2-クロロプロピオン酸メチル

Methyl 2-chloropropionate

HCID 28659CAS 17639-93-9
部分構造検索類似構造を探す

基本情報

標準SMILES
COC(=O)C(C)Cl
InChIKey
JLEJCNOTNLZCHQ-UHFFFAOYSA-N
分子式
C4H7ClO2
平均分子量
122.55 g/mol
単同位体質量
122.01345714

概要

Methyl 2-chloropropionate appears as a colorless liquid. Insoluble in water. Irritating and narcotic in high concentrations. Used as a solvent and for making other chemicals and dyes.

名称と識別子

優先名称
Methyl 2-chloropropionate
IUPAC
methyl 2-chloropropanoate
現地名
2-クロロプロピオン酸メチル
英語名
Methyl 2-chloropropionate
分子式
C4H7ClO2
分子量
122.55

名称と別名

METHYL 2-CHLOROPROPIONATEMethyl 2-chloropropanoate17639-93-9Propanoic acid, 2-chloro-, methyl esterPropionic acid, 2-chloro-, methyl esterMethyl alpha-chloropropionateFDN17EXK1JNSC-70983DTXSID60864786MecpaRefChem:157318DTXCID10813264
名称をさらに表示
2-クロロプロピオン酸メチル2-クロロプロパン酸メチルメチル2-クロロプロピオナートメチル-2-クロロプロピオネトメチル2クロロプロピオネ-ト2-クロロプロピオン酸メチル 塩化物メチル 2-クロロプロピオネートMethyl 2-chloropropionate,96%Mehyl 2-chloropropionateMethyl 2-ChloropropionatCH3CHClC(O)OCH32-ChloropropionateMethyl 2-chloropropi2-chloropropyl MethylMethyl 2-chloropropion
2-chloropropionic acid, methyl esterMETHYL DL-ALPHA-CHLOROPROPIONATEalpha-chloropropionic acid, methyl esterMETHYL 2-CHLOROPROPANOATE, (A+-)-241-624-52-Chloropropionic acid methyl ester(+)-Methyl (R)-2-chloropropionateMFCD00000863

データベース識別子

CAS
17639-93-9
PubChem CID
28659
DTXSID
DTXSID60864786
UNII
FDN17EXK1J
EC Number
241-624-5
Nikkaji
J34.936D

物性

構造計算による物性

XLogP
1.1
極性表面積
26.3 Ų
水素結合供与体数
0
水素結合受容体数
2
回転可能結合数
2
重原子数
7

実験および物理化学的性質

Chemical ClassesFlammable agents - 3rd degree
Physical DescriptionMethyl 2-chloropropionate appears as a colorless liquid. Insoluble in water. Irritating and narcotic in high concentrations. Used as a solvent and for making other chemicals and dyes.

物理化学的性質

融点
-10 °C · -10 °C
沸点
132 · 132-133 °C(lit.)
比重(密度)
1.075 g/mL · 1.075 g/mL at 25 °C(lit.)
蒸気密度
4.22 · 4.22 (vs air)
蒸気圧
5.25 mm · 5.25 mm Hg ( 20 °C)
屈折率
20 · n20/D 1.417(lit.)

化学的性質

化学的特性clear colorless liquid

安全と法規制

GHS分類

GHS Classification · 6 件

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 91 reports by companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Warning

H226: Flammable liquid and vapor [Warning Flammable liquids]

危険有害性情報

Regulatory Information · 4 件

Chemical: Propanoic acid, 2-chloro-, methyl ester

Status: Active Update: 09-08-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/5504

Methyl 2-chloropropionate: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelFlammable Liquid
Fire Hazards · 2 件

Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

· HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Health Hazards · 2 件

Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

· May cause toxic effects if inhaled or absorbed through skin.

DOT ID and Guide2933 129
Reactive GroupEsters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters

安全と保護具

Fire FightingExcerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:
Accidental Release Measures · 2 件

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 件

Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:
Isolation and Evacuation · 2 件

Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]:

Immediate precautionary measure

安全データ

wgk
1
tsca
TSCA listed
rtecs
UE9100000
ridadr
UN 2933
hs_code
29159080
risk_code
10-36/37/38

化学と産業

用途と製造

General Manufacturing InformationPropanoic acid, 2-chloro-, methyl ester: ACTIVE
応用分野 · 4 件

用途有機合成原料。

用途医薬?農薬中間体、有機合成中間体

使用Methyl 2-chloropropionate is used as initiator during the synthesis of acrylamide homopolymers and acrylamide-N-isopropylacrylamide block copolymers. It is also used to produce 2-thiophen-2-yl-propionic acid methyl ester.

一般的な説明A colorless liquid. Flash point 101°F. Density 8.9 lb / gal. Insoluble in water. Irritating and narcotic in high concentrations. Used as a solvent and for making other chemicals and dyes.

上流・下流製品情報

サプライヤー50 社

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
Shandong chuangyingchemical Co., Ltd.18853181302 · [email protected]
武汉欣扬瑞和化学科技有限公司153-07155313 15307155313 · [email protected]

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