ビス(3-カルボキシプロピオニル)ペルオキシド

In case of fire, water should be applied by the sprinkler system or by hose from a safe distance, preferably with a fog nozzle. Foam may be necessary instead if the peroxide is diluted in a low density flammable solvent. Portable extinguishers should not be used except for very small fires. Peroxides threatened by fire should be wetted from a safe distance for cooling. /Peroxides, Organic and Inorganic/

KEEP WELL CLOSED & PROTECTED FROM LIGHT.

THEY SHOULD BE STORED IN COOL, VENTILATED, ISOLATED AREA AWAY FROM ORGANIC OR OTHER EASILY OXIDIZABLE MATERIALS & AWAY FROM ACUTE FIRE HAZARDS. CONTAINERS SHOULD BE KEPT CLOSED & PLAINLY LABELED. /PEROXIDES, ORGANIC/

Spills should be cleaned up promptly using non-sparking tools and an inert, moist diluent such as vermiculite or sand. Sweepings may be placed in open containers or polyethylene bags and the area washed with water and detergent. Spilled, contaminated, waste or questionable peroxides should be destroyed. /Peroxides, Organic and Inorganic/

Most peroxides can be hydrolyzed by adding them slowly with stirring to about ten times their weight of cold 10% sodium hydroxide solution. The reaction may require several hours. /Peroxides, Organic and Inorganic/

Dilute and drain into the sewer with abundant water. /Hydrogen peroxide/

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Excerpt from ERG Guide 146 [Organic Peroxides (Heat, Contamination and Friction Sensitive)]:

PERSONNEL SHOULD BE CAUTIONED REGARDING THEIR USE. PERSONNEL WHO MUST BE EXPOSED TO THESE MATERIALS SHOULD USE PROTECTIVE EQUIPMENT. RECOMMENDED ARE PROTECTIVE CLOTHING TO AVOID SKIN CONTACT, CHEMICAL SAFETY GOGGLES FOR PROTECTION OF EYES, & RESPIRATOR TO AVOID INHALATION OF EXTENSIVE AMT OF THESE MATERIALS IN VAPOR FORM. /PEROXIDES, ORGANIC/

Persons handling peroxides should use safety glasses with side shields, goggles or face shield for eye protection. Emergency eyewash facilities should be provided. Gloves, aprons and other protective clothing as necessary should be used to prevent skin contact. Clothing and equipment that generate static electricity should be avoided. Smoking should be prohibited. /Peroxides, Organic and Inorganic/

THE MAIN TOXIC EFFECT IS IRRITATION OF SKIN, MUCOUS MEMBRANES AND EYES. PROLONGED SKIN CONTACT OR SPLASHES IN THE EYES MAY CAUSE INJURY. SOME ORGANIC PEROXIDE VAPORS ARE IRRITATING AND MAY ALSO CAUSE HEADACHES, INTOXICATION SIMILAR TO ALCOHOL AND LUNG EDEMA. /ORG PEROXIDES/

Moderately toxic by ingestion and inhalation.

The main toxic effect of most peroxides is irritation of skin, mucous membranes and eyes. Prolonged or intense skin contact or splashes in the eyes may cause severe injury. Some organic peroxide vapors are irritating and may also cause headaches, intoxication similar to alcohol, and lung edema in inhaled in high concentrations. Some are ... skin sensitizers. Dialkyl peroxides are generally not as strongly irritating, and the diacyl peroxides are the least irritating of the peroxides. Hydroperoxides, peroxyacids and particularly methyl ethyl ketone peroxide are much more severe. They are extremely irritating and corrosive to the eyes, wit risk of blindness, and may cause serious injury or death if ingested in sufficient quantity. /Peroxides, Organic and Inorganic/

Peroxides should be washed promptly from the skin to prevent irritation. In the case of eye contact, the eyes should be flushed immediately with large amounts of water, and medical attention should be obtained. ... Medical attention should also be obtained in case of accidental ingestion. ... /Peroxides, Organic and Inorganic/