

優先名称: Dichloro(1,1'-(1,3-propanediyl)bis(1,1-diphenylphosphine-kappaP))nickel
IUPAC: dichloronickel;3-diphenylphosphanylpropyl(diphenyl)phosphane
現地名: [1,3-ビス(ジフェニルホスフィノ)プロパン]ニッケル(ＩＩ)ジクロリド
英語名: [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
分子式: C27H26Cl2NiP2
分子量: 542.04

名称と別名

15629-92-2RefChem:586663Dichloro(1,1'-(1,3-propanediyl)bis(1,1-diphenylphosphine-kappaP))nickel1,3-Bis(diphenylphosphino)propane nickel(II) chloride[1,3-Bis(diphenylphosphino)propane]nickel(II) chlorideNi(dppp)Cl2[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)(1,3-dppp)NiCl21,3-Bis(diphenylphosphino)propane nickel (II) chloride1,3-Bis(diphenylphosphino)propane nickel(II)chloridedichloronickel;3-diphenylphosphanylpropyl(diphenyl)phosphaneNiCl2(dppp)

名称をさらに表示

[1,3-ビス(ジフェニルホスフィノ)プロパン]ニッケル(ＩＩ)ジクロリドジクロロ[1,3-ビス(ジフェニルホスフィノ)プロパン]ニッケル（Ⅱ)塩化〔1,3-ビス(ジフェニルホスフィノ)プロパン〕ニッケル(II)[1,3-ビス(ジフェニルホスフィノ)プロパン]ジクロロニッケル(II)ジクロロ[1,3-ビス(ジフェニルホスフィノ)プロパン]ニッケル(II)塩化[1,3‐ビス(ジフェニルホスフィノ)プロパン]ニッケル(II)ジクロロ[ビス(1,3-ジフェニルホスフィノ)プロパン]ニッケル(II)ニッケル(II)1,3-ビス(ジフェニルホスフィノ)プロパンクロリド, 99%塩化[1,3-ビス(ジフェニルホスフィノ)プロパン]ニッケル(II)NiCl2(DPPP)NiCl2(DPPP)1.3-Bis(dipheny phosphine) propane nickel(II)chlorideDichloro[bis(1,3-diphenylphosphino)propane]nickel(II)1,3-Bis(diphenyl phosphine)propane nickel(II)dichloride1,3-B

C27H26Cl2NiP2(1,3-Bis(diphenylphosphino)propane)dichloronickel; 1,3-Bis(diphenylphosphino)nickel Dichloride; Dichloro[1,3-bis(diphenylphosphino)propane]nickel; Nickel 1,3-Bis(diphenylphosphino)propane Dichloride; (1,3-dppp)NiCl2;SCHEMBL6328AKOS005259144AC-4982FD14035[1,3-Bis(diphenylphosphino)propane] dichloronickel?3-diphenylphosphanylpropyl(diphenyl)phosphane dichloronickel

データベース識別子

CAS: 15629-92-2
PubChem CID: 2724937
EC Number: 605-052-3

物性

構造計算による物性

極性表面積: 0 Å²
水素結合供与体数: 0
水素結合受容体数: 0
回転可能結合数: 8
重原子数: 32
形式電荷: 0
複雑度: 353

物理化学的性質

融点: 213 °C · 213 °C (dec.)(lit.)
貯蔵温度: Inert atmosphere,Room Temperature
外見: 結晶
色: 赤
水溶解度: 不溶性
InChI: InChI=1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
InChIKey: ZBQUMMFUJLOTQC-UHFFFAOYSA-L
SMILES: P(C1=CC=CC=C1)(CCCP(C1C=CC=CC=1)C1C=CC=CC=1)C1C=CC=CC=1.[Ni](Cl)Cl
CAS データベース: 15629 · 15629-92-2(CAS DataBase Reference)

化学的性質

化学的特性red to red-brown powder or crystals

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H315 (99.2%): Causes skin irritation [Warning Skin corrosion/irritation]；H317 (100%): May cause an allergic skin reaction [Warning Sensitization, Skin]；H319 (99.2%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H334 (34.7%): May cause allergy or asthma symptoms or breathing difficulties if inhaled [Danger Sensitization, respiratory]；H335 (98.3%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]；H350 (92.6%): May cause cancer [Danger Carcinogenicity]

P203, P233, P260, P261, P264, P264+P265, P271, P272, P280, P284, P302+P352, P304+P340, P305+P351+P338, P318, P319, P321, P332+P317, P333+P317, P337+P317, P342+P316, P362+P364, P403, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 121 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory InformationRestricted substance: Nickel, dichloro[1,1'-(1,3-propanediyl)bis[1,1-diphenylphosphine-[?]P]]-；EC: 605-052-3；Restriction condition document: PDF link

Hazard Classes and CategoriesSkin Irrit. 2 (99.2%)；Skin Sens. 1 (100%)；Eye Irrit. 2 (99.2%)；Resp. Sens. 1 (34.7%)；STOT SE 3 (98.3%)；Carc. 1A (92.6%)

法規制情報

Regulatory InformationRestricted substance: Nickel, dichloro[1,1'-(1,3-propanediyl)bis[1,1-diphenylphosphine-[?]P]]-；EC: 605-052-3；Restriction condition document: PDF link

安全データ

F: 10-21
wgk: 3
tsca: No
ridadr: 3282
PRTR法: 特定第一種指定化学物質
hs_code: 29319090
risk_code: 49-36/37/38-42/43-40
安衛法: 特化則特定化学物質(管理第2類)
hazard_code: T,Xn
safety_code: 53-26-36/37/39-45-24-22
Hazard Classifications: Carc. 1AEye Irrit. 2Resp. Sens. 1Skin Irrit. 2Skin Sens. 1STOT SE 3
ストレージクラス: 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects

化学と産業

応用分野 · 2 件

用途有機合成触媒。

使用[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.

上流・下流製品情報

上流原料

ニッケルクロリドヘキサ水和物ジフェニルホスフィンエタノール 1,3-ジクロロプロパン (1mg/mlメタノール溶液) [水質分析用]1,3-ビス(ジフェニルホスフィノ)プロパン 1,3-ジブロモプロパンテトラヒドロフラン酢酸エチル塩酸ジクロロメタン水酸化ナトリウムトリフェニルホスフィン

サプライヤー100 社

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

衢州润东化工有限公司0570-8789886 18892685668 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

INTATRADE GmbH+49 3493/605464 · [email protected]

化合物ノート

読み込み中…

[1,3-ビス(ジフェニルホスフィノ)プロパン]ニッケル(ＩＩ)ジクロリド

基本情報