メチル-5-ノルボルネン-2,3-ジカルボン酸無水物
Methyl nadic anhydride
基本情報
- CAS
25134-21-8- 標準SMILES
CC12C=CC(C1)C1C(=O)OC(=O)C12- InChIKey
LTVUCOSIZFEASK-MPXCPUAZSA-N- 分子式
- C10H10O3
- 平均分子量
- 178.18 g/mol
名称と識別子
- 優先名称
- Methyl nadic anhydride
- IUPAC
- 1-methyl-4-oxatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
- 現地名
- メチル-5-ノルボルネン-2,3-ジカルボン酸無水物
- 英語名
- Methyl-5-norbornene-2,3-dicarboxylic anhydride
- 分子式
- C10H10O3
- 分子量
- 178.18
名称と別名
Nadic methyl anhydrideKayahard MCDHardener HY906Methylendic anhydrideHSDB 6093MEA 610EINECS 246-644-8BRN 0162395TK 10 524CCRIS 9477endo-Methylenemethyltetrahydrophthalic anhydride5-Norbornene-2,3-dicarboxylic anhydride, methyl-
名称をさらに表示
メチル-5-ノルボルネン-2,3-ジカルボン酸無水物ナジックメチル酸無水物カヤハルドNMAメチルナド酸無水物メチルナジック酸無水物ナジックメチルアンヒドリドメチル-3,6-endo-メチレンテトラヒドロフタル酸無水物メチル-3,6-エンドメチレンテトラヒドロ無水フタル酸カヤハードMCDメチレンジックアンヒドリド無水メチルエンドメチレンテトラヒドロフタル酸メチル-3a'α,4,7,7aα-テトラヒドロ-4α,7α-メタノイソベンゾフラン-1,3-ジオン(3aα,4α,7α,7aα)-3a,4,7,7a-テトラヒドロメチル-4,7-メタノイソベンゾフラン-1,3-ジオンメチルナジックアンヒドリド3aα,4α,7α,7aα-テトラヒドロメチル-4,7-メタノイソベンゾフラン-1,3-ジオンメチルビシクロ[2.2.1]ヘプテン-2,3-ジカルボン酸無水物エピクレNMAメチルエンドメチレンテトラヒドロフタル酸無水物無水メチル-5-ノルボルネン-2,3-ジカルボン酸無水メチルナジン酸MNAMETHYL NADIC ANHYDRIDENMAXMNAmea610tk10524epicurenmaEpicure NMA
Methyl-tetrahydro-3,6-endomethylenephthalic anhydrideMethylbicyclo(2.2.1)heptene-2,3-dicarboxylic anhydrideMethyl-1,2,3,6-tetrahydro-3,6-endomethylenephthalic anhydrideMethylbicyclo(2.2.1)heptene-2,3-dicarboxylic anhydride isomersEC 246-644-84,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aalpha,4alpha,7alpha,7aalpha)-5-17-11-00199 (Beilstein Handbook Reference)RefChem:157957
データベース識別子
- CAS
25134-21-8- PubChem CID
- 32802
- EC Number
- 246-644-8
- Nikkaji
- J1.864.179H
物性
構造計算による物性
- XLogP
- 1.2
- 極性表面積
- 43.4 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 3
- 回転可能結合数
- 0
- 重原子数
- 13
- 形式電荷
- 0
- 複雑度
- 344
実験および物理化学的性質
PolymersPlastics & Rubber -> Acid Anhydrides, Cyclic
Density
1.200-1.250 @ 20 °C/20 °C
1.232 @25 °C
Viscosity175-225 CP @ 25 °C
Color/FormCOLORLESS TO LIGHT-YELLOW VISCOUS LIQ
SolubilityMISCIBLE IN ALL PROPORTIONS WITH ACETONE, BENZENE, NAPHTHA, & XYLENE
Melting Point18 °C
Vapor Pressure0.1 [mmHg]
Food Contact Substances
FCS -> FDA Cumulative Estimated Daily Intake (CEDI)
FCS -> FDA Inventory of Food Contact Substances Listed in 21 CFR
Refractive IndexINDEX OF REFRACTION: 1.500-1.506 @ 20 °C/D
Physical Description
Liquid
Colorless to light yellow liquid; [HSDB] Colorless liquid; [MSDSonline]
物理化学的性質
安全と法規制
安全情報は参考情報です。供給元の安全データシート（SDS）、適用法令、専門家による評価に代わるものではありません。
GHS分類
GHS Classification
Danger
H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]
P233, P260, P261, P264, P264+P265, P270, P271, P272, P280, P284, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P319, P321, P330, P332+P317, P333+P317, P337+P317, P342+P316, P362+P364, P363, P403, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 295 reports by companies from 15 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Warning
H302: Harmful if swallowed [Warning Acute toxicity, oral]
危険有害性情報
Regulatory Information
Chemical: 4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3a.alpha.,4.alpha.,7.alpha.,7a.alpha.)-
4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aR,4S,7R,7aS)-rel- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aR,4S,7R,7aS)-rel- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
REACH registered substance: 1,2,3,6-tetrahydromethyl-3,6-methanophthalic anhydride (EC: 246-644-8)
Methylnorbornen-2,3-dicarboxylic anhydride: Does not have an individual approval but may be used under an appropriate group standard
Hazards SummaryA skin and eye irritant; May cause respiratory sensitization; [eChemPortal: ERMA] An irritant; Inhalation may cause respiratory sensitization; [MSDSonline] See ACID ANHYDRIDES.
Hazard Classes and Categories
Acute Tox. 4 (100%)
Acute toxicity (Oral) - Category 4
Acute toxicity (Oral) - Category 4
安全と保護具
化学と産業
用途と製造
Uses
Used as a curing agent (epoxy resins), an intermediate (polyesters, alkyd resins, and plasticizers), and in electrical laminating and filament-winding; [HSDB]
Plastic Composites Manufacturing [Category: Industry]
CURING AGENT FOR EPOXY RESINS; INTERMEDIATE FOR POLYESTERS, ALKYD RESINS, & PLASTICIZERS; ELECTRICAL LAMINATING & FILAMENT-WINDING
CURING AGENT FOR EPOXY RESINS-EG, FOR ELECTRICAL CASTINGS
CHEM INT FOR POLYESTER RESINS
U.S. Exports
(1979) No Data
(1981) No Data
U.S. Imports
(1979) No Data
(1981) No Data
U.S. Production
2023: 154,070 lb
(1981) PROBABLY GREATER THAN 2.27X10+6 GRAMS
(1982) MORE THAN 2.27X10+6 G (MIXED ISOMERS)
Consumer UsesIntermediate
Industry UsesIntermediate
Methods of ManufacturingREACTION OF METHYLCYCLOPENTADIENE WITH MALEIC ANHYDRIDE
General Manufacturing Information
All Other Basic Organic Chemical Manufacturing
4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aR,4S,7R,7aS)-rel-: ACTIVE
応用分野
用途エポキシ樹脂硬化剤 (NITE CHRIP)
使用Methyl-5-norbornene-2,3-dicarboxylic anhydride is used as a curing agent in epoxy resins and in the preparation of vertically aligned and penetrated carbon nanotube/polymer film. It serves as an intermediate in polyesters, alkyd resins and plasticizers. It is also used in electrical laminating and filament-winding. Further, it is used in the preparation of methyl nadimides endcapped resins based on tris(3-aminophenyl)phosphine oxide. It is utilized in the flame retarding treatment.
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