2-Ethyl-6-methylaniline (HCID 32485)

名称と識別子

優先名称: 2-Ethyl-6-methylaniline
IUPAC: 2-ethyl-6-methylaniline
現地名: 2-メチル-6-エチルアニリン
英語名: 6-Ethyl-o-toluidine
分子式: C9H13N
分子量: 135.21

名称と別名

2-ETHYL-6-METHYLANILINE24549-06-26-Ethyl-o-toluidineBenzenamine, 2-ethyl-6-methyl-2-Methyl-6-ethylanilineo-Toluidine, 6-ethyl-6-Ethyl-2-methylanilineDTXSID7027833C 25702DTXCID40783332Y3271G51RefChem:471877

名称をさらに表示

2-メチル-6-エチルアニリン6-エチル-o-トルイジン2-エチル-6-メチルベンゼンアミン2-エチル-6-メチルアニリン6-エチル-2-メチルアニリン6-メチル-2-エチルアニリン2‐エチル‐6‐メチルアニリン標準品2-エチル-6-メチルアニリン標準品EMA標準品MEA3-ethyl-2-methylaniline2-ethyl-6-methyl-benzenaminMEA1c25702

246-309-62-ethyl-6-methyl-aniline2-Ethyl-6-methylbenzenamineMFCD00007752Aniline, 2-methyl-6-ethyl-6-ethyl-2-methylphenylamine6-Ethyl-2-toluidine2-Methyl-6-ethyl aniline

データベース識別子

CAS: 24549-06-2
PubChem CID: 32485
DTXSID: DTXSID7027833
ChEMBL: CHEMBL3187754
UNII: 32Y3271G51
EC Number: 246-309-6
Nikkaji: J3.796F

物性

構造計算による物性

XLogP: 2.4
極性表面積: 26 Å²
水素結合供与体数: 1
水素結合受容体数: 1
回転可能結合数: 1
重原子数: 10
形式電荷: 0
複雑度: 101

実験および物理化学的性質

Density0.969 at 68 °F (USCG, 1999) - Less dense than water; will float

Flash Point215 °F (USCG, 1999)

Boiling Point447.8 °F at 760 mmHg (USCG, 1999)

Melting Point-27.4 °F (USCG, 1999)

Physical Description · 2 件

2-methyl-6-ethyl aniline appears as a clear liquid with a pungent odor. Water insoluble and less dense than water. Hence floats on water. (USCG, 1999)

Liquid

Kovats Retention Index1217.7

物理化学的性質

融点: -33 °C · -33 °C (lit.)
沸点: 231 °C · 231 °C (lit.)
比重(密度): 0.968 g/mL · 0.968 g/mL at 25 °C (lit.)
蒸気圧: 0.06 mm · 0.06 mm Hg ( 20 °C)
屈折率: 20 · n20/D 1.552(lit.)
闪点: 193 °F · 193 °F
貯蔵温度: Keep in dark place,Inert atmosphere,Room temperature
溶解性: 2.66 g/リットル · 2.66g/リットル
酸解離定数(Pka): 4.22 · 4.22±0.10(Predicted)
外見: clear liquid
色: Colorless to Light red to Green
BRN: 2079468 · 2079468
Henry's Law Constant: 3.2 · 3.2×100 mol/(m3Pa) at 25℃, Zhang et al. (2010)
InChI: 1S/C9H13N/c1-3-8-6-4-5-7(2)9(8)10/h4-6H,3,10H2,1-2H3
InChIKey: JJVKJJNCIILLRP-UHFFFAOYSA-N
SMILES: CCc1cccc(C)c1N
LogP: 2.66 · 2.66
CAS データベース: 24549 · 24549-06-2(CAS DataBase Reference)
NISTの化学物質情報: 2 · Benzenamine, 2-ethyl-6-methyl-(24549-06-2)
EPAの化学物質情報: 2 · 2-Ethyl-6-methylaniline (24549-06-2)

化学的性質

化学的特性Liquid

安全と法規制

GHS分類

GHS Classification · 5 件

Danger

H302+H312+H332 (27.4%): Harmful if swallowed, in contact with skin or if inhaled [Warning Acute toxicity, oral; acute toxicity, dermal; acute toxicity, inhalation]；H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]；H312 (59.4%): Harmful in contact with skin [Warning Acute toxicity, dermal]；H331 (36.8%): Toxic if inhaled [Danger Acute toxicity, inhalation]；H332 (55.7%): Harmful if inhaled [Warning Acute toxicity, inhalation]；H412 (59.4%): Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P261, P264, P270, P271, P273, P280, P301+P317, P302+P352, P304+P340, P316, P317, P321, P330, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 106 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

危険有害性情報

Regulatory Information · 3 件

Chemical: Benzenamine, 2-ethyl-6-methyl-

Benzenamine, 2-ethyl-6-methyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzenamine, 2-ethyl-6-methyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 14-05-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/12644

Fire HazardsSpecial Hazards of Combustion Products: Contain poisonous oxides of nitrogen and carbon dioxide.；Behavior in Fire: Produces poisonous gases. (USCG, 1999)

Health HazardsInhalation causes weakness, reduction in respiratory rate, coma, gradual respiratory failure, and mild cyanosis (high concentrations). Causes severe irritation of the eyes. Ingestion may produce cyanosis. (USCG, 1999)

Reactive GroupAmines, Aromatic

Reactivity Profile · 1 件

2-METHYL-6-ETHYL ANILINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides.

Air and Water ReactionsInsoluble in water.

安全と保護具

Fire FightingFire Extinguishing Agents: Water, dry chemical, foam, carbon dioxide. (USCG, 1999)

First Aid · 1 件

INHALATION: Remove to fresh air; call a physician.；EYES: Flush eyes with plenty of running water for at least 15 minutes. Call a physician.；SKIN: Wash thoroughly with soap and water. Flush with running water for at least 15 minutes.；INGESTION: If victim is conscious, have victim drink water or milk and induce vomiting. (USCG, 1999)

Personal Protective Equipment (PPE)Chemical goggles - face shield, protective gloves, organic vapor canister mask. (USCG, 1999)

毒性情報

USGS Health-Based Screening Levels for Evaluating Water-Quality · 3 件

2-Ethyl-6-methylaniline

Pesticide degradation product

Smith, C.D. and Nowell, L.H., 2024. Health-Based Screening Levels for evaluating water-quality data (3rd ed.). DOI:10.5066/F71C1TWP

法規制情報

Regulatory Information · 3 件

Chemical: Benzenamine, 2-ethyl-6-methyl-

Benzenamine, 2-ethyl-6-methyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzenamine, 2-ethyl-6-methyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 14-05-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/12644

安全データ

F: 8-23
wgk: 2
tsca: TSCA listed
rtecs: BY5600000
ridadr: 2810
毒性: mouse,LD50,oral,930mg/kg (930mg/kg),BEHAVIORAL: MUSCLE WEAKNESSAUTONOMIC NERVOUS SYSTEM: OTHER (DIRECT) PARASYMPATHOMIMETICBEHAVIORAL: ATAXIA,Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 52(6), Pg. 85, 1987.
hs_code: 29214980
risk_code: 22-20/21/22-26-22/23-10
消防法: 危-4-3-III
hazard_code: Xn
safety_code: 24/25-23-3/14
Hazard Classifications: Acute Tox. 4 DermalAcute Tox. 4 InhalationAcute Tox. 4 OralAquatic Chronic 3
ストレージクラス: 10 - Combustible liquids

化学と産業

用途と製造

U.S. Production2023: 40,000,000 - <55,000,000 lb；2022: 40,000,000 - <55,000,000 lb；2021: 25,000,000 - <40,000,000 lb；2020: 40,000,000 - <55,000,000 lb

Industry UsesIntermediate；Processing aids not otherwise specified

General Manufacturing Information · 2 件

Pesticide, Fertilizer, and Other Agricultural Chemical Manufacturing

Benzenamine, 2-ethyl-6-methyl-: ACTIVE

応用分野

使用2-Ethyl-6-methylaniline is an intermediate for the production of alachlor, butachlor, metolachlor-herbicides, tiafentiurone-insecticide, carbodiimide and RIM-PUR Product Data Sheet

一般的な説明A clear liquid with a pungent odor. Water insoluble and less dense than water. Hence floats on water.

上流・下流製品情報

上流原料

エタノール o-トルイジン塩酸 Benzene, 1-ethyl-3-methyl-2-nitro-3-エチルトルエン

下流製品

2-クロロ-N-(2-エチル-6-メチルフェニル)アセトアミドプロピソクロル N-(エトキシメチル)-N-(2-エチル-6-メチルフェニル)-2-クロロアセトアミド 2-クロロ-2'-エチル-N-(2-メトキシ-1-メチルエチル)-6'-メチルアセトアニリド Acetochlor E.C.硝酸グアニジン 4-ブロモ-6-エチル-2-メチルアニリン 2-エチル-6-メチル-N-メチレンベンゼンアミン

サプライヤー50 社

国药集团化学试剂有限公司86-21-63210123 · [email protected]

常州帝通化工有限公司+86-0519-88298848 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

郑州阿尔法化工有限公司+86-18530059196 · [email protected]

湖北永阔科技有限公司027-59223108 15972152991 · [email protected]

2-メチル-6-エチルアニリン

基本情報